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| 中文名 | 班酰氯 |
|---|---|
| 英文名 | bansyl chloride |
| 中文别名 | 5-二丁基氨基-1-萘磺酰氯 |
| 英文别名 |
Bansyl Chloride
MFCD00059134 5-(dibutylamino)naphthalene-1-sulfonyl chloride |
| 密度 | 1.19g/cm3 |
|---|---|
| 沸点 | 449.2ºC at 760mmHg |
| 分子式 | C18H24ClNO2S |
| 分子量 | 353.90700 |
| 闪点 | 225.4ºC |
| 精确质量 | 353.12200 |
| PSA | 45.76000 |
| LogP | 6.25470 |
| 外观性状 | 液体;Light yellow to Brown clear liquid to cloudy liquid |
| 折射率 | 1.579 |
| 储存条件 | 密封、阴凉、干燥保存 |
| 稳定性 | 常规情况下不会分解，没有危险反应 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:3 4.可旋转化学键数量:8 5.互变异构体数量:无 6.拓扑分子极性表面积45.8 7.重原子数量:23 8.表面电荷:0 9.复杂度:440 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：未确定 2. 密度（g/mL,25ºC）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC）：未确定 6. 沸点（ºC，5mm hg）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（ºC）：未确定 10. 自燃点或引燃温度（ºC）： 未确定 11. 蒸气压（kPa,20ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
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Section I.Chemical Product and Company Identification Chemical NameBansyl Chloride (10% in Hexane) Portland OR 1-Naphthalenesulfonyl chloride, 5-(dibutylamino)- Synonym (CA INDEX NAME);
5-(N,N-Dibutylamino)naphthalene-1-sulfonyl Chloride Chemical FormulaC18H24ClNO2S CAS Number43040-76-2 110-54-3 (Hexane) Section II.Composition and Information on Ingredients CAS Number Percent (%)TLV/PELToxicology Data Chemical Name Bansyl Chlorideca. 10.0This chemical is classified as a (Hexane) 43040-76-2 (10% in Hexane)carcinogen. There is noRat LD50 (oral) 25 gm/kg 110-54-3ca. 90.0 (Hexane)acceptable exposure limit for a Rat LD50 (inhalation) 48000 ppm/4H carcinogen. This compound is classified as a possible mutagen. There is no acceptable exposure limit for a mutagen. Section III. Hazards Identification Acute Health EffectsCorrosive to skin, eyes, and respiratory system. Liquid or spray mist may produce tissue damage, particularly in mucous membranes of the eyes, mouth and respiratory tract. Skin contact may produce burns. Eye contact can result in corneal damage or blindness. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Corrosive materials may cause serious injury if ingested. Harmful if ingested or inhaled. Minimize exposure to this material. Severe overexposure can result in injury or death. Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound. Chronic Health EffectsCARCINOGENIC EFFECTS : Carcinogenic by RTECS criteria. MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Tumorigenic effects. (Hexane) Rat TCLo Inhalation 1000 ppm/4H for 59 weeks intermittent TOXIC EFFECTS: Tumorigenic – Carcinogenic by RTECS criteria Tumorigenic Effects – Testicular tumors Mouse TCLo Inhalation 9018 ppm/6H for 2 years intermittent TOXIC EFFECTS: Tumorigenic – Neoplastic by RTECS criteria Liver - Tumors DEVELOPMENTAL TOXICITY: Reproductive effects. (Hexane) Rat TCLo Inhalation 5000 ppm, female 6-19 days of pregnancy TOXIC EFFECTS: Specific Developmental Abnormalities – Musculoskeletal system Specific Developmental Abnormalities – Urogenital system Rat TCLo Inhalation 5000 ppm/20 hours, female 6-19 days of pregnancy TOXIC EFFECTS: Effects on Embryo or Fetus – Fetotoxicity Mouse TCLo Inhalation 5000 ppm, female 6-17 days of pregnancy TOXIC EFFECTS: Effects on Fertility – Post-implantation mortality Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Continued on Next Page Bansyl Chloride (10% in Hexane) Section IV.First Aid Measures Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 Eye Contact minutes. Get medical attention. Skin ContactIn case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. InhalationIf the victim is not breathing, perform mouth-to-mouth resuscitation. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, oxygen can be administered. Seek medical attention if respiration problems do not improve. IngestionDO NOT INDUCE VOMITING. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Section V.Fire and Explosion Data 223°C (433.4°F) (Hexane) Flammable.Auto-Ignition Flammability Flash PointsFlammable LimitsLOWER: 1.1% UPPER: 7.5% (Hexane) -20°C (-4°F) (Hexane) Combustion ProductsThese products are toxic carbon oxides (CO, CO2), nitrogen oxides (NO, NO2), halogenated compounds, sulfur oxides (SOx). WARNING: Highly toxic HCl gas is produced during combustion. Fire Hazards Not available. Risks of explosion of the product in presence of mechanical impact: Not available. Explosion Hazards Risks of explosion of the product in presence of static discharge: Not available. Fire Fighting MediaFlammable liquid. SMALL FIRE: Use DRY chemical powder. and Instructions LARGE FIRE: Use alcohol foam, water spray or fog. Consult with local fire authorities before attempting large scale fire-fighting operations. Section VI.Accidental Release Measures Spill CleanupFlammable material. Corrosive material. Harmful material. Carcinogenic material. Possibly mutagenic material. Environmentally hazardous material. Moisture sensitive material. Instructions Keep away from heat. Mechanical exhaust required. