18746-63-9

• 常用中文名：六氯钌酸铵
• 常用英文名：Diammonium hexachlororuthenate
• CAS号：18746-63-9
• 分子式：H₈Cl₆N₂Ru
• 分子量：349.865
• 相关类别： 无机化工 无机盐 无机铵盐
• 发布时间：2018-08-29 18:49:37
• 更新时间：2024-01-03 07:09:27

• 光谱分析标准。

名称

• 中文名: 氯钌酸铵
• 英文名: ammonium hexachlororuthenate
• 中文别名: 水合六氯代钌铵(IV)
• 英文别名: ruthenium(iv)-ammonium chloride; Diammonium hexachlororuthenate(2-); AMMONIUM HEXACHLORORUTHENATE(IV); Ammonium ruthenium hydrochloride; RutheniuM aMMouiuM chloride; Ruthenate(2-), hexachloro-, ammonium (1:2); MFCD00015962; AMMONIUM CHLORORUTHENATE; Ammonium hexachlororuthenate(IV),(trace metal basis); EINECS 242-552-7; RUTHENIUM AMMONIUM CHLORIDE; Ammoniumhexachlororuthenate(IV); Ammonium chlororuthenzte(IV); Ammonium hexachlororuthenate(IV),Ru min

物化性质

• 分子式: H₈Cl₆N₂Ru
• 分子量: 349.865
• 精确质量: 347.786255
• LogP: 4.88940
• 外观性状: 暗棕色至黑色粉末
• 蒸汽压: 5990mmHg at 25°C
• 储存条件:

  密封阴凉干燥保存。

• 稳定性:

  常温常压下稳定

  避免的物料：水分/潮湿 氧化物
• 计算化学:

  1、 氢键供体数量：2

  2、 氢键受体数量：6

  3、 可旋转化学键数量：0

  4、 拓扑分子极性表面积（TPSA）：2

  5、 重原子数量：9

  6、 表面电荷：0

  7、 复杂度：0

  8、 同位素原子数量：0

  9、 确定原子立构中心数量：0

  10、 不确定原子立构中心数量：0

  11、 确定化学键立构中心数量：0

  12、 不确定化学键立构中心数量：0

  13、 共价键单元数量：9

• 更多:

  1. 性状：棕黑色粉末

  2. 密度（g/mL,25/4℃）：不确定

  3. 相对蒸汽密度（g/mL,空气=1）：不确定

  4. 熔点（ºC）：不确定

  5. 沸点（ºC,常压）：不确定

  6. 沸点（ºC, 5.2kPa）：不确定

  7. 折射率：不确定

  8. 闪点（ºC）：不确定

  9. 比旋光度（º）：不确定

  10. 自燃点或引燃温度（ºC）：不确定

  11. 蒸气压（kPa,25ºC）：不确定

  12. 饱和蒸气压（kPa,60ºC）：不确定

  13. 燃烧热（KJ/mol）：不确定

  14. 临界温度（ºC）：不确定

  15. 临界压力（KPa）：不确定

  16. 油水（辛醇/水）分配系数的对数值：不确定

  17. 爆炸上限（%,V/V）：不确定

  18. 爆炸下限（%,V/V）：不确定

  19. 溶解性：溶于水

MSDS

Name: Ammonium hexachlororuthenate(iv) 99% Material Safety Data Sheet Synonym: Ammonium chlororuthenate; Diammonium hexachlororuthenate; Ruthenate(2-), hexachloro-, diammonium, (OC-6-11) CAS: 18746-63-9 Section 1 - Chemical Product MSDS Name:Ammonium hexachlororuthenate(iv) 99% Material Safety Data Sheet Synonym:Ammonium chlororuthenate; Diammonium hexachlororuthenate; Ruthenate(2-), hexachloro-, diammonium, (OC-6-11) Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 18746-63-9 Ammonium hexachlororuthenate(IV) 99 242-552-7 Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. May cause chemical conjunctivitis. Skin: Causes skin irritation. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation: Causes respiratory tract irritation. Can produce delayed pulmonary edema. Chronic: Effects may be delayed. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Sweep up, then place into a suitable container for disposal. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 18746-63-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: dark brown Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Not available. Solubility in water: Not available. Specific Gravity/Density: Not available. Molecular Formula: H8Cl6N2Ru Molecular Weight: 349.85 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Incompatible materials, excess heat, strong oxidants. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, irritating and toxic fumes and gases, ammonia and/or derivatives, nitrogen. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 18746-63-9 unlisted. LD50/LC50: Not available. Carcinogenicity: Ammonium hexachlororuthenate(IV) - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 18746-63-9: 2 Canada CAS# 18746-63-9 is listed on Canada's NDSL List. CAS# 18746-63-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 18746-63-9 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。

安全

• 符号: GHS06
• 信号词: Danger
• 危害声明: H301-H311-H331
• 警示性声明: P261-P280-P301 + P310-P311
• 个人防护装备: Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
• 危害码 (欧洲): T: Toxic;
• 风险声明 (欧洲): R23/24/25
• 安全声明 (欧洲): S26-S28-S36/37/39-S45
• 危险品运输编码: UN 3288 6.1/PG 3
• WGK德国: 3
• 包装等级: III
• 危险类别: 6.1(b)