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| 中文名 | 1,1,2,3,3,3-五氟丙基乙醚 |
|---|---|
| 英文名 | 1,1,1,2,3,3-Hexafluoropropyl ethyl ether |
| 中文别名 | 乙基1,1,2,3,3,3-六氟丙醚 |
| 英文别名 |
MFCD00236122
2-ethoxy-1,1,1,2,3,3-hexafluoropropane |
| 密度 | 1.302g/cm3 |
|---|---|
| 沸点 | 51.6ºC at 760mmHg |
| 分子式 | C5H6F6O |
| 分子量 | 196.09100 |
| 闪点 | -10 °C |
| 精确质量 | 196.03200 |
| PSA | 9.23000 |
| LogP | 2.51610 |
| 外观性状 | 液体;Colorless to Almost colorless clear liquid |
| 折射率 | 1.305 |
| 储存条件 | 室温，干燥 |
|
Ethyl 1,1,2,3,3,3-Hexafluoropropyl Ether
SAFETY DATA SHEET Section1. IDENTIFICATION Product name:Ethyl 1,1,2,3,3,3-Hexafluoropropyl Ether 5.3 Section2. HAZARDS IDENTIFICATION
GHS classification
PHYSICAL HAZARDS Category 2 Flammable liquids HEALTH HAZARDS Category 2 Skin corrosion/irritation Serious eye damage/eye irritationCategory 2A Not classified ENVIRONMENTAL HAZARDS GHS label elements, including precautionary statements Pictograms or hazard symbols Signal wordDanger Hazard statementsHighly flammable liquid and vapour Causes skin irritation Causes serious eye irritation Precautionary statements: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. [Prevention] Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Take precautionary measures against ignition by the static discharge and the spark. Wash hands thoroughly after handling. Wear protective gloves/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, [Response] if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. [Storage]Store in a well-ventilated place. Keep cool. [Disposal]Dispose of contents/container through a waste management company authorized by the local government. Ethyl 1,1,2,3,3,3-Hexafluoropropyl Ether Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture:Substance Components:Ethyl 1,1,2,3,3,3-Hexafluoropropyl Ether Percent:>98.0%(GC) CAS Number:380-34-7 Chemical Formula:C5H6F6O Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion:Get medical advice/attention if you feel unwell. Rinse mouth. A rescuer should wear personal protective equipment, such as rubber gloves and air- Protection of first-aiders: tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, foam, water spray, carbon dioxide. media: Unsuitable extinguishing Solid streams of water media: Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to from the chemical:generate poisonous fume. Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by spraying with water. Eliminate all ignition sources if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Personal precautions,Use personal protective equipment. Keep people away from and upwind of spill/leak. protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled emergency procedures: around the leakage area by roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Absorb spilled material in dry sand or inert absorbent before recovering it into an containment and cleaning airtight container. In case of large amount of spillage, contain a spill by bunding. up: Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations. Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in hazards:case of a fire. Use spark-proof tools and explosion-proof equipment. Section7. HANDLING AND STORAGE Precautions for safe handling Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment. Prevent generation of vapour or mist. Keep away from heat/sparks/open flame/hot surfaces. -No smoking. Take measures to prevent the build up of electrostatic charge. Use explosion-proof equipment. Wash hands and face thoroughly after handling. Use a closed system if possible. Use a ventilation, local exhaust if vapour or aerosol will be generated. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Ethyl 1,1,2,3,3,3-Hexafluoropropyl Ether Section7. HANDLING AND STORAGE Storage conditions:Keep container tightly closed. Store in a cool, dark and well-ventilated place. Store away from incompatible materials such as oxidizing agents. Packaging material:Comply with laws. Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls:Install a closed system or local exhaust. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Vapor respirator. Follow local and national regulations. Hand protection:Protective gloves. Eye protection:Safety glasses. A face-shield, if the situation requires. Skin and body protection: Protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Liquid Form:Clear Colour:Colorless - Very pale yellow Odour:No data available pH: No data available Melting point/freezing point:No data available Boiling point/range:65°C Flash point:No data available Flammability or explosive limits: No data available Lower: Upper:No data available 1.32 Relative density: Solubility(ies): [Water]No data available [Other solvents]No data available Section10. STABILITY AND REACTIVITY Stable under proper conditions. Chemical stability: Possibility of hazardous No special reactivity has been reported. reactions: Conditions to avoid:Spark, Open flame, Static discharge Incompatible materials: Oxidizing agents Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen fluoride products: Section11. TOXICOLOGICAL INFORMATION Acute Toxicity:No data available Skin corrosion/irritation: No data available No data available Serious eye damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: IARC =No data available NTP =No data available Reproductive toxicity:No data available Section12. ECOLOGICAL INFORMATION Ecotoxicity: No data available Fish: Crustacea:No data available No data available Algae: Persistence / degradability: No data available Ethyl 1,1,2,3,3,3-Hexafluoropropyl Ether Section12. ECOLOGICAL INFORMATION BioaccumulativeNo data available potential(BCF): Mobility in soil No data available Log Pow: Soil adsorption (Koc):No data available No data available Henry's Law constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical incinerator equipped with an afterburner and scrubber system but exert extra care in igniting as this material is highly flammable. Observe all federal, state and local regulations when disposing of the substance Section14. TRANSPORT INFORMATION 3: Flammable liquid. Hazards Class: UN-No:3271 Ethers, n.o.s. Proper shipping name: Packing group:II Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | Xi: Irritant; |
|---|---|
| 风险声明 (欧洲) | R11 |
| 安全声明 (欧洲) | 16-26-36 |
| 危险品运输编码 | UN 3271 |
| 危险类别 | 3.0 |
| 海关编码 | 2909199090 |
|
~99%
380-34-7 |
| 文献：Il'in; Bakhmutov; Ivanova; Furin; Tolstikova; Sukhinin Russian Journal of Applied Chemistry, 2004 , vol. 77, # 1 p. 98 - 101 |
|
~%
380-34-7 |
| 文献：Park et al. Journal of the American Chemical Society, 1956 , vol. 78, p. 1685 |
|
~%
380-34-7 |
| 文献：Ishikawa,N.; Takaoka,A. Journal of Fluorine Chemistry, 1984 , vol. 25, p. 203 |
|
~%
380-34-7 |
| 文献：Park et al. Journal of the American Chemical Society, 1956 , vol. 78, p. 1685 |
|
~%
380-34-7 |
| 文献：Haszeldine Journal of the Chemical Society, 1952 , p. 4259,4266 Journal of the Chemical Society, 1953 , p. 3761,3767 |
| 海关编码 | 2909199090 |
|---|---|
| 中文概述 | 2909199090. 其他无环醚及其卤化衍生物（包括磺化，硝化或亚硝化衍生物）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0% |
