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10102-05-3生产厂家

10102-05-3价格

10102-05-3

10102-05-3结构式
10102-05-3结构式
  • 常用中文名:硝酸钯
  • 常用英文名:Palladium nitrate
  • CAS号:10102-05-3
  • 分子式:N2O6Pd
  • 分子量:230.430
  • 相关类别: 无机化工 无机盐 金属硝酸盐及亚硝酸盐
  • 发布时间:2018-06-20 18:24:29
  • 更新时间:2024-01-02 12:34:15
  • 【用途一】
    用作分析试剂和氧化剂,也用于氯和碘的分离
    【用途二】
    催化剂,合成多种钯化合物和催化剂的原料,大量用来配制钯镀槽液

化源商城直购

中文名 硝酸钯
英文名 Palladium nitrate
英文别名 PaladiumNitrate
PALLADIUM STANDARD SOLUTION
PALLADIUM(II) NITRATE 2 H2O
Palladous nitrate
Palladium(II) nitrate
Palladium(II) nitrate dihydrate
Palladium(II) nitrate solution
MFCD00011169
palladium dinitrate
palladiumdinitrate
Palladium nitrate di
UNII-5G27LBZ05U
EINECS 233-265-8
Pa Nitrate
nitric acid, palladium(2+) salt
Palladium(2+) dinitrate
PALLACIUM(II)NITRATE
密度 1.118 g/mL at 25 °C
沸点 83ºC at 760 mmHg
熔点 >100ºC
分子式 N2O6Pd
分子量 230.430
精确质量 229.879120
PSA 137.76000
LogP 0.56820
外观性状 黄色或橙色棕色液体,酸味
储存条件

储存注意事项 储存于阴凉、通风的库房。远离火种、热源。库温不超过30℃,相对湿度不超过80%。包装密封。应与易(可)燃物、还原剂等分开存放,切忌混储。储区应备有合适的材料收容泄漏物。

稳定性

1.稳定性 稳定

2.禁配物 还原剂、易燃或可燃物、活性金属粉末、硫、磷

3.避免接触的条件 受热

4.聚合危害 不聚合

5.分解产物 氮氧化物

分子结构

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:229.879119 Da

8、标称质量:230 Da

9、平均质量:230.4298 Da

计算化学

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:6

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积126

7.重原子数量:9

8.表面电荷:0

9.复杂度:18.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

更多

1.性状:棕黄色结晶或粉末,有潮解性。

2.熔点(℃):分解

3.相对密度(水=1):1.118

4.溶解性:溶于水,溶于稀硝酸。


Section 1: Product Identification
Chemical Name:Palladium (II) nitrate hydrate(Pd approx. 40%) (99.9%-Pd)
CAS Registry Number:10102-05-3
Formula:Pd(NO3)2.XH2O
EINECS Number:233-265-8
Chemical Family:metal nitrate salts
Synonym:Palladium dinitrate, Nitric acid, palladium (+2) salt

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound10102-05-3100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to eyes, skin and respiratory tract. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion
Eye Contact:Causes slight to mild irritation of the eyes
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: Metal nitrates can be oxidizers. Contact with strong reducing agents could lead to fires and/or explosions.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a tightly sealed container. Keep away from heat and direct sunlight.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:brown xtl.
Molecular Weight:230.72
Melting Point:dec.
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:very soluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Contact with strong reducing agents or organic matter. Some nitrates can explode if heated to high
Conditions to Avoid:
temperatures.
Incompatibility:reducing agents, organic matter, phosphorus and sulfur
Decomposition Products:nitrogen oxides and palladium salts

SECTION 11: Toxicological Information
RTECS Data:Intraperitoneal (rat); DNA inhibition: 56 umol/kg.
Carcinogenic Effects:No data available
Mutagenic Effects:Possible mutagenic effects reported in RTECS
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No data available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Nitrates, Inorganic, N.O.S.
Hazard Class (CFR):5.1
Additional Hazard Class (CFR):NA
Packaging Group (CFR):II
UN ID Number (CFR):UN# 1477
Shipping Name (IATA):Nitrates, Inorganic, N.O.S.
Hazard Class (IATA):5.1
Additional Hazard Class (IATA):NA
Packaging Group (IATA):II
UN ID Number (IATA):UN# 1477

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title Compound: See Category Code N511 for reporting.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

毒理学数据:

1.急性毒性 暂无资料

2.刺激性 暂无资料

生态学数据:

1.生态毒性 暂无资料

2.生物降解性 暂无资料

3.非生物降解性 暂无资料

4.其他有害作用 该物质对环境有危害,应特别注意对水体的污染。

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QV0560000
CHEMICAL NAME :
Nitric acid, palladium(2+) salt
CAS REGISTRY NUMBER :
10102-05-3
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
N2-O6.Pd
MOLECULAR WEIGHT :
230.42

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TEST SYSTEM :
Rodent - rat
DOSE/DURATION :
56 umol/kg
REFERENCE :
EVHPAZ EHP, Environmental Health Perspectives. (U.S. Government Printing Office, Supt of Documents, Washington, DC 20402) No.1- 1972- Volume(issue)/page/year: 12,57,1975 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1001 No. of Facilities: 17 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 140 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - A1001 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1445 (estimated) No. of Female Employees: 230 (estimated)

符号 GHS03 GHS05
GHS03, GHS05
信号词 Danger
危害声明 H272-H314
警示性声明 P210-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338
个人防护装备 Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
危害码 (欧洲) Xi: Irritant;C: Corrosive;O: Oxidizing agent;
风险声明 (欧洲) R34
安全声明 (欧洲) S26-S36/37/39-S45-S17
危险品运输编码 UN 3264 8/PG 2
WGK德国 3
RTECS号 QV0560000
包装等级 II
危险类别 5.1

将金属钯粉或新制备的氢氧化钯加入浓硝酸中,水浴加热。过滤,所得滤液减压蒸馏浓缩后,放入干燥器中冷却结晶。抽滤。产品密封保存。