42106-48-9

• 常用中文名：2-吗啉苯甲酸
• 常用英文名：2-Morpholinobenzoic Acid
• CAS号：42106-48-9
• 分子式：C₁₁H₁₃NO₃
• 分子量：207.22600
• 发布时间：2018-05-29 08:00:00
• 更新时间：2024-01-12 11:09:41
• 下载msds

名称

• 中文名: 2-(4-吗啉基)苯甲酸
• 英文名: 2-Morpholinobenzoic Acid
• 中文别名: 2-吗啉苯甲酸
• 英文别名: 2-Morpholinobenzoic acid; 2-morpholin-4-ylbenzoic acid

物化性质

• 密度: 1.253g/cm3
• 沸点: 387.5ºC at 760mmHg
• 熔点: 157ºC
• 分子式: C₁₁H₁₃NO₃
• 分子量: 207.22600
• 闪点: 188.2ºC
• 精确质量: 207.09000
• PSA: 49.77000
• LogP: 1.28640
• 折射率: 1.579
• 储存条件: 室温，干燥

MSDS

Name: 2-Morpholinobenzoic acid 97% Material Safety Data Sheet Synonym: CAS: 42106-48-9 Section 1 - Chemical Product MSDS Name:2-Morpholinobenzoic acid 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 42106-48-9 2-Morpholinobenzoic acid 97% unlisted Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 42106-48-9: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white crystalline solid Odor: odorless - slight odor pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 157 - 159 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C11H13NO3 Molecular Weight: 207.23 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, acids, reducing agents, amines. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 42106-48-9 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-Morpholinobenzoic acid - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 42106-48-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 42106-48-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 42106-48-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi
• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): S26-S37/39
• 海关编码: 2934999090

合成路线

192817-79-1 ~90% 42106-48-9

文献：Boehringer Ingelheim Pharma KG Patent: US2003/73836 A1, 2003 ;

110-91-8 445-29-4 ~% 42106-48-9

文献：Pinard, Emmanuel; Alberati, Daniela; Borroni, Edilio; Fischer, Holger; Hainzl, Dominik; Jolidon, Synese; Moreau, Jean-Luc; Narquizian, Robert; Nettekoven, Matthias; Norcross, Roger D.; Stalder, Henri; Thomas, Andrew W. Bioorganic and Medicinal Chemistry Letters, 2008 , vol. 18, # 18 p. 5134 - 5139

110-91-8 88-65-3 ~% 42106-48-9

文献：Lisitsyn,V.N.; Shestakov,V.A. J. Appl. Chem. USSR (Engl. Transl.), 1973 , vol. 46, p. 472 - 474,497 - 499

海关

海关编码	2934999090
中文概述	2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%