55-38-9

55-38-9结构式
55-38-9结构式
  • 常用中文名:倍硫磷
  • 常用英文名:mpp
  • CAS号:55-38-9
  • 分子式:C10H15O3PS2
  • 分子量:278.328
  • 相关类别: 有机原料 有机膦化合物
  • 发布时间:2018-02-07 08:00:00
  • 更新时间:2024-01-03 11:34:32
  • 【用途一】
    一种兼有接触和内吸性的广谱、速效、残效期长的杀虫剂
    【用途二】
    主要用于防治大豆食心虫,棉花、果树、蔬菜和水稻害虫,也可防治卫生害虫
    【用途三】
    广谱、速效、中毒有机磷杀虫剂,对螨类也有效。具触杀、胃毒作用,渗透性较强,有一定的内吸作用,残效期长。可用于水稻、棉花、果树、大豆等作物防治二化螟、三化螟、稻叶蝉、稻苞虫、稻纵卷叶虫、棉红铃虫、棉铃虫、棉蚜、菜青虫、菜蚜、果树食心虫、介壳虫、柑橘锈壁虱、网蝽象、茶毒蛾、茶小绿叶蝉、大豆食心虫及卫生害虫。如防治水稻害虫及棉铃虫、红铃虫,用50%乳油11.3~15mL/100m2对水喷雾;防治棉红蜘蛛、棉蚜、菜青虫、菜蚜等害虫,用50%乳油7.5~11.3mL/100m2对水喷雾;防治棉红蜘蛛、棉蚜、菜青虫、菜蚜等害虫,用50%乳油7.5~11.3mL/100m2对水喷雾;防治大豆食心虫,用50%乳油7.5~11.3mL/100m2,对水喷雾,效果80%以上,或用3%粉剂,225~300kg/100m2喷粉;防治柑橘锈壁虱、网蝽象用50%乳油1000倍液喷雾。
    【用途四】
    倍硫磷是对人、畜低毒的有机磷杀虫剂,对多种害虫有效,主要起触杀的胃毒作用,残效期长,对螨类效果不如甲基对硫磷,主要用于防治大豆食心虫,棉花害虫,果树害虫,蔬菜和水稻害虫,用于防治蚊,蝇,臭虫,虱子,蟑螂也有良好效果。
    【用途五】
    倍硫磷是对人、畜低毒的有机磷杀虫剂,对多种害虫有效,主要起触杀的胃毒作用,残效期长,对螨类效果不如甲基对硫磷,主要由于防治大豆食心虫,棉花害虫,果树害虫,蔬菜和水稻害虫,用于防治蚊虫,蝇,臭虫,虱子,蟑螂也有良好效果。校准仪器和装置;评价方法;工作标准;质量保证/质量控制;其他。

化源商城直购

中文名 倍硫磷
英文名 fenthion
中文别名 O,O-二甲基-O-(3-甲基-4-甲硫基苯基)硫代磷酸酯
百治屠
英文别名 Phosphorothioic acid, O,O-dimethyl O-[3-methyl-4-(methylthio)phenyl] ester
Baytex
Lebaycid
MPP (VAN)
Phenthion
MPP
Mercaptophos
dimethoxy-(3-methyl-4-methylsulfanylphenoxy)-sulfanylidene-λ<sup>5</sup>-phosphane
MFCD00055449
Thiophosphate de O,O-diméthyle et de O-[3-méthyl-4-(méthylsulfanyl)phényle]
O,O-Dimethyl O-[3-methyl-4-(methylsulfanyl)phenyl] phosphorothioate
Fenthione
Phosphorothioic acid, O,O-dimethyl O-[4-(methylthio)-m-tolyl] ester
O,O-dimethyl O-[3-methyl-4-(methylthio)phenyl] phosphorothioate
O,O-dimethyl O-[3-methyl-4-(methylthio)phenyl] thiophosphate
Figuron
Sulfidophos
O,O-dimethyl O-4-methylthio-m-tolyl phosphorothioate
O,O-Dimethyl-O-[3-methyl-4-(methylsulfanyl)phenyl]thiophosphat
Baycid
EINECS 200-231-9
Phosphorothioic Acid O,O-Dimethyl O-[3-Methyl-4-(methylthio)phenyl] Ester
Fenthion
Fenthionon
O,O-Dimethyl O-[4-(Methylthio)-m-tolyl] Phosphorothioate
Fenthion (Baytex)
Bayer S 1752
密度 1.3±0.1 g/cm3
沸点 330.0±52.0 °C at 760 mmHg
熔点 7.5°C
分子式 C10H15O3PS2
分子量 278.328
闪点 153.4±30.7 °C
精确质量 278.020020
PSA 94.89000
LogP 3.21
外观性状 黄色棕色油性液体
蒸汽压 0.0±0.7 mmHg at 25°C
折射率 1.565
储存条件

