4497-04-5

• 常用中文名：3-(4-吗啉基)丙酸
• 常用英文名：4-Morpholinepropionic acid
• CAS号：4497-04-5
• 分子式：C₇H₁₃NO₃
• 分子量：159.183
• 相关类别： 化学试剂 有机试剂 芳香酸
• 发布时间：2018-07-17 10:47:47
• 更新时间：2024-01-02 20:03:53

名称

• 中文名: 3-(4-吗啉基)丙酸
• 英文名: 3-Morpholin-4-yl-propionic acid
• 中文别名: 4-吗啉丙酸
• 英文别名: 3-(4-Morpholinyl)propanoic acid; 3-(morpholin-4-yl)propanoic acid; 4-Morpholinepropanoic acid; 3-Morpholinopropanoic acid; 3-morpholin-4-ylpropanoic acid; 4-Morpholinepropionic acid; MFCD02089311

物化性质

• 密度: 1.2±0.1 g/cm3
• 沸点: 299.2±25.0 °C at 760 mmHg
• 分子式: C₇H₁₃NO₃
• 分子量: 159.183
• 闪点: 134.8±23.2 °C
• 精确质量: 159.089539
• PSA: 49.77000
• LogP: -0.52
• 蒸汽压: 0.0±1.3 mmHg at 25°C
• 折射率: 1.482
• 储存条件: 室温，干燥密封

MSDS

Name: 3-Morpholinopropanoic Acid Hydrobromic Salt Material Safety Data Sheet Synonym: None known CAS: 4497-04-5 Section 1 - Chemical Product MSDS Name:3-Morpholinopropanoic Acid Hydrobromic Salt Material Safety Data Sheet Synonym:None known Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 4497-04-5 3-Morpholinopropanoic Acid Hydrobromic ca 100 unlisted Hazard Symbols: XI Risk Phrases: 36/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes and skin.The toxicological properties of this material have not been fully investigated.Hygroscopic (absorbs moisture from the air). Potential Health Effects Eye: Causes eye irritation. May cause chemical conjunctivitis. Skin: Causes skin irritation. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: Effects may be delayed. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 4497-04-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: white Odor: none reported pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 190-194C Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C7H13NO3HBr Molecular Weight: 240.0069 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Incompatible materials, dust generation, excess heat, exposure to moist air or water. Incompatibilities with Other Materials: Moisture, strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 4497-04-5 unlisted. LD50/LC50: Not available. Carcinogenicity: 3-Morpholinopropanoic Acid Hydrobromic Salt - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/38 Irritating to eyes and skin. Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 4497-04-5: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 4497-04-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 4497-04-5 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi
• 海关编码: 2934999090

合成路线

33611-43-7 ~89% 4497-04-5

文献：US6184225 B2, ;

110-91-8 292638-85-8 ~80% 4497-04-5

文献：Russian Chemical Bulletin, , vol. 47, # 9 p. 1732 - 1735

110-91-8 57-57-8 ~% 4497-04-5

文献：US2526558 , ; Journal of the American Chemical Society, , vol. 73, p. 3168,3171

62131-51-5 ~% 4497-04-5 108-95-2

文献：Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, , vol. 21, # 5 p. 515 - 516

上下游产品

上游产品  5
33611-43-7 110-91-8 292638-85-8 57-57-8
62131-51-5
下游产品  0

海关

海关编码	2934999090
中文概述	2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%