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| 中文名 | 异丙氧基铁(III) |
|---|---|
| 英文名 | iron(3+),propan-2-olate |
| 中文别名 | 异丙氧铁 |
| 英文别名 |
Ferric triisopropoxide
Ferricisopropoxide Iron triisopropoxide MFCD00070436 |
| 密度 | 0.79 |
|---|---|
| 沸点 | 82℃ |
| 分子式 | C9H21FeO3 |
| 分子量 | 233.10600 |
| 闪点 | 12°(54°F) |
| 精确质量 | 233.08400 |
| PSA | 27.69000 |
| LogP | 2.62460 |
| 外观性状 | solid | brown to black |
| 储存条件 | 密闭于阴凉干燥环境中 |
| 稳定性 | 遵照规定使用和储存则不会分解。 |
| 水溶解性 | It hydrolyzes with water. |
| 分子结构 | 1、摩尔折射率：无可用 2、 摩尔体积（cm3/mol）：无可用 3、 等张比容（90.2K）：无可用 4、 表面张力（dyne/cm）：无可用 5、 极化率：无可用 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:3 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积69.2 7.重原子数量:13 8.表面电荷:0 9.复杂度:10.8 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:4 |
| 更多 | 1. 性状：无可用 2. 密度（g/mL,25/4℃）：无可用 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：无可用 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：无可用 |
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Section 1: Product Identification Chemical Name:Iron (III) i-propoxide (99.9+%-Fe) CAS Registry Number:14995-22-3 Formula:Fe(OC3H7)3 EINECS Number:None Chemical Family:metal alkoxide Synonym:Ferric propoxide, Iron propylate
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound14995-22-3100%1 mg/m3 (Sol Fe)no data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. Primary Routes of Exposure:Ingestion, skin, inhalation, eyes Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes irritation, redness, and pain to skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Prolonged ingestion may lead to damage to the liver and pancreas. Prolonged inhalation of dusts may cause Chronic Health Affects: pulmonary fibrosis. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:53°F(2-propanol) Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, water, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: Contact with moisture will produce flammable isopropanol SECTION 6: Accidental Release Measures Remove sources of ignition. Small spills can be mixed with vermiculite, sodium carbonate or other suitable non Spill and Leak Procedures: combustible adsorbent and swept up. SECTION 7: Handling and Storage Keep material in a tightly sealed container in a cool dry place. Prolonged exposure to the moist air will result in Handling and Storage: degradation of the product. Handle and store material under a dry atmosphere. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:brown to black solid Molecular Weight:233.12 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:slight alcohol odor Solubility in Water:hydrolyzes in water SECTION 10: Stability and Reactivity Stability:moisture sensitive Hazardous Polymerization:no hazardous polymerization Prolonged contact with air or moisture. Keep away from heat and ignition sources including open flame and Conditions to Avoid: electrostatic discharge. Incompatibility:Oxidizing agents, halogens and active metals Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, and iron oxide SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。
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| 危害码 (欧洲) | F+ |
|---|---|
| 危险品运输编码 | UN3180 |
| 包装等级 | III |
| 危险类别 | 4.1 |