61166-05-0

• 常用中文名：9-甲基-3-硝基-9h-咔唑
• 常用英文名：9-METHYL-3-NITRO-9H-CARBAZOLE
• CAS号：61166-05-0
• 分子式：C₁₃H₁₀N₂O₂
• 分子量：226.23100
• 发布时间：2018-06-11 19:30:23
• 更新时间：2024-02-05 20:19:32

名称

• 中文名: 9-甲基-3-硝基-9h-咔唑
• 英文名: 9-methyl-3-nitrocarbazole
• 英文别名: 9H-Carbazole,9-methyl-3-nitro; 9-methyl-3-nitro-carbazole; 3-Nitro-9-methyl-carbazol; 9-Methyl-3-nitro-carbazol; 3-nitro-9-methylcarbazole; 9-Methyl-3-nitro-9H-carbazole

物化性质

• 密度: 1.31g/cm3
• 沸点: 349.1ºC at 760 mmHg
• 熔点: 172ºC
• 分子式: C₁₃H₁₀N₂O₂
• 分子量: 226.23100
• 闪点: 164.9ºC
• 精确质量: 226.07400
• PSA: 50.75000
• LogP: 3.76290
• 折射率: 1.671

MSDS

Name: 9-Methyl-3-nitro-9h-carbazole 97% Material Safety Data Sheet Synonym: CAS: 61166-05-0 Section 1 - Chemical Product MSDS Name:9-Methyl-3-nitro-9h-carbazole 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 61166-05-0 9-Methyl-3-nitro-9H-carbazole 97% unlisted Hazard Symbols: XN Risk Phrases: 68 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Possible risk of irreversible effects. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Possible risk of irreversible effects. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 61166-05-0: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: brown Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 172 - 173.5 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C13H10N2O2 Molecular Weight: 226 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 61166-05-0: FE6270000 LD50/LC50: Not available. Carcinogenicity: 9-Methyl-3-nitro-9H-carbazole - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 68 Possible risk of irreversible effects. Safety Phrases: S 36/37 Wear suitable protective clothing and gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 61166-05-0: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 61166-05-0 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 61166-05-0 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 海关编码: 2933990090

合成路线

1484-12-4 ~86% 61166-05-0

文献：Agarwal, Alka; Agarwal, Shiv K; Bhakuni, D S Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1992 , vol. 31, # 1 p. 44 - 49

1484-12-4 ~73% 61166-05-0 66243-81-0

文献：Chakrabarty; Batabyal Synthetic Communications, 1994 , vol. 24, # 1 p. 1 - 10

86-74-8 ~% 61166-05-0

文献：Deady; Sette Australian Journal of Chemistry, 2001 , vol. 54, # 3 p. 177 - 180

3077-85-8 ~95% 61166-05-0

文献：Deady; Sette Australian Journal of Chemistry, 2001 , vol. 54, # 3 p. 177 - 180

3077-85-8 77-78-1 ~% 61166-05-0

文献：Lindemann Chemische Berichte, 1924 , vol. 57, p. 557 Full Text Show Details Stevens; Tucker Journal of the Chemical Society, 1923 , vol. 123, p. 2147

5393-41-9 ~% 61166-05-0

文献：Stevens; Tucker Journal of the Chemical Society, 1923 , vol. 123, p. 2147

3077-85-8 74-88-4 ~% 61166-05-0

文献：Stevens; Tucker Journal of the Chemical Society, 1923 , vol. 123, p. 2147

1484-12-4 7697-37-2 98-95-3 ~% 61166-05-0

文献：Hoechster Farbw. Patent: DE294016 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 12, p. 909

7647-01-0 1484-12-4 71-43-2 ~% 61166-05-0

文献：Hoechster Farbw. Patent: DE259504 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 11, p. 172

上下游产品

上游产品  10
1484-12-4 86-74-8 3077-85-8 77-78-1
5393-41-9 74-88-4 7697-37-2 98-95-3
7647-01-0 71-43-2
下游产品  3
318-11-6 94127-15-8 61166-04-9

海关

海关编码	2933990090
中文概述	2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期
Summary	2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%