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| 中文名 | 二水合溴化钡 |
|---|---|
| 英文名 | Barium Bromide Dihydrate, Puratronic |
| 中文别名 | 溴化钡二水 |
| 英文别名 |
MFCD00149153
barium(2+),dibromide,dihydrate EINECS 234-140-0 |
| 密度 | 3.58 |
|---|---|
| 分子式 | BaBr2H4O2 |
| 分子量 | 333.16600 |
| 精确质量 | 331.76300 |
| PSA | 18.46000 |
| LogP | 1.56260 |
| 外观性状 | 白色结晶粉末 |
| 储存条件 | 1.干性的保护气体下处置， 2.保持贮藏器密封,放入紧密的贮藏器内，储存在阴凉，干燥的地方 |
| 稳定性 | 1.如果遵照规格使用和储存则不会分解 2.避免接触酸，空气，水分/潮湿。溶于水和醇。有毒。有强吸湿性。在100g水中的溶解度为151g（20℃），204g（100℃）。加热结晶时75℃时就失去1分子的结晶水，在150℃时转变为无水物。 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:2 3.氢键受体数量:4 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积2 7.重原子数量:5 8.表面电荷:0 9.复杂度:0 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:5 |
| 更多 | 1. 性状：无色板状结晶，属单斜晶系。 2. 密度（g/mL 25ºC）：3.58 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：880 5. 沸点（ºC，常压）：未确定 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率（n20/D）：1.713 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值（25℃）：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性(mg/mL) ：易溶于水、甲醇。溶于乙醇。不溶于丙酮、醋酸乙酯、二噁烷 |
Synonym:Barium dibromide dihydrate Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed.Hygroscopic (absorbs moisture from the air). Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause kidney, liver and spleen damage. The barium ion is a muscle poison causing stimulation and then paralysis. Initial symptoms are gastrointestinal, including nausea, vomiting, colic, and diarrhea, followed by myocardial and general muscular stimulation with tingling in the extremities. The barium ion is a muscle poison causing stimulation and then paralysis. Initial symptoms are gastrointestinal, including nausea, vomiting, colic, and diarrhea, followed by myocardial and general muscular stimulation with tingling in the extremities. The barium ion is a muscle poison causing stimulation and then paralysis. Initial symptoms are gastrointestinal, including nausea, vomiting, colic, and diarrhea, followed by myocardial and general muscular stimulation with tingling in the extremities. Inhalation: Harmful if inhaled. The toxicological properties of this substance have not been fully investigated. Inhalation of dust may cause respiratory tract irritation. Inhalation at high concentrations may cause CNS depression and asphixiation. Chronic: Inhalation at high concentrations may cause CNS depression and asphixiation. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Institute cardiac monitoring for all significant ingestions of soluble barium salts. Institute cardiac monitoring for all significant ingestions of soluble barium salts. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Substance is noncombustible. Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Wash area with soap and water. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a cool, dry place. Store in a tightly closed container. Store protected from moisture. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits CAS# 7791-28-8: United Kingdom, WEL - TWA: (listed as barium, soluble compounds): mg/m3 TWA (as Ba) United Kingdom, WEL - STEL: (listed as barium, soluble compounds) 1.5 mg/m3 STEL (as Ba) United States OSHA: 0.5 mg/m3 TWA (listed under Barium).0.5 mg/m TWA (as Ba) (listed under Barium, soluble compounds). Belgium - TWA: (listed as barium, soluble compounds): 0.5 mg/m3 V (as Ba) France - VME: (listed as barium, soluble compounds): 0.5 mg/m3 VM (as Ba) Germany: (listed as barium, soluble compounds): 0.5 mg/m3 VME (as Malaysia: (listed as barium, soluble compounds): 0.5 mg/m3 TWA (a Ba) Netherlands: (listed as barium, soluble compounds): 0.5 mg/m3 MAC Ba) Spain: (listed as barium, soluble compounds): 0.5 mg/m3 VLA-ED (a Ba) CAS# 10553-31-8: United Kingdom, WEL - TWA: (listed as barium, soluble compounds): mg/m3 TWA (as Ba) United Kingdom, WEL - STEL: (listed as barium, soluble compounds) 1.5 mg/m3 STEL (as Ba) United States OSHA: 0.5 mg/m3 TWA (as Ba) (listed under Barium, soluble compounds). Belgium - TWA: (listed as barium, soluble compounds): 0.5 mg/m3 V (as Ba) France - VME: (listed as barium, soluble compounds): 0.5 mg/m3 VM (as Ba) Germany: (listed as barium, soluble compounds): 0.5 mg/m3 VME (as Malaysia: (listed as barium, soluble compounds): 0.5 mg/m3 TWA (a Ba) Netherlands: (listed as barium, soluble compounds): 0.5 mg/m3 MAC Ba) Spain: (listed as barium, soluble compounds): 0.5 mg/m3 VLA-ED (a Ba) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Soluble. Specific Gravity/Density: 3.5800g/cm3 Molecular Formula: BaBr2.2H2O Molecular Weight: 333.19 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Not currently available. Conditions to Avoid: Dust generation, moisture. Incompatibilities with Other Materials: Acids. Hazardous Decomposition Products: Barium oxide, hydrogen bromide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 7791-28-8 unlisted. CAS# 10553-31-8 unlisted. LD50/LC50: Not available. Not available. Carcinogenicity: Barium bromide dihydrate - Not listed by ACGIH, IARC, or NTP. Barium bromide, anhydrous - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: BARIUM COMPOUND, N.O.S. Hazard Class: 6.1 UN Number: 1564 Packing Group: III IMO Shipping Name: BARIUM COMPOUND, N.O.S. Hazard Class: 6.1 UN Number: 1564 Packing Group: III RID/ADR Shipping Name: BARIUM COMPOUND, N.O.S. Hazard Class: 6.1 UN Number: 1564 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/22 Harmful by inhalation and if swallowed. Safety Phrases: S 28A After contact with skin, wash immediately with plenty of water. WGK (Water Danger/Protection) CAS# 7791-28-8: 1 CAS# 10553-31-8: No information available. Canada CAS# 10553-31-8 is listed on Canada's NDSL List. CAS# 7791-28-8 is not listed on Canada's Ingredient Disclosure List. CAS# 10553-31-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 7791-28-8 is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form is on the inventory (40CFR720.3(u)(2)). CAS# 10553-31-8 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 对水是稍微危害的，若无政府许可，勿将材料排入周围环境
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