15364-94-0

• 常用中文名：高氯酸锰六水合物
• 常用英文名：manganese (ii) perchlorate
• CAS号：15364-94-0
• 分子式：Cl₂H₁₂MnO₁₄
• 分子量：361.93100
• 相关类别： 无机化工 无机盐 金属卤化物及卤酸盐 金属氯化物及盐
• 发布时间：2018-04-11 08:00:00
• 更新时间：2024-01-06 10:33:26

名称

• 中文名: 高氯酸锰六水合物
• 英文名: Manganese(ii)perchlorate hexahydrate
• 中文别名: 六水高氯酸锰; 六水高氯酸锰(II)
• 英文别名: Manganese(II) perchlorate hexahydrate, Reagent Grade; Manganese(II) perchlorate hexahydrate; MFCD00150255; EINECS 237-390-9

物化性质

• 密度: 2.100
• 熔点: 165ºC
• 分子式: Cl₂H₁₂MnO₁₄
• 分子量: 361.93100
• 精确质量: 360.89800
• PSA: 203.92000
• LogP: 0.04280
• 外观性状: Crystalline Solid | Pink
• 储存条件:

  常温密闭避光，通风干燥

• 稳定性:

  常温常压下稳定

  避免的物料：水分/潮湿 还原剂 易氧化材料 有机材料

• 水溶解性: Soluble in benzene, ethyl acetate | Soluble in water, benzene, ethyl acetate
• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:6

  3.氢键受体数量:14

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积155

  7.重原子数量:17

  8.表面电荷:0

  9.复杂度:95.8

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:9

• 更多:

  1.性状：粉色晶体。吸湿。

  2.密度（g/mL,25/4℃）：2.10

  3.相对蒸汽密度（g/mL,空气=1）：未确定

  4.熔点（ºC）：165

  5.沸点（ºC,常压）：未确定

  6.沸点（ºC,5.2kPa）：未确定

  7.折射率：未确定

  8.闪点（ºC）：未确定

  9.比旋光度（º）：未确定

  10.自燃点或引燃温度（ºC）：未确定

  11.蒸气压（kPa,25ºC）：未确定

  12.饱和蒸气压（kPa,60ºC）：未确定

  13.燃烧热（KJ/mol）：未确定

  14.临界温度（ºC）：未确定

  15.临界压力（KPa）：未确定

  16.油水（辛醇/水）分配系数的对数值：未确定

  17.爆炸上限（%,V/V）：未确定

  18.爆炸下限（%,V/V）：未确定

  19.溶解性：未确定

MSDS

Section 1: Product Identification Chemical Name:Manganese (II) perchlorate hexahydrate, 99% CAS Registry Number:15364-94-0 Formula:Mn(ClO4)2.6H2O EINECS Number:233-108-3 Chemical Family:metal perchlorate salt Synonym:Perchloric acid, Manganese(II) salt, hexahydrate Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound15364-94-0100%0.2mg/m35mg/m3 Section 3: Hazards Identification Irritating to eyes, skin and respiratory tract. Manganese affects the central nervous system. Perchlorates may Emergency Overview: affect thyroid and kidney functions Primary Routes of Exposure:Ingestion Eye Contact:Causes moderate irritation of the eyes. Skin Contact:Causes moderate irritation of the skin. Inhalation:May cause difficulty in breathing and irritate mucous membranes and respiratory tract. Ingestion:No information available on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Prolonged exposure to manganese containing dust may produce manganese pneumonitis and manganese Chronic Health Affects:poisoning. Symptoms include sleepiness, weakness and emotional disturbances. Equivocal studies have shown manganese may decrease fertility in men. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:Water spray Spray closed containers with water until fire is out. Avoid contact with combustible material. Fire fighters Special Fire Fighting Procedures: should be equipped with a NIOSH approved self-contained breathing apparatus. Hazardous Combustion andIf involved in a fire this material may emit corrosive hydrogen chloride fumes. Decomposion Products: Releases oxygen on heating. May decompose explosively under fire fighting conditions. Do not mix with Unusual Fire or Explosion Hazards: combustibles. SECTION 6: Accidental Release Measures Do not mix spilled powder with any combustible materials, such as sawdust. Sweep up the solid and dilute Spill and Leak Procedures: with water. SECTION 7: Handling and Storage Store in a tightly sealed container in a cool dry place away from combustible and flammable materials. If the Handling and Storage: container is left open, salt will adsorb moisture from the atmosphere. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:pink xtl. Molecular Weight:253.84 (361.93) Melting Point:no data Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:Very soluble SECTION 10: Stability and Reactivity Stability:hygroscopic Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:Any contact with combustible matter. Incompatibility:Reducing agents, organic matter, active metals, phosphorus, sulfur, hydrazine, hydroxylamine, strong acids Decomposition Products:Oxygen, Manganese oxide, hydrogen chloride, SECTION 11: Toxicological Information RTECS Data:Intraperitoneal (rat); LD50: 410 mg/kg. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No data available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Perchlorates, Inorganic, N.O.S. Hazard Class (CFR):5.1 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 1481 Shipping Name (IATA):Perchlorates, Inorganic, N.O.S. Hazard Class (IATA):5.1 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 1481 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound: See Category Code N450 for reporting. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。 CHEMICAL IDENTIFICATION RTECS NUMBER : SC9275000 CHEMICAL NAME : Perchloric acid, manganese(2+) salt, hexahydrate CAS REGISTRY NUMBER : 15364-94-0 LAST UPDATED : 199712 DATA ITEMS CITED : 20 MOLECULAR FORMULA : Cl2-O8.Mn.6H2-O MOLECULAR WEIGHT : 361.96 WISWESSER LINE NOTATION : MN G-O4*2 &QH 6 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 410 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 14,512,1966 *** REVIEWS *** ACGIH TLV-TWA 0.2 mg(Mn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:CL 5 mg(Mn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,149,1971 OSHA PEL (Gen Indu):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Mn)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Mn)/m3 JAN 1993 OEL-DENMARK:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-HUNGARY:TWA 0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JAN 1993 OEL-JAPAN:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Mn)/m3 JAN 1993 OEL-POLAND:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-SWEDEN:TWA 1 mg(Mn)/m3;STEL 2.5 mg(Mn)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 2.5 mg(Mn)/m3;STEL 5 mg(Mn)/m3 (total dust) JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Mn)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

安全

• 危害码 (欧洲): O,Xi
• 风险声明 (欧洲): R8
• 安全声明 (欧洲): S15
• 危险品运输编码: UN 1481 5.1/PG 2
• WGK德国: 3
• RTECS号: SC9275000
• 包装等级: II
• 危险类别: 5.1

制备

把过量的（5mL）无水高氯酸在-80℃（用干冰冷却）加到大约2g无水硝酸锰中。此时没有反应发生，缓慢升温至0℃以下开始反应。放置过夜。抽真空除去过量的高氯酸，在110℃，真空下至恒重，得水合高氯酸锰。