本品应密封于阴凉处保存。

稳定性

易洛于甲醉、乙醉、甲笨、二甲笨、丙酮、氯化烃、脂肪油等有机洛剂,难洛于石油醚,在水中洛解度为54 - 56mg /L。工业品呈棕黄色,带特殊臭味。对光和热比较稳定,在酸性或碱性介质中水解比甲基对硫磷稳定。在100’时,pH值1 . 8~5介质中,水解半衰期为36h, pH值11介质中,水解半衰期为95mino用过氧化氢或高锰酸钾可使硫醚链氧化,生成相应的亚飒和飒类化合物。

水溶解性 0.0055 g/100 mL
分子结构

五、分子性质数据:

1、 摩尔折射率:72.23

2、 摩尔体积(cm3/mol):221.8

3、 等张比容(90.2K):586.5

4、 表面张力(dyne/cm):48.8

5、 极化率(10-24cm3):28.63

计算化学

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:5

4.可旋转化学键数量:5

5.互变异构体数量:无

6.拓扑分子极性表面积85.1

7.重原子数量:16

8.表面电荷:0

9.复杂度:254

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

更多

1. 性状:棕色液体。微有蒜臭。

2. 密度(g/mL,25/4℃): 1.250

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC): 319

5. 沸点(ºC,常压):87

6. 沸点(ºC,5.2kPa):未确定

7. 折射率:1.5698

8. 闪点(ºC): 未确定

9. 比旋光度(º):未确定

10. 自燃点或引燃温度(ºC):未确定

11. 蒸气压(kPa,25ºC):未确定

12. 饱和蒸气压(kPa,60ºC):未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC):未确定

15. 临界压力(KPa):未确定

16. 油水(辛醇/水)分配系数的对数值:未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V):未确定

19. 溶解性:易溶于甲醇、乙醇、乙醚、丙酮和多种其他有机溶剂,几乎溶于水(55mg/L)

