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| 中文名 | 乙酸铝Al(OH)2(CH3COO).XH3BO3 |
|---|---|
| 英文名 | acetyloxyaluminum,dihydrate |
| 中文别名 | 次乙酸铝 |
| 英文别名 |
MFCD00008688
Aluminum acetate,dibasic EINECS 205-518-2 Dihydroxyaluminum acetate Aluminum Acetate Dibasic |
| 分子式 | C2H5AlO4 |
|---|---|
| 分子量 | 120.04000 |
| 精确质量 | 120.00000 |
| PSA | 66.76000 |
| 外观性状 | 固体 |
| 储存条件 | 密封于阴凉干燥环境。 |
| 稳定性 | 如果遵照规格使用和储存则不会分解。 |
| 分子结构 | 1、摩尔折射率：无可用 2、 摩尔体积（cm3/mol）： 无可用 3、 等张比容（90.2K）：无可用 4、 表面张力（dyne/cm）：无可用 5、 极化率：无可用 |
| 计算化学 | 1、 疏水参数计算参考值（XlogP）：无可用 2、 氢键供体数量：2 3、 氢键受体数量：4 4、 可旋转化学键数量：2 5、 拓扑分子极性表面积（TPSA）：28.3 6、 重原子数量：7 7、 表面电荷：0 8、 复杂度：45 9、 同位素原子数量：0 10、 确定原子立构中心数量：0 11、 不确定原子立构中心数量：0 12、 确定化学键立构中心数量：0 13、 不确定化学键立构中心数量：0 14、 共价键单元数量：3 |
| 更多 | 1. 性状：无可用 2. 密度（g/mL,25/4℃）： 无可用 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：无可用 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）： 无可用 7. 折射率： 无可用 8. 闪点（ºC）： 无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）： 无可用 19. 溶解性：无可用 |
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Section1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE Product identifiers Product name: Aluminum acetate, dibasic CAS-No.: 7360-44-3 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Laboratory chemicals, Manufacture of substances Section2. HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Reproductive toxicity (Category 1B) Classification according to EU Directives 67/548/EEC or 1999/45/EC May impair fertility. May cause harm to the unborn child. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal wordDanger Hazard statement(s) H360FDMay damage fertility. May damage the unborn child. Precautionary statement(s) P201Obtain special instructions before use. P308 + P313IF exposed or concerned: Get medical advice/ attention. Supplemental Hazardnone Statements Restricted to professional users. According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R60May impair fertility. R61May cause harm to the unborn child. S-phrase(s) S53Avoid exposure - obtain special instructions before use. S45In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Restricted to professional users. Other hazards - none Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substances Synonyms: Dihydroxyaluminum acetate Formula: C2H5AlO4 Molecular Weight: 120,04 g/mol ComponentConcentration Boric acid Included in the Candidate List of Substances of Very High Concern (SVHC) according to Regulation (EC) No. 1907/2006 (REACH) CAS-No.10043-35-310 - 20 % EC-No.233-139-2 Index-No.005-007-00-2 Registration number01-2119486683-25-XXXX Section4. FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed Toxicity reported for borates in humans: ingestion or absorption may cause nausea, vomiting, diarrhea, abdominal cramps, anderythematous lesions on the skin and mucous membranes. Other symptoms include: circulatory collapse, tachycardia, cyanosis, delirium, convulsions, and coma. Death has been reported to occur in infants from less than 5 grams and in adults from 5 to 20 grams. Indication of any immediate medical attention and special treatment needed no data available Section5. FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides, Borane/boron oxides, Aluminum oxide Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available Section6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. Section7. HANDLING AND STORAGE Precautions for safe handling Avoid formation of dust and aerosols.Avoid exposure - obtain special instructions before use. Provide appropriate exhaust ventilation at places where dust is formed. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Specific end use(s) no data available Section8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Section9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) AppearanceForm: powder b) Odourno data available c) Odour Thresholdno data available d) pHno data available e) Melting point/freezingno data available point f) Initial boiling point and no data available boiling range g) Flash pointno data available h) Evaporation rateno data available i) Flammability (solid, gas) no data available j) Upper/lowerno data available flammability or explosive limits k) Vapour pressureno data available l) Vapour densityno data available m) Relative densityno data available n) Water solubilityno data available o) Partition coefficient: n- no data available octanol/water p) Auto-ignitionno data available temperature q) Decompositionno data available temperature r) Viscosityno data available s) Explosive propertiesno data available t) Oxidizing propertiesno data available Other safety information no data available Section10. STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Contains the following stabiliser(s): Boric acid (>=12,5 - <=13 %) Possibility of hazardous reactions no data available Conditions to avoid no data available Incompatible materials no data available Hazardous decomposition products Other decomposition products - no data available Section11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity no data available (Aluminum, (acetato-.kappa.O)dihydroxy-) Skin corrosion/irritation no data available (Aluminum, (acetato-.kappa.O)dihydroxy-) Serious eye damage/eye irritation no data available (Aluminum, (acetato-.kappa.O)dihydroxy-) Respiratory or skin sensitization no data available (Aluminum, (acetato-.kappa.O)dihydroxy-) Germ cell mutagenicity no data available (Aluminum, (acetato-.kappa.O)dihydroxy-) Carcinogenicity IARC:No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available (Aluminum, (acetato-.kappa.O)dihydroxy-) Specific target organ toxicity - single exposure no data available (Aluminum, (acetato-.kappa.O)dihydroxy-) Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available (Aluminum, (acetato-.kappa.O)dihydroxy-) Potential health effects InhalationMay be harmful if inhaled. May cause respiratory tract irritation. IngestionMay be harmful if swallowed. SkinMay be harmful if absorbed through skin. May cause skin irritation. EyesMay cause eye irritation. Signs and Symptoms of Exposure Toxicity reported for borates in humans: ingestion or absorption may cause nausea, vomiting, diarrhea, abdominal cramps, anderythematous lesions on the skin and mucous membranes. Other symptoms include: circulatory collapse, tachycardia, cyanosis, delirium, convulsions, and coma. Death has been reported to occur in infants from less than 5 grams and in adults from 5 to 20 grams. Additional Information RTECS: Not available Section12. ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available (Aluminum, (acetato-.kappa.O)dihydroxy-) Results of PBT and vPvB assessment no data available Other adverse effects no data available Section13. DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. Section14. TRANSPORT INFORMATION UN number ADR/RID: -IMDG: -IATA: - UN proper shipping name ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA:Not dangerous goods Transport hazard class(es) ADR/RID: -IMDG: -IATA: - Packaging group ADR/RID: -IMDG: -IATA: - Environmental hazards ADR/RID: noIMDG Marine Pollutant: noIATA: no Special precautions for user no data available SECTION 15 - REGULATORY INFORMATION N/A SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 通常对水是不危害的，若无政府许可，勿将材料排入周围环境。
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| 符号 |
GHS08 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H360FD |
| 警示性声明 | P201-P308 + P313 |
| 危害码 (欧洲) | Xn |
| 风险声明 (欧洲) | 20/21/22-40 |
| 安全声明 (欧洲) | 22-36 |
| 危险品运输编码 | NONH for all modes of transport |
| WGK德国 | 3 |