7035-02-1

• 常用中文名：2-甲氧基苄基氯
• 常用英文名：2-methoxybenzylchloride
• CAS号：7035-02-1
• 分子式：C₈H₉ClO
• 分子量：156.609
• 发布时间：2018-07-30 22:06:19
• 更新时间：2024-01-09 18:54:37

名称

• 中文名: 2-甲氧基氯化苄
• 英文名: 2-Methoxybenzyl chloride
• 中文别名: 2-甲氧基氯苄; 2-甲氧基苄基氯; 2-甲氧基苄氯
• 英文别名: 2-methoxybenzylchloride; 1-(Chloromethyl)-2-methoxybenzene; EINECS 230-312-4; 2-(Chloromethyl)phenyl methyl ether; MFCD00060276; Benzene, 1-(chloromethyl)-2-methoxy-; o-Methoxybenzyl chloride

物化性质

• 密度: 1.1±0.1 g/cm3
• 沸点: 215.2±15.0 °C at 760 mmHg
• 熔点: 28.3-29.8 °C(lit.)
• 分子式: C₈H₉ClO
• 分子量: 156.609
• 闪点: 89.6±14.4 °C
• 精确质量: 156.034195
• PSA: 9.23000
• LogP: 2.40
• 蒸汽压: 0.2±0.4 mmHg at 25°C
• 折射率: 1.517
• 储存条件:

  密封储存，储存于阴凉、干燥的库房。冷藏温度4ºC。常用氮气保护。

• 稳定性:

  常温常压下稳定，对水敏感。避免与不相容材料，湿空气，水接触。与强氧化剂反应。

• 分子结构:

  1、摩尔折射率：42.69

  2、摩尔体积（cm³/mol）：141.1

  3、等张比容（90.2K）：339.1

  4、表面张力（dyne/cm）：33.3

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：16.92

  7、单一同位素质量：156.034193 Da

  8、标称质量：156 Da

  9、平均质量：156.6095 Da

• 计算化学:

  1、 疏水参数计算参考值（XlogP）：2.4

  2、 氢键供体数量：0

  3、 氢键受体数量：1

  4、 可旋转化学键数量：2

  5、 互变异构体数量：

  6、 拓扑分子极性表面积（TPSA）：9.2

  7、 重原子数量：10

  8、 表面电荷：0

  9、 复杂度：95.3

  10、 同位素原子数量：0

  11、 确定原子立构中心数量：0

  12、 不确定原子立构中心数量：0

  13、 确定化学键立构中心数量：0

  14、 不确定化学键立构中心数量：0

  15、 共价键单元数量：1

• 更多:

  1. 性状：白色或黄色透明液体

  2. 密度（g/mL,25℃）：1.125

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：28.3-29.8

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC，26mmHg）：122-124

  7. 折射率(n20/D)：1.549

  8. 闪点（ºC）：98

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（mmHg,217ºC）：未确定

  12. 饱和蒸气压（kPa,25ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

Name: 2-Methoxybenzyl chloride Material Safety Data Sheet Synonym: 2-(Chloromethyl)anisol CAS: 7035-02-1 Section 1 - Chemical Product MSDS Name:2-Methoxybenzyl chloride Material Safety Data Sheet Synonym:2-(Chloromethyl)anisol Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 7035-02-1 2-Methoxybenzyl chloride 230-312-4 Hazard Symbols: C Risk Phrases: 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Causes burns. Potential Health Effects Eye: Causes eye burns. Lachrymator (substance which increases the flow of tears). Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER! Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a tightly closed container. Keep refrigerated. (Store below 4C/39F.) Store under nitrogen. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 7035-02-1: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 122 - 124 deg C @26mmHg Freezing/Melting Point: 28.3 - 29.8 deg C Autoignition Temperature: Not available. Flash Point: 98 deg C ( 208.40 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.125 Molecular Formula: C8H9ClO Molecular Weight: 156.61 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, exposure to moist air or water. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 7035-02-1 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-Methoxybenzyl chloride - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.* Hazard Class: 8 UN Number: 3261 Packing Group: III IMO Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. Hazard Class: 8 UN Number: 3261 Packing Group: III RID/ADR Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. Hazard Class: 8 UN Number: 3261 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 7035-02-1: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 7035-02-1 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 7035-02-1 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): C: Corrosive;
• 风险声明 (欧洲): R34
• 安全声明 (欧洲): S26-S27-S36-S45-S36/37/39
• 危险品运输编码: UN 3261 8/PG 3
• WGK德国: 3
• 海关编码: 2909309090

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海关

海关编码	2909309090
中文概述	2909309090 其他芳香醚及其卤化衍生物、磺化、硝化衍生物（包括亚硝化衍生物）。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%