中文名 | 3-甲基-5-苯基-4-异噁唑甲醛 |
---|---|
英文名 | 3-methyl-5-phenyl-1,2-oxazole-4-carbaldehyde |
英文别名 |
3-Methyl-5-phenyl-isoxazol-4-carbaldehyd
3-methyl-5-phenyl-4-isoxazolecarbaldehyde 3-methyl-4-formyl-5-phenyl-1,2-oxazole 4-formyl-3-methyl-5-phenylisoxazole 4-Isoxazolecarboxaldehyde,3-methyl-5-phenyl 3-methyl-5-phenylisoxazole-4-carbaldehyde |
密度 | 1.179g/cm3 |
---|---|
沸点 | 357.2ºC at 760 mmHg |
熔点 | 85ºC |
分子式 | C11H9NO2 |
分子量 | 187.19500 |
闪点 | 169.8ºC |
精确质量 | 187.06300 |
PSA | 43.10000 |
LogP | 2.46250 |
折射率 | 1.58 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Not available. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Store under nitrogen. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 89479-66-3: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Needles Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 89 - 90 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C11H9NO2 Molecular Weight: 187.2 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents, reducing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 89479-66-3 unlisted. LD50/LC50: Not available. Carcinogenicity: 3-Methyl-5-phenyl-4-isoxazolecarbaldehyde - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 89479-66-3: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 89479-66-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 89479-66-3 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
危害码 (欧洲) | Xi: Irritant; |
---|---|
安全声明 (欧洲) | 24/25 |
海关编码 | 2934999090 |
~56% 89479-66-3 |
文献:Green, Jeremy; Bemis, Guy; Grillot, Anne-Laure; Ledeboer, Mark; Salituro, Francesco G.; Harrington, Edmund; Gao, Huai; Baker, Christopher; Cao, Jingrong; Hale, Michael Patent: US2003/149051 A1, 2003 ; |
~68% 89479-66-3 |
文献:Heck, Reinhard; Ofenloch, Roland; Wolf, Roland Synthesis, 1990 , # 1 p. 62 - 64 |
~% 89479-66-3 |
文献:Synthesis, , # 1 p. 62 - 64 |
~36% 89479-66-3 |
文献:Alberola, Angel; Calvo, Luis; Rodriguez, M. Teresa Rodriguez; Sanudo, M. Carmen Journal of Heterocyclic Chemistry, 1995 , vol. 32, # 2 p. 537 - 542 |
~% 89479-66-3 |
文献:Journal of Heterocyclic Chemistry, , vol. 20, p. 1505 - 1507 |
上游产品 7 | |
---|---|
下游产品 1 | |
海关编码 | 2934999090 |
---|---|
中文概述 | 2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0% |
申报要素 | 品名, 成分含量, 用途 |
Summary | 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |