126949-63-1

• 常用中文名：2,6-二异丙基苯基亚氨基新芽孢杆菌钼(VI)双(三氟甲磺酸盐)二甲氧基乙烷加合物
• 常用英文名：2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM (VI) BIS(TRIFLUOROMETHANESULFONATE)DIMETHOXYETHANE ADDUCT
• CAS号：126949-63-1
• 分子式：C₂₈H₃₉F₆MoNO₈S₂
• 分子量：791.69200
• 发布时间：2016-07-01 03:36:59
• 更新时间：2024-04-07 16:33:41

名称

• 中文名: 2,6-二异丙基苯基亚氨基新芽孢杆菌钼(VI)双(三氟甲磺酸盐)二甲氧基乙烷加合物
• 英文名: 1,2-dimethoxyethane,[2,6-di(propan-2-yl)phenyl]imino-(2-methyl-2-phenylpropylidene)molybdenum(2+),trifluoromethanesulfonate
• 英文别名: 2,6-diisopropylphenylimido neophylidenemolybdenum(vi) bis(trifluoromethanesulfonate)dimethoxyethane adduct; 2,5-dihydro-furan-2-carboxylic acid

物化性质

• 分子式: C₂₈H₃₉F₆MoNO₈S₂
• 分子量: 791.69200
• 精确质量: 793.10800
• PSA: 161.98000
• LogP: 9.15710
• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：793.107533 Da

  8、标称质量：793 Da

  9、平均质量：791.6716 Da

• 更多:

  1. 性状：未确定

  2. 密度（g/mL,20℃）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,KPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（Pa,20ºC）：未确定

  12. 饱和蒸气压（KPa,20ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

Section 1: Product Identification 2,6-Diisopropylphenylimido neophylidenemolybdenum (VI) bis(trifluoromethanesulfonate)dimethoxyethane Chemical Name: adduct CAS Registry Number:126949-63-1 Formula:Mo(C10H12)(C12H17N)(OSO2CF3)2(C4H10O2) EINECS Number:none Chemical Family:organometallic complexes Synonym:none Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound126949-63-1100%10mg/m3 (as Mo)15mg/m3 (as Mo) Section 3: Hazards Identification Severe irritant to skin and eyes. Material hydrolyzes in contact with moisture releasing aqueous Emergency Overview: trifluoromethane sulfonic acid. Primary Routes of Exposure:Ingestion, inhalation, skin, eyes Eye Contact:A severe irritant to the eyes. Skin Contact:Causes severe irritation of the skin causing redness, pain, itching, pimples, boils, hives and blisters. Inhalation:Inhalation of vapors will lead to irritation of the respiratory tract. Ingestion:Severe irritation of the Gastrointestinal system may occur. Acute Health Affects:Irritating to skin, eyes and respiratory tract. May cause dyspnea (breathing difficulty), and pulmonary edema. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, foam or dry powder If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andThis material may emit toxic organic fumes and hydrogen fluoride, carbonyl fluoride, and sulfur dioxide. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be neutralized with sodium carbonate, sodium bicarbonate or lime. The solids can then be Spill and Leak Procedures: swept up and properly disposed of. SECTION 7: Handling and Storage Store material under argon in a tightly sealed bottle away from air and moisture. If possible, handle material in Handling and Storage: an efficient fume hood. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and protective clothing. Ventilation:If possible, handle the material in an efficient fume hood. In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a Respirator: Respirator Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:yellow to orange pwdr. Molecular Weight:791.68 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:reacts with water SECTION 10: Stability and Reactivity Stability:air sensitive, moisture sensitive (store cold) Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:Contact with air or moisture. Incompatibility:oxidizing agents and halogens Decomposition Products:carbonyl fluoride, carbon monoxide, organic fumes, hydrogen fluoride, and sulfur dioxide. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): C
• 风险声明 (欧洲): R34
• 安全声明 (欧洲): S26;S45;S36/S37/S39
• 危险品运输编码: UN 1760 8/PG 3