14640-21-2

• 常用中文名：间四苯基卟吩镁单水合物
• 常用英文名：Magnesium meso-tetraphenylporphine
• CAS号：14640-21-2
• 分子式：C₄₄H₂₈MgN₄
• 分子量：637.02500
• 相关类别： 研究领域 其他
• 发布时间：2018-03-14 08:00:00
• 更新时间：2024-01-05 21:11:23
• meso-四苯基卟啉镁是一种生物化学试剂,可作为生物材料或有机化合物进行生命科学相关研究。

名称

• 中文名: 间四苯基卟吩镁单水合物
• 英文名: magnesium tetraphenylporphyrin
• 中文别名: 5,10,15,20-四苯基卟吩镁; N水四苯基啡洛林镁; 四苯基卟啉镁
• 英文别名: MFCD00049815; Magnesium,[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-(SP-4-1); MAGNESIUM MESO-TETRAPHENYLPORPHYRIN; 5,10,15,20-Tetraphenyl-21H,23H-porphine Magnesium(II); Magnesium(II) meso-Tetraphenylporphine; 5,10,15,20-tetraphenyl-21H,23H-porphine,magnesium complex (1:1); Magnesium meso-Tetraphenylporphine n-hydrate; magnesium tetraphenylporphine; MAGNESIUM MESO-TETRAPHENYLPORPHINE; (5,10,15,20-tetraphenyl-porphinato(2-)-N21,N22,N23,N24)-magnesium; Magnesium TPP; (meso-tetraphenylporphyrinato)magnesium(II); Magnesium meso-te

物化性质

• 分子式: C₄₄H₂₈MgN₄
• 分子量: 637.02500
• 精确质量: 636.21600
• PSA: 34.58000
• LogP: 7.15260
• 外观性状: 固体
• 储存条件:

  常温密闭避光，通风干燥

• 稳定性:

  常温常压下稳定

  避免的物料：氧化物
• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：636.216439 Da

  8、标称质量：636 Da

  9、平均质量：637.0249 Da

• 计算化学:

  1、 疏水参数计算参考值（XlogP）：

  2、 氢键供体数量：2

  3、 氢键受体数量2

  4、 可旋转化学键数量：4

  5、 互变异构体数量：

  6、 拓扑分子极性表面积（TPSA）：29.9

  7、 重原子数量：49

  8、 表面电荷：2

  9、 复杂度：1330

  10、 同位素原子数量：0

  11、 确定原子立构中心数量：0

  12、 不确定原子立构中心数量：0

  13、 确定化学键立构中心数量：4

  14、 不确定化学键立构中心数量：0

  15. 共价键单元数量：2
• 更多:

  1.性状：未确定

  2.密度（g/mL,25/4℃）：未确定

  3.相对蒸汽密度（g/mL,空气=1）：未确定

  4.熔点（ºC）：未确定

  5.沸点（ºC,常压）：未确定

  6.沸点（ºC,5.2kPa）：未确定

  7.折射率：未确定

  8.闪点（ºC）：未确定

  9.比旋光度（º）：未确定

  10.自燃点或引燃温度（ºC）：未确定

  11.蒸气压（kPa,25ºC）：未确定

  12.饱和蒸气压（kPa,60ºC）：未确定

  13.燃烧热（KJ/mol）：未确定

  14.临界温度（ºC）：未确定

  15.临界压力（KPa）：未确定

  16.油水（辛醇/水）分配系数的对数值：未确定

  17.爆炸上限（%,V/V）：未确定

  18.爆炸下限（%,V/V）：未确定

  19.溶解性：未确定

生物活性

• 描述: meso-四苯基卟啉镁是一种生物化学试剂,可作为生物材料或有机化合物进行生命科学相关研究。
• 相关类别:
  研究领域 >> 其他

MSDS

Section 1: Product Identification Chemical Name:Magnesium meso-tetraphenylporphine hydrate CAS Registry Number:14640-21-2 Formula:(C44H28N4)Mg.XH2O EINECS Number:none Chemical Family:metal porphine (porphyrin) complex Synonym:none Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound14640-21-2100%no datano data Section 3: Hazards Identification Emergency Overview:No particular hazard associated with this material. Primary Routes of Exposure:Ingestion Eye Contact:May cause slight to mild irritation of the eyes Skin Contact:May cause slight to mild irritation of the skin. Inhalation:Dust may be irritating to the nose, mucous membranes and respiratory tract. Ingestion:No specific information is available on the physiological effects of ingestion. Acute Health Affects:May be irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:dry chemical, carbon dioxide, or foam. If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Store the material in a tightly sealed container in a cool, dry place. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and clothing. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Respirator:No respirator is required when handling this material. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:purple xtl. Molecular Weight:637.04 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:none Decomposition Products:carbon dioxide, carbon monoxide, magnesium oxide, nitrogen oxides, and organic fumes SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory SARA (Title 313):Title compound not listed Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。

安全

• 危害码 (欧洲): Xn

合成路线

917-23-7 ~% 14640-21-2

文献：Inorganic Chemistry, , vol. 49, # 18 p. 8287 - 8297

100-52-7 ~% 14640-21-2

文献：Inorganic Chemistry, , vol. 52, # 18 p. 10394 - 10406

10002-30-9 107798-98-1 ~% 14640-21-2

文献：Inorganic Chemistry, , vol. 52, # 18 p. 10394 - 10406

上下游产品

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