化学品中文名称:
倍硫磷
化学品英文名称:
Baytex
中文名称 2
百治屠
英文名称 2
Fenthion
技术说明书编码:
1900
CAS No.
55-38-9
分子式:
C10H15O3PS2
分子量:
278.33
有害物成分
含量
CAS No.
倍硫磷
55-38-9
危险性类别:
侵入途径:
健康危害:
本品的有机磷中毒症状出现较迟,作用慢,但持续时间长,且症状常出现反复。本品急性中毒后可诱发中间型综合征,主要表现为突触后的神经肌肉接头损伤,罹及呼吸肌,重者可导致呼吸肌麻痹。
环境危害:
对环境有危害,对水体可造成污染。
燃爆危险:
本品可燃,有毒。
皮肤接触:
立即脱去污染的衣着,用肥皂水及流动清水彻底冲洗污染的皮肤、头发、指甲等。就医。
眼睛接触:
提起眼睑,用流动清水或生理盐水冲洗。就医。
吸入:
迅速脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难,给输氧。如呼吸停止,立即进行人工呼吸。就医。
食入:
饮足量温水,催吐。用清水或 2 %~ 5 %碳酸氢钠溶液洗胃。就医。
危险特性:
遇明火、高热可燃。受热分解,放出磷、硫的氧化物等毒性气体。
有害燃烧产物:
一氧化碳、二氧化碳、硫化氢、氧化硫、氧化磷。
灭火方法:
消防人员须佩戴防毒面具、穿全身消防服,在上风向灭火。尽可能将容器从火场移至空旷处。喷水保持火场容器冷却,直至灭火结束。处在火场中的容器若已变色或从安全泄压装置中产生声音,必须马上撤离。灭火剂:雾状水、泡沫、干粉、二氧化碳、砂土。
应急处理:
迅速撤离泄漏污染区人员至安全区,并进行隔离,严格限制出入。切断火源。建议应急处理人员戴自给正压式呼吸器,穿防毒服。尽可能切断泄漏源。防止流入下水道、排洪沟等限制性空间。小量泄漏:用干燥的砂土或类似物质吸收。大量泄漏:构筑围堤或挖坑收容。用泵转移至槽车或专用收集器内,回收或运至废物处理场所处置。
操作注意事项:
密闭操作,局部排风。操作尽可能机械化、自动化。操作人员必须经过专门培训,严格遵守操作规程。建议操作人员佩戴过滤式防毒面具(半面罩),戴化学安全防护眼镜,穿防毒物渗透工作服,戴乳胶手套。远离火种、热源,工作场所严禁吸烟。使用防爆型的通风系统和设备。防止蒸气泄漏到工作场所空气中。避免与氧化剂接触。搬运时要轻装轻卸,防止包装及容器损坏。配备相应品种和数量的消防器材及泄漏应急处理设备。倒空的容器可能残留有害物。
储存注意事项:
储存于阴凉、通风的库房。远离火种、热源。寒冷季节要注意保持库温在结晶点以上,防止冻裂容器及变质。应与氧化剂、食用化学品分开存放,切忌混储。配备相应品种和数量的消防器材。储区应备有泄漏应急处理设备和合适的收容材料。
职业接触限值
中国 MAC(mg/m3)
未制定标准
前苏联 MAC(mg/m3)
0.3[ ]( 推荐值 )
TLVTN
ACGIH 0.2mg/m3( )
TLVWN
未制订标准
监测方法:
溶剂解吸-气相色谱法
工程控制:
密闭操作,局部排风。尽可能机械化、自动化。
呼吸系统防护:
空气中浓度较高时,应该佩戴过滤式防毒面具(半面罩)。紧急事态抢救或逃生时,建议佩戴空气呼吸器。
眼睛防护:
戴化学安全防护眼镜。
身体防护:
穿防毒物渗透工作服。
手防护:
戴乳胶手套。
其他防护:
皮肤防护也可采用塑料薄膜和涂皂面布相结合的方法。工作完毕,淋浴更衣。
主要成分:
纯品
外观与性状:
纯品为无色液体 , 工业品为有轻度蒜臭的褐色油状液体。
pH
熔点 ( )
无资料
沸点 ( )
87( )(0.0013kPa)
相对密度 ( =1)
1.25
相对蒸气密度 ( 空气 =1)
无资料
饱和蒸气压 (kPa)
0.000004(20)
燃烧热 (kJ/mol)
无资料
临界温度 ( )
无资料
临界压力 (MPa)
无资料
辛醇 / 水分配系数的对数值:
无资料
闪点 ( )
无资料
引燃温度 ( )
无资料
爆炸上限 %(V/V)
无资料
爆炸下限 %(V/V)
无资料
溶解性:
不溶于水,易溶于多数有机溶剂。
主要用途:
主要是触杀和胃毒作用 , 用于蔬菜、水稻、豆类、棉花、果树等 , 对于防治卫生害虫也有良效 , 且残效期长 , 常用于疟区灭蚊。
其它理化性质:
稳定性:
禁配物:
强氧化剂。
避免接触的条件:
聚合危害:
分解产物:
急性毒性:
LD50 150 mg/kg( 小鼠经口 ) 150 180 mg/kg( 兔经口 )

LC50
:无资料
亚急性和慢性毒性:
刺激性:
致敏性:
致突变性:
致畸性:
致癌性:
生态毒理毒性:
生物降解性:
非生物降解性:
生物富集或生物积累性:
其它有害作用:
该物质对环境有危害,应特别注意对水体的污染。
废弃物性质:
废弃处置方法:
处置前应参阅国家和地方有关法规。建议用焚烧法处置。焚烧炉排出的气体要通过洗涤器除去。
废弃注意事项:
危险货物编号:
61847
UN 编号:
2783
包装标志:
包装类别:
包装方法:
小开口钢桶;安瓿瓶外普通木箱;螺纹口玻璃瓶、铁盖压口玻璃瓶、塑料瓶或金属桶(罐)外普通木箱;螺纹口玻璃瓶、塑料瓶或镀锡薄钢板桶(罐)外满底板花格箱、纤维板箱或胶合板箱。
运输注意事项:
运输前应先检查包装容器是否完整、密封,运输过程中要确保容器不泄漏、不倒塌、不坠落、不损坏。严禁与酸类、氧化剂、食品及食品添加剂混运。运输时运输车辆应配备相应品种和数量的消防器材及泄漏应急处理设备。运输途中应防曝晒、雨淋,防高温。公路运输时要按规定路线行驶,勿在居民区和人口稠密区停留。
,
法规信息
化学危险物品安全管理条例 (1987 2 17 日国务院发布 ) ,化学危险物品安全管理条例实施细则 ( 化劳发 [1992] 677 ) ,工作场所安全使用化学品规定 ([1996] 劳部发 423 ) 等法规,针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定;常用危险化学品的分类及标志 (GB 13690-92) 将该物质划为第 6.1 类毒害品。
参考文献:
填表时间:
填表部门:
数据审核单位:
修改说明:
其他信息:
MSDS 修改日期:

