90064-46-3

• 常用中文名：1-氯-4-碘-2,5-二甲氧基苯
• 常用英文名：1-Chloro-4-iodo-2,5-dimethoxybenzene
• CAS号：90064-46-3
• 分子式：C₈H₈ClIO₂
• 分子量：298.50500
• 发布时间：2018-12-29 17:29:21
• 更新时间：2024-01-05 17:53:57

名称

• 中文名: 1-氯-4-碘-2,5-二甲氧基苯
• 英文名: 1-Chloro-4-iodo-2,5-dimethoxybenzene
• 英文别名: 1-Chlor-4-jod-2,5-dimethoxy-benzol; 1-chloro-4-iodo-2,5-dimethoxy-benzene; 1-chloro-4-iodo-2,5-dimetoxybenzene; 4-Chloro-2,5-dimethoxyiodobenzene; HMS550H22

物化性质

• 密度: 1.74g/cm3
• 沸点: 324.8ºC at 760mmHg
• 熔点: 115-116ºC
• 分子式: C₈H₈ClIO₂
• 分子量: 298.50500
• 闪点: 150.2ºC
• 精确质量: 297.92600
• PSA: 18.46000
• LogP: 2.96180
• 折射率: 1.584

MSDS

Name: 1-Chloro-4-iodo-2 5-dimethoxybenzene 97% Material Safety Data Sheet Synonym: CAS: 90064-46-3 Section 1 - Chemical Product MSDS Name:1-Chloro-4-iodo-2 5-dimethoxybenzene 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 90064-46-3 1-Chloro-4-iodo-2,5-dimethoxybenzene 97% unlisted Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin.Light sensitive. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 90064-46-3: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: cream Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 115 - 116 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C8H8ClIO2 Molecular Weight: 299 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, light. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide, hydrogen iodide, iodine, acrid smoke and fumes. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 90064-46-3 unlisted. LD50/LC50: Not available. Carcinogenicity: 1-Chloro-4-iodo-2,5-dimethoxybenzene - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 90064-46-3: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 90064-46-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 90064-46-3 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi: Irritant;
• 风险声明 (欧洲): R36/37/38

合成路线

150-78-7 ~58% 51560-21-5 90064-46-3

文献：Wariishi, Koji; Morishima, Sin-Ichi; Inagaki, Yoshio Organic Process Research and Development, 2003 , vol. 7, # 1 p. 98 - 100

150-78-7 ~23% 90064-46-3

文献：Sargent, Thornton; Shulgin, Alexander T.; Mathis, Chester A. Journal of Medicinal Chemistry, 1984 , vol. 27, # 8 p. 1071 - 1077

2100-42-7 ~53% 90064-46-3

文献：Huenig, Siegfried; Bau, Robert; Kemmer, Martina; Meixner, Hubert; Metzenthin, Tobias; et al. European Journal of Organic Chemistry, 1998 , # 2 p. 335 - 348

6358-64-1 ~% 90064-46-3

文献：Posternak et al. Helvetica Chimica Acta, 1948 , vol. 31, p. 525,535

6940-53-0 ~% 90064-46-3

文献：Posternak et al. Helvetica Chimica Acta, 1948 , vol. 31, p. 525,535

615-67-8 ~% 90064-46-3

文献：Posternak et al. Helvetica Chimica Acta, 1948 , vol. 31, p. 525,535

25245-35-6 ~% 90064-46-3

文献：Kauffmann; Fritz Chemische Berichte, 1908 , vol. 41, p. 4424

上下游产品

上游产品  6
150-78-7 2100-42-7 6358-64-1 6940-53-0
615-67-8 25245-35-6
下游产品  3
90064-48-5 7310-97-6 131590-30-2