52768-17-9

• 常用中文名：4-(1-吡咯基)苯胺
• 常用英文名：4-(1-Pyrrolyl)aniline
• CAS号：52768-17-9
• 分子式：C₁₀H₁₀N₂
• 分子量：158.20000
• 发布时间：2018-09-20 09:47:42
• 更新时间：2024-01-08 09:14:47

名称

• 中文名: 4-(1-吡咯基)苯胺
• 英文名: 4-(1H-Pyrrol-1-yl)aniline
• 中文别名: 4-(1H-吡络）苯胺
• 英文别名: 4-pyrrol-1-ylaniline; 4-(1-Pyrrolyl)aniline

物化性质

• 密度: 1.09g/cm3
• 沸点: 307.8ºC at 760 mmHg
• 熔点: 81ºC
• 分子式: C₁₀H₁₀N₂
• 分子量: 158.20000
• 闪点: 140ºC
• 精确质量: 158.08400
• PSA: 30.95000
• LogP: 2.64070
• 折射率: 1.602
• 储存条件: 室温，干燥

MSDS

Name: 4-(1h-pyrrol-1-yl)aniline 97% Material Safety Data Sheet Synonym: 1-(4-Aminbophenyl)pyrrol CAS: 52768-17-9 Section 1 - Chemical Product MSDS Name:4-(1h-pyrrol-1-yl)aniline 97% Material Safety Data Sheet Synonym:1-(4-Aminbophenyl)pyrrol Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 52768-17-9 4-(1H-Pyrrol-1-yl)aniline 97% unlisted Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Not available. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 52768-17-9: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 80.7 - 81.2 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C10H10N2 Molecular Weight: 158.2 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 52768-17-9 unlisted. LD50/LC50: Not available. Carcinogenicity: 4-(1H-Pyrrol-1-yl)aniline - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 52768-17-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 52768-17-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 52768-17-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi
• 风险声明 (欧洲): 36/37/38
• 安全声明 (欧洲): S24/25
• 海关编码: 2933990090

合成路线

696-59-3 106-50-3 ~95% 52768-17-9

文献：Ma, Fei-Ping; Li, Pei-He; Li, Bao-Le; Mo, Li-Ping; Liu, Ning; Kang, Hui-Jun; Liu, Ya-Nan; Zhang, Zhan-Hui Applied Catalysis A: General, 2013 , vol. 457, p. 34 - 41

109-97-7 106-40-1 ~72% 52768-17-9

文献：Panda, Niranjan; Jena, Ashis Kumar; Mohapatra, Sasmita; Rout, Smruti Ranjan Tetrahedron Letters, 2011 , vol. 52, # 16 p. 1924 - 1927

109-97-7 540-37-4 ~10% 52768-17-9

文献：Ma, Heng-Chang; Jiang, Xuan-Zhen Journal of Organic Chemistry, 2007 , vol. 72, # 23 p. 8943 - 8946

5044-38-2 ~88% 52768-17-9

文献：Lundgren, Rylan J.; Peters, Brendan D.; Alsabeh, Pamela G.; Stradiotto, Mark Angewandte Chemie - International Edition, 2010 , vol. 49, # 24 p. 4071 - 4074

4533-42-0 ~44% 52768-17-9

文献：Bach; Beyer; Gelbrich; Hallmeier; Hennig; Moebius; Richter; Szargan; Fernandez; Losada Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1996 , vol. 51, # 6 p. 757 - 764

5044-38-2 ~% 52768-17-9 258354-47-1

文献：Cheung, Chi Wai; Surry, David S.; Buchwald, Stephen L. Organic Letters, 2013 , vol. 15, # 14 p. 3734 - 3737

635-90-5 ~% 52768-17-9

文献：Dhont; Wibaut Recueil des Travaux Chimiques des Pays-Bas, 1943 , vol. 62, p. 177,181, 183

上下游产品

上游产品  8
696-59-3 106-50-3 109-97-7 106-40-1
540-37-4 5044-38-2 4533-42-0 635-90-5
下游产品  1
85754-51-4

海关

海关编码	2933990090
中文概述	2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期
Summary	2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%