毒理学数据:

毒性雄性大鼠急性经日LD50为215 mg /kg ,雌性为24Jmg/kg。大鼠急性经皮LD50为330-SOOmg/kg。大鼠60d词喂试验最大允许剂量为10 mg /kg ,用50 mg /kg剂量喂狗1年,其体重和摄食量无影响。对鱼LC50约lmg/L (48h)0对蜜蜂、寄生蜂、草岭(蚜狮)等益虫高毒。

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TF9625000
CHEMICAL NAME :
Phosphorothioic acid, O,O-dimethyl O-(4-(methylthio)-m-tolyl) ester
CAS REGISTRY NUMBER :
55-38-9
LAST UPDATED :
199712
DATA ITEMS CITED :
69
MOLECULAR FORMULA :
C10-H15-O3-P-S2
MOLECULAR WEIGHT :
278.34
WISWESSER LINE NOTATION :
1SR B1 DOPS&O1&O1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - woman
DOSE/DURATION :
1200 uL/kg
TOXIC EFFECTS :
Behavioral - coma Cardiac - pulse rate Gastrointestinal - hypermotility, diarrhea
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
643 uL/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - fasciculations Behavioral - ataxia Cardiac - pulse rate
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
257 mg/kg
TOXIC EFFECTS :
Cardiac - pulse rate increase, without fall in BP Gastrointestinal - hypermotility, diarrhea Gastrointestinal - nausea or vomiting
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - woman
DOSE/DURATION :
525 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - miosis (pupillary constriction) Behavioral - muscle contraction or spasticity Lungs, Thorax, or Respiration - respiratory depression
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Human
DOSE/DURATION :
50 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
800 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
330 mg/kg
TOXIC EFFECTS :
Behavioral - tremor Behavioral - convulsions or effect on seizure threshold Behavioral - excitement
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
260 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
88100 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1 gm/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
125 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
144 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
320 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intracerebral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
50 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intramuscular
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
40 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
150 mg/kg
TOXIC EFFECTS :
Behavioral - muscle weakness Gastrointestinal - changes in structure or function of salivary glands Kidney, Ureter, Bladder - other changes
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
1 gm/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
260 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
1 gm/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
310 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - pigeon
DOSE/DURATION :
1780 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - chicken
DOSE/DURATION :
20 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Bird - chicken
DOSE/DURATION :
20 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
11 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
5900 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
44 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intramuscular
SPECIES OBSERVED :
Mammal - domestic
DOSE/DURATION :
46 mg/kg
TOXIC EFFECTS :
Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - reactivates cholinesterase
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
105 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - food intake (animal) Behavioral - muscle contraction or spasticity
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intramuscular
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
46200 ug/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - food intake (animal) Behavioral - muscle contraction or spasticity
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - wild bird species
DOSE/DURATION :
1300 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
172 mg/kg/6D-I
TOXIC EFFECTS :
Peripheral Nerve and Sensation - structural change in nerve or sheath Blood - changes in bone marrow (not otherwise specified) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
380 mg/kg/19D-I
TOXIC EFFECTS :
Brain and Coverings - other degenerative changes Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3225 mg/kg/43W-I
TOXIC EFFECTS :
Brain and Coverings - other degenerative changes
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
365 mg/kg/5D-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1200 mg/kg/60D-C
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5200 mg/kg/1Y-I
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - retinal changes (pigmentary depositions, retinitis, other) Liver - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
260 mg/kg/13W-I
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - retinal changes (pigmentary depositions, retinitis, other)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Bird - chicken
DOSE/DURATION :
35 mg/kg/7D-I
TOXIC EFFECTS :
Behavioral - ataxia Nutritional and Gross Metabolic - weight loss or decreased weight gain Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other esterases
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - domestic
DOSE/DURATION :
7500 ug/kg/5D-C
TOXIC EFFECTS :
Behavioral - food intake (animal) Nutritional and Gross Metabolic - weight loss or decreased weight gain Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1730 mg/kg/103W-C
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Skin and Appendages - tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
1050 mg/kg
SEX/DURATION :
multigenerations
TOXIC EFFECTS :
Reproductive - Fertility - female fertility index (e.g. # females pregnant per # sperm positive females; # females pregnant per # females mated) Reproductive - Effects on Newborn - viability index (e.g., # alive at day 4 per # born alive) Reproductive - Effects on Newborn - weaning or lactation index (e.g., # alive at weaning per # alive at day 4)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
40 mg/kg
SEX/DURATION :
female 11 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue) Reproductive - Specific Developmental Abnormalities - musculoskeletal system