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. DO NOT get water inside container. DO NOT touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Consult federal, state, and/or local authorities for assistance on disposal. Section VII. Handling and Storage FLAMMABLE. CORROSIVE. HARMFUL. CARCINOGEN. POSSIBLE MUTAGEN. ENVIRONMENTAL HAZARD. Handling and Storage MOISTURE SENSITIVE. MAY DEVELOP PRESSURE. Keep container dry. Keep away from heat. Mechanical exhaust Information required. Avoid excessive heat and light. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. Wear suitable protective clothing. If you feel unwell, seek medical attention and show the label when possible. Treat symptomatically and supportively. Always store away from incompatible compounds such as oxidizing agents, moisture. Section VIII. Exposure Controls/Personal Protection Engineering ControlsProvide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash station and safety shower is proximal to the work-station location. Personal ProtectionFace shield. Lab coat. Vapor respirator. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Be sure to use a MSHA/NIOSH approved respirator or equivalent. Exposure LimitsThis chemical is classified as a carcinogen. There is no acceptable exposure limit for a carcinogen. This compound is classified as a possible mutagen. There is no acceptable exposure limit for a mutagen. Section IX. Physical and Chemical Properties Liquid. (Clear, yellow.)Solubility Physical state @ 20°CNot available. 0.66 (water=1) (Hexane) Specific Gravity C18H24ClNO2S = 353.91 Molecular WeightPartition CoefficientLOG Pow: 3.9 (Hexane) C6H14 = 86.18 (Hexane) Boiling Point68°C (154.4°F) (Hexane)Vapor Pressure17.6 kPa (@ 20°C) (Hexane) -94°C (-137.2°F) (Hexane)2.97 (Air = 1) (Hexane) Melting PointVapor Density Not available.VolatilityNot available. Refractive Index Not available. Critical TemperatureNot available.Odor ViscosityNot available.TasteNot available. Continued on Next Page Bansyl Chloride (10% in Hexane) Section X.Stability and Reactivity Data This material is stable if stored under proper conditions. (See Section VII for instructions) Stability Conditions of InstabilityAvoid excessive heat and light. Moisture sensitive. Incompatibilities Reactive with oxidizing agents, moisture, chlorine, fluorine, magnesium perchlorate. Section XI. Toxicological Information MN9275000 RTECS Number Routes of ExposureEye Contact. Ingestion. Inhalation. Skin contact. (Hexane) Toxicity Data Rat LD50 (oral) 25 gm/kg Rat LD50 (inhalation) 48000 ppm/4H CARCINOGENIC EFFECTS : Carcinogenic by RTECS criteria. Chronic Toxic Effects MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Tumorigenic effects. (Hexane) Rat TCLo Inhalation 1000 ppm/4H for 59 weeks intermittent TOXIC EFFECTS: Tumorigenic – Carcinogenic by RTECS criteria Tumorigenic Effects – Testicular tumors Mouse TCLo Inhalation 9018 ppm/6H for 2 years intermittent TOXIC EFFECTS: Tumorigenic – Neoplastic by RTECS criteria Liver - Tumors DEVELOPMENTAL TOXICITY: Reproductive effects. (Hexane) Rat TCLo Inhalation 5000 ppm, female 6-19 days of pregnancy TOXIC EFFECTS: Specific Developmental Abnormalities – Musculoskeletal system Specific Developmental Abnormalities – Urogenital system Rat TCLo Inhalation 5000 ppm/20 hours, female 6-19 days of pregnancy TOXIC EFFECTS: Effects on Embryo or Fetus – Fetotoxicity Mouse TCLo Inhalation 5000 ppm, female 6-17 days of pregnancy TOXIC EFFECTS: Effects on Fertility – Post-implantation mortality Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Corrosive to skin, eyes, and respiratory system. Liquid or spray mist may produce tissue damage, particularly in mucous Acute Toxic Effects membranes of the eyes, mouth and respiratory tract. Skin contact may produce burns. Eye contact can result in corneal damage or blindness. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Corrosive materials may cause serious injury if ingested. Harmful if ingested or inhaled. Minimize exposure to this material. Severe overexposure can result in injury or death. Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound. Section XII.Ecological Information Not available. Ecotoxicity Environmental Faten-Hexane's production and use as a pure or commercial grade solvent, as a raw material in the synthesis of polyolefins, elastomers and pharmaceuticals, in the formulation of glues, stains, varnishes and other industrial chemicals may result in its release to the environment through various waste streams. n-Hexane is also a component of natural gas and crude oil. The vast majority of n-hexane is released to the environment through the manufacture, use, and disposal of many products associated with the petroleum industry and the combustion of gasoline. If released to air, a vapor pressure of 153 mm Hg at 25 deg C indicates n-hexane will exist solely as a vapor in the ambient atmosphere. Vapor-phase n-hexane will be degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals; the half-life for this reaction in air is estimated to be 3 days. If released to soil, n-hexane is expected to have high mobility based upon an estimated Koc of 150. Volatilization from moist soil surfaces is expected to be an important fate process based upon an estimated Henry's Law constant of 1.83 atm-cu m/mole. n-Hexane may volatilize from dry soil surfaces based upon its vapor pressure. Screening studies suggest that n-hexane will undergo biodegradation in soil and water surfaces, but volatilization is expected to be the predominant fate process in the environment. If released into water, n-hexane is not expected to adsorb to suspended solids and sediment based upon the estimated Koc. Volatilization from water surfaces is expected to be an important fate process based upon this compound's estimated Henry's Law constant. Estimated volatilization half-lives for a model river and model lake are 1 hour and 3 days, respectively. An estimated BCF of 200 suggests the potential for bioconcentration in aquatic organisms is high. Hydrolysis is not expected to be an important environmental fate process since this compound lacks functional groups that hydrolyze under environmental conditions. Occupational exposure to n-hexane may occur through inhalation and dermal contact with this compound at workplaces where n-hexane is produced or used. Monitoring data indicate that the general population may be exposed to n-hexane via inhalation of ambient air, particularly at urban areas with heavy vehicular traffic or gasoline filling stations. Continued on Next Page Bansyl Chloride (10% in Hexane) Section XIII. Disposal Considerations Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a Waste Disposal combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section XIV. Transport Information DOT ClassificationDOT CLASS 3: Flammable liquid DOT CLASS 8: Corrosive material PIN Number Proper Shipping NameFlammable liquid, corrosive, n.o.s. II Packing Group (PG) DOT Pictograms Section XV. Other Regulatory Information and Pictograms TSCA Chemical InventoryThis product is NOT on the EPA Toxic Substances Control Act (TSCA) inventory. The following notices are required by 40 CFR 720.36 (C) for those products not on the inventory list: (EPA) (i) These products are supplied solely for use in research and development by or under the supervision of a technically qualified individual as defined in 40 CFR 720.0 et sec. (ii) The health risks of these products have not been fully determined. Any information that is or becomes available will be supplied on an MSDS sheet. This compound is ON the EPA Toxic Substances Control Act (TSCA) inventory list. (Hexane) WHMIS ClassificationCLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). CLASS D-2B: Material causing other toxic effects (TOXIC). (Canada) CLASS E: Corrosive liquid. On DSL. (Hexane) EINECS Number (EEC)203-777-6 (Hexane) EEC Risk StatementsR11- Highly flammable. R18- In use, may form flammable/explosive vapor-air mixture. R20/21/22- Harmful by inhalation, in contact with skin and if swallowed. R34- Causes burns. R45- May cause cancer. R46- May cause heritable genetic damage. R47- May cause birth defects. R51- Toxic to aquatic organisms. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 对水是稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统，若无政府许可，勿将材料排入周围环境
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| 危害码 (欧洲) | Xn |
|---|---|
| 风险声明 (欧洲) | 34 |
| 安全声明 (欧洲) | S26-S36/37/39 |
| 危险品运输编码 | 3261 |
| 海关编码 | 2921199090 |
| 海关编码 | 2921199090 |
|---|---|
| 中文概述 | 2921199090 其他无环单胺及其衍生物及其盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |