24140-30-5

• 常用中文名：(S)-(+)-2-甲基丙烯酸[(对甲氧基亚苄基)氨基]肉桂酸酯
• 常用英文名：(S)-(+)-2-DIBENZYLAMINO-3-PHENYL-1-PROPANOL
• CAS号：24140-30-5
• 分子式：C₂₂H₂₅NO₃
• 分子量：351.43900
• 发布时间：2018-11-23 16:12:10
• 更新时间：2024-04-05 18:22:09

名称

• 中文名: (S)-(+)-2-甲基丙烯酸[(对甲氧基亚苄基)氨基]肉桂酸酯
• 英文名: [(2S)-2-methylbutyl] (E)-3-[4-[(4-methoxyphenyl)methylideneamino]phenyl]prop-2-enoate
• 中文别名: (S)-(+)-2-甲基丁基-p-[(p-甲氧基亚苄基)氨基]肉桂酸; (2E)-3-[4-[(E)-[(4-甲氧基苯基)亚甲基]氨基]苯基]-2-丙烯酸 (2S)-2-甲基丁酯
• 英文别名: (+)-2-METHYLBUTYL-4-METHOXYBENZYLIDINE-4'-AMINOCINNAMATE; EINECS 212-594-0; DSSTox_CID_5581; (+)-2-methylbutyl-p<(p-methoxybenzylidene)amino>cinnamate; (+)-2-Methylbutyl-4-methoxybenzyladine-4'-aminocyannate; MFCD03703493

物化性质

• 密度: 1.02g/cm3
• 沸点: 502.9ºC at 760mmHg
• 分子式: C₂₂H₂₅NO₃
• 分子量: 351.43900
• 闪点: 190.8ºC
• 精确质量: 351.18300
• PSA: 47.89000
• LogP: 5.04830
• 外观性状: 浅黄色固体
• 蒸汽压: 3.06E-10mmHg at 25°C
• 折射率: 1.525
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 分子结构:

  1、 摩尔折射率：104.96

  2、 摩尔体积（m³/mol）：341.9

  3、 等张比容（90.2K）：835.3

  4、 表面张力（dyne/cm）：35.6

  5、 极化率（10 ^-24cm ³）：41.61

• 计算化学:

  1、 疏水参数计算参考值（XlogP）：5.2

  2、 氢键供体数量：0

  3、 氢键受体数量：4

  4、 可旋转化学键数量：9

  5、 拓扑分子极性表面积（TPSA）：47.9

  6、 重原子数量：26

  7、 表面电荷：0

  8、 复杂度：458

  9、 同位素原子数量：0

  10、 确定原子立构中心数量：1

  11、 不确定原子立构中心数量：0

  12、 确定化学键立构中心数量：1

  13、 不确定化学键立构中心数量：0

  14、 共价键单元数量：1

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：无可用

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

MSDS

Name: (S)-(+)-2-Methylbutyl p-[(p-methoxybenzylidene)amino]cinnamate 98% Material Safety Data Sheet Synonym: act-Amyl p-anisalaminocinnamate CAS: 24140-30-5 Section 1 - Chemical Product MSDS Name:(S)-(+)-2-Methylbutyl p-[(p-methoxybenzylidene)amino]cinnamate 98% Material Safety Data Sheet Synonym:act-Amyl p-anisalaminocinnamate Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 24140-30-5 act-Amyl p-anisalaminocinnamate 98 unlisted Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. The toxicological properties of this material have not been fully investigated. Skin: May cause skin irritation. The toxicological properties of this material have not been fully investigated. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 24140-30-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Not available. Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 0 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C22H25NO3 Molecular Weight: 351.45 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Excess heat. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 24140-30-5: UD3393000 LD50/LC50: Not available. Carcinogenicity: act-Amyl p-anisalaminocinnamate - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: IMO Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: RID/ADR Shipping Name: Not regulated. Hazard Class: UN Number: Packing group: Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 24140-30-5: No information available. Canada CAS# 24140-30-5 is listed on Canada's NDSL List. CAS# 24140-30-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 24140-30-5 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 通常对水是不危害的，若无政府许可，勿将材料排入周围环境。 CHEMICAL IDENTIFICATION RTECS NUMBER : UD3393000 CHEMICAL NAME : 2-Propenoic acid, 3-(4-(((4-methoxyphenyl)methylene)amino)phenyl)-, 2-methylbutyl ester CAS REGISTRY NUMBER : 24140-30-5 LAST UPDATED : 199701 DATA ITEMS CITED : 2 MOLECULAR FORMULA : C22-H25-N-O3 MOLECULAR WEIGHT : 351.48 HEALTH HAZARD DATA ACUTE TOXICITY DATA MUTATION DATA TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 1 mg/plate REFERENCE : EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 19(Suppl 21),2,1992

安全

• 安全声明 (欧洲): 24/25