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Lung
DOSE/DURATION :
40 mg/L
REFERENCE :
ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 4,621,1982 *** REVIEWS *** ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 0.2 mg/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 TOXICOLOGY REVIEW RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 46,1,1973 TOXICOLOGY REVIEW CNDQA8 Cahiers de Nutrition et de Dietetique. (Editions Meteore, 42, rue du Louvre, 75001 Paris, France) V.1- 1966- Volume(issue)/page/year: 10(3),43,1975 TOXICOLOGY REVIEW RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 63,1,1976 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.2 mg/m3;Skin JAN 1993 OEL-BELGIUM:TWA 0.2 mg/m3;Skin JAN 1993 OEL-DENMARK:TWA 0.1 mg/m3;Skin JAN 1993 OEL-GERMANY:TWA 0.2 mg/m3;Skin JAN 1993 OEL-JAPAN:TWA 0.2 mg/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg/m3;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X9267 No. of Facilities: 221 (estimated) No. of Industries: 4 No. of Occupations: 6 No. of Employees: 2142 (estimated) No. of Female Employees: 442 (estimated)

符号 GHS06 GHS08 GHS09
GHS06, GHS08, GHS09
信号词 Danger
危害声明 H302 + H312-H331-H341-H372-H410
警示性声明 P261-P273-P280-P311-P501
个人防护装备 Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
危害码 (欧洲) T:Toxic;N:Dangerousfortheenvironment;
风险声明 (欧洲) R21/22;R23;R48/25;R50/53;R68
安全声明 (欧洲) S36/37-S45-S60-S61-S62
危险品运输编码 UN 2810/3017
RTECS号 TF9625000
包装等级 III
危险类别 6.1(b)
海关编码 2930909066
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由间甲酚与二甲基二硫反应制备中间体对甲硫基间甲酚,再与O,O-二甲基硫代磷酰氯反应得到倍硫磷。
1.对甲硫基间甲酚的制备将间甲酚(或混甲酚);二甲基二硫按2:1(重量比)配料,加入反应锅,搅拌冷却至10-15℃,开始滴加浓硫酸。在1h左右滴完(用量与二甲基二硫等重量),在10-15℃继续反应3h。静置分层,弃去下层废酸。有机层用10%碳酸钠溶液中和,再用水洗涤于pH7-8。减压蒸馏回收未反应的二甲基二硫和甲酚,所剩物料即中间体对甲硫基间甲酚。
2.倍硫磷的制备将20%的氢氧化钠溶液加入反应锅,搅拌冷却至25℃以下,投入上述制备的中间体,然后在10-20℃均匀滴加O,O-二甲基硫代磷酰氯,约30-40min滴完,三种物料的投料量按摩尔比为1.3:1:1.2。缓缓升温到60℃,保温2h,反应过程中检查pH变化情况,当pH<9时,应补加氢氧化钠溶液。反应结束后,降温至45℃,加氢氧化钠溶液洗涤,再用水洗涤,静置分层。取下层有机层减压脱水,冷却,过滤,得倍硫磷原油,含量90%,收率90%。

海关编码 2930909066
中文概述 2930909066 倍硫磷、甲基内吸磷、乙酯磷等〔包括丰索磷、内吸磷、发硫磷〕 退税率:9.0% 监管条件:S(进出口农药登记证明)
申报要素 品名, 成分含量, 用途
监管条件 S.进出口农药登记证明
Summary 2930909066 o,o-diethyl s-(2-(isopropylamino)-2-oxoethyl) phosphorodithioate