89353-42-4

• 常用中文名：3-(1H-吡咯-1-基)苯胺
• 常用英文名：3-(1H-Pyrrol-1-yl)aniline
• CAS号：89353-42-4
• 分子式：C₁₀H₁₀N₂
• 分子量：158.200
• 发布时间：2018-07-26 12:04:35
• 更新时间：2024-01-09 19:10:13

名称

• 中文名: 3-(1H-吡咯-1-基)苯胺
• 英文名: 3-pyrrol-1-ylaniline
• 英文别名: MFCD03407309; 3-(1-pyrrolyl)aniline; 1-(3-aminophenyl)pyrrole; 1-(3-aminophenyl)-1H-pyrrole; 3-(pyrrol-1-yl)aniline; 3-(1H-Pyrrol-1-yl)aniline; Benzenamine, 3-(1H-pyrrol-1-yl)-; 3-pyrrolylphenylamine; 3-Pyrrol-1-yl-phenylamine

物化性质

• 密度: 1.1±0.1 g/cm3
• 沸点: 323.4±25.0 °C at 760 mmHg
• 熔点: 43-44ºC
• 分子式: C₁₀H₁₀N₂
• 分子量: 158.200
• 闪点: 149.4±23.2 °C
• 精确质量: 158.084396
• PSA: 30.95000
• LogP: 1.80
• 蒸汽压: 0.0±0.7 mmHg at 25°C
• 折射率: 1.602

MSDS

Name: 3-(1H-Pyrrol-1-yl)aniline 97% Material Safety Data Sheet Synonym: CAS: 89353-42-4 Section 1 - Chemical Product MSDS Name:3-(1H-Pyrrol-1-yl)aniline 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 89353-42-4 3-(1H-Pyrrol-1-yl)aniline unlisted Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 89353-42-4: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Not available. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: beige Odor: mild odor - faint odor pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 43 - 45 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C10H10N2 Molecular Weight: 158.2 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 89353-42-4 unlisted. LD50/LC50: Not available. Carcinogenicity: 3-(1H-Pyrrol-1-yl)aniline - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 89353-42-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 89353-42-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 89353-42-4 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi: Irritant;
• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): 26-36/37/39-37/39
• 海关编码: 2933990090

合成路线

696-59-3 108-45-2 ~64% 89353-42-4

文献：Zhang, Xingxian; Shi, Junchen Tetrahedron, 2011 , vol. 67, # 5 p. 898 - 903

109-97-7 626-01-7 ~89% 89353-42-4

文献：Ma, Heng-Chang; Jiang, Xuan-Zhen Journal of Organic Chemistry, 2007 , vol. 72, # 23 p. 8943 - 8946

4310-42-3 ~49% 89353-42-4

文献：Corelli; Massa; Stefancich; Artico; Panico; Simonetti Farmaco, Edizione Scientifica, 1984 , vol. 39, # 2 p. 95 - 109

99-09-2 ~% 89353-42-4

文献：Farmaco, Edizione Scientifica, , vol. 39, # 2 p. 95 - 109

696-59-3 108-45-2 ~27% 1196796-10-7 89353-42-4

文献：Asian Journal of Chemistry, , vol. 25, # 1 p. 501 - 504

上下游产品

上游产品  6
696-59-3 108-45-2 109-97-7 626-01-7
4310-42-3 99-09-2
下游产品  2
89353-40-2 89353-45-7

海关

海关编码	2933990090
中文概述	2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期
Summary	2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%