5160-02-1

• 常用中文名：金光红C
• 常用英文名：D & C red no. 9
• CAS号：5160-02-1
• 分子式：C₃₄H₂₄BaCl₂N₄O₈S₂
• 分子量：888.939
• 相关类别： 染料及颜料 颜料
• 发布时间：2018-07-12 11:29:54
• 更新时间：2024-01-04 01:39:37
• 用途一：主要用于油墨、橡胶制品和自行车内胎的着色。也用于文教及塑料用品的着色。橡胶大红LC的结构与金光红C相同，但其合成工艺是偶合后直接制取钡盐色淀，产品为艳黄光大红色，质地松软，着色力强，耐热性好，不变色，无迁移性，主要用于橡胶、电缆和塑料制品的着色。
  用途二：用于静电复印机
  用途三：主要用于油漆、油墨、塑料制品的着色
  用途四：用于油墨、橡胶、塑料、文教用品等的着色
  用途五：主要用于橡胶、塑料及文教用品的着色

名称

• 中文名: 金光红C
• 英文名: Pigment Red 53:1
• 中文别名: C.I.颜料红53：1
• 英文别名: 1860red; Barium bis(2-chloro-5-((2-hydroxy-1-naphthyl)azo)toluene-4-sulphonate); cred9; redzhb; D and C red 9; Benzenesulfonic acid, 5-chloro-2-[(E)-2-(2-hydroxy-1-naphthalenyl)diazenyl]-4-methyl-, barium salt (2:1); redno204; D & C red no. 9; Barium bis{5-chloro-2-[(E)-(2-hydroxy-1-naphthyl)diazenyl]-4-methylbenzenesulfonate}; red1860; C.I. Pigment Red 9; MFCD01941571; Red 53:1; barium bis{5-chloro-2-[(E)-(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonate}; Toner; D and C Red No. 9; EINECS 225-935-3; AKA204; 1-(4-Chloro-o-sulfo-5-tolylazo)-2-naphthol Barium Salt; redlakec

物化性质

• 密度: 1.48g/cm3
• 熔点: 343-345°C
• 分子式: C₃₄H₂₄BaCl₂N₄O₈S₂
• 分子量: 888.939
• 精确质量: 887.946472
• PSA: 221.06000
• LogP: 11.81500
• 外观性状: 淡黄色-红色或微红的橙色粉末
• 储存条件:

  内衬塑料袋，外用铁桶包装。贮存于阴凉、干燥、通风的库房中，远离火种、热源，不可与易燃物品堆放在一起。

• 稳定性:

  颜色鲜艳，显示强烈彩色金光，且金光又较为耐久牢固，制成的油墨流动性好，耐晒性和耐热性较好。遇浓硫酸呈樱桃红色，稀释后呈棕红色沉淀，微溶于10%热氢氧化钠（为黄色）、水和乙醇，不溶于丙酮和苯。

• 水溶解性: 水溶性：微溶；微溶：乙醇；不溶：苯,丙酮
• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：887.946501Da

  8、标称质量：888Da

  9、平均质量：888.9394Da

• 计算化学:

  1、 氢键供体数量：2

  2、 氢键受体数量：12

  3、 可旋转化学键数量：4

  4、 互变异构体数量：6

  5、 拓扑分子极性表面积（TPSA）：197

  6、 重原子数量：51

  7、 表面电荷：0

  8、 复杂度：672

  9、 同位素原子数量：0

  10、 确定原子立构中心数量：0

  11、 不确定原子立构中心数量：0

  12、 确定化学键立构中心数量：2

  13、 不确定化学键立构中心数量：0

  14、 共价键单元数量：3

• 更多:

  1. 性状：红色带黄光的粉末

  2. 密度（g/mL ,25/4℃）：不确定

  3. 相对蒸汽密度（g/mL,空气=1）：不确定

  4. 熔点（ºC）：343-345

  5. 沸点（ºC,常压）：不确定

  6. 沸点（ºC,2.5mmHg）：不确定

  7. 折射率（nD20）：不确定

  8. 闪点（ºF）：不确定

  9. 比旋光度（º）：不确定

  10. 自燃点或引燃温度（ºC）：不确定

  11. 蒸气压（kPa,25ºC）：不确定

  12. 饱和蒸气压（kPa,60ºC）：不确定

  13. 燃烧热（KJ/mol）：不确定

  14. 临界温度（ºC）：不确定

  15. 临界压力（KPa）：不确定

  16. 油水（辛醇/水）分配系数的对数值：不确定

  17. 爆炸上限（%,V/V）：不确定

  18. 爆炸下限（%,V/V）：不确定

  19. 溶解性：微溶于水、乙醇和10%氢氧化钠热溶液，不溶于苯和丙酮

MSDS

Lake Red CBA Revision number: 5 SAFETY DATA SHEET Section1. IDENTIFICATION Product name:Lake Red CBA Revision number:5 Section2. HAZARDS IDENTIFICATION GHS classification PHYSICAL HAZARDSNot classified HEALTH HAZARDS Acute toxicity (Oral)Category 3 Blood, Spleen Specific target organ toxicity - Repeated exposure [Category 2] Not classified ENVIRONMENTAL HAZARDS GHS label elements, including precautionary statements Pictograms or hazard symbols Signal wordDanger Hazard statementsToxic if swallowed May cause damage to organs through prolonged or repeated exposure : Blood Spleen Precautionary statements: Do not breathe dust/fume/gas/mist/vapours/spray. [Prevention] Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. [Response]IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Get medical advice/attention if you feel unwell. Store locked up. [Storage] [Disposal]Dispose of contents/container through a waste management company authorized by the local government. Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture:Substance Components:Lake Red CBA Percent:.... CAS Number:5160-02-1 1-(4-Chloro-o-sulfo-5-tolylazo)-2-naphthol Barium Salt Synonyms: Chemical Formula:C34H24BaCl2N4O8S2 Lake Red CBA Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion:Immediately call a POISON CENTER or doctor/physician. Rinse mouth. A rescuer should wear personal protective equipment, such as rubber gloves and air- Protection of first-aiders: tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, foam, water spray, carbon dioxide. media: Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to from the chemical:generate poisonous fume. Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Personal precautions,Use extra personal protective equipment (P3 filter respirator for toxic particles). Keep protective equipment and people away from and upwind of spill/leak. Entry to non-involved personnel should emergency procedures: be controlled around the leakage area by roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it. containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with up: appropriate laws and regulations. Section7. HANDLING AND STORAGE Precautions for safe handling Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment. Prevent dispersion of dust. Wash hands and face thoroughly after handling. Use a closed system if possible. Use a local exhaust if dust or aerosol will be generated. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Storage conditions:Keep container tightly closed. Store in a cool and dark place. Store locked up. Store away from incompatible materials such as oxidizing agents. Comply with laws. Packaging material: Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls:Install a closed system or local exhaust. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Dust respirator, self-contained breathing apparatus(SCBA), supplied air respirator, etc. Use respirators approved under appropriate government standards and follow local and national regulations. Impervious gloves. Hand protection: Eye protection:Safety goggles. A face-shield, if the situation requires. Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires. Lake Red CBA Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Solid Form:Crystal- Powder Yellow red - Red Colour: Odour:No data available pH: No data available Melting point/freezing point:No data available No data available Boiling point/range: Flash point:No data available Flammability or explosive limits: No data available Lower: Upper:No data available No data available Relative density: Solubility(ies): Slightly soluble [Water] [Other solvents] Ethanol Slightly soluble: Insoluble:Benzene, Acetone -0.49 Log Pow: Section10. STABILITY AND REACTIVITY Chemical stability:Stable under proper conditions. Possibility of hazardous No special reactivity has been reported. reactions: Incompatible materials: Oxidizing agents Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx), Sulfur oxides, Hydrogen products:chloride Section11. TOXICOLOGICAL INFORMATION No data available Acute Toxicity: Skin corrosion/irritation: No data available No data available Serious eye damage/irritation: Germ cell mutagenicity: mmo-sat 1 mg/plate (+S9) Carcinogenicity: Group 3 (Not classifiable as carcinogenic to humans) IARC = NTP =No data available No data available Reproductive toxicity: RTECS Number:DB5500000 Section12. ECOLOGICAL INFORMATION Ecotoxicity: Fish:No data available Crustacea:No data available Algae:No data available Persistence / degradability: 0% (by BOD) Bioaccumulative0.9 - 1.8 (conc. 0.7 mg/L), 8.5 - 15 (conc. 0.07 mg/L) potential(BCF): Mobility in soil Log Pow:-0.49 Soil adsorption (Koc):No data available Henry's LawNo data available constant(PaM3/mol): Lake Red CBA Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Hazards Class:6.1: Toxic substance. UN-No:1564 Proper shipping name:Barium compound, n.o.s. III Packing group: Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 可燃；火场分解有毒氮氧化物,，硫氧化物，氯化物和氧化钡烟雾。 CHEMICAL IDENTIFICATION RTECS NUMBER : DB5500000 CHEMICAL NAME : Benzenesulfonic acid, 5-chloro-2-((2-hydroxy-1-naphthalenyl)azo)-4-methyl-, barium salt CAS REGISTRY NUMBER : 5160-02-1 LAST UPDATED : 199710 DATA ITEMS CITED : 17 MOLECULAR FORMULA : C17-H12-Cl-N2-O4-S.1/2Ba MOLECULAR WEIGHT : 444.49 WISWESSER LINE NOTATION : L66J BNUNR DG C FSWQ& CQ & 2-BA- HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 27300 mg/kg/91D-C TOXIC EFFECTS : Liver - other changes Related to Chronic Data - death TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 546 gm/kg/2Y-C TOXIC EFFECTS : Endocrine - changes in spleen weight TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 21 gm/kg/14D-C TOXIC EFFECTS : Related to Chronic Data - death TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 130 gm/kg/2Y-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors Blood - tumors TYPE OF TEST : TD - Toxic dose (other than lowest) ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 109 gm/kg/2Y-C TOXIC EFFECTS : Tumorigenic - neoplastic by RTECS criteria Blood - tumors MUTATION DATA TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 1 mg/plate REFERENCE : SCIEAS Science. (American Assoc. for the Advancement of Science, 1333 H St., NW, Washington, DC 20005) V.1- 1895- Volume(issue)/page/year: 236,933,1987 *** REVIEWS *** IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 57,203,1993 IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 8,107,1975 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 8,107,1975 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 57,203,1993 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 57,203,1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M3849 No. of Facilities: 1160 (estimated) No. of Industries: 15 No. of Occupations: 21 No. of Employees: 14370 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M3849 No. of Facilities: 8245 (estimated) No. of Industries: 43 No. of Occupations: 49 No. of Employees: 122313 (estimated) No. of Female Employees: 23095 (estimated)

安全

• 风险声明 (欧洲): R20/21/22
• 安全声明 (欧洲): S22-S36/37/39
• 危险品运输编码: 1564.0
• RTECS号: DB5500000
• 危险类别: 1.0

制备

在重氮桶放水2000L，加入拉开粉3kg，然后加入20%氨水50kg，再倒入CLT酸119kg，在搅拌下徐徐加入30%盐酸157kg，使CLT酸呈细态析出，加完续搅20min，温度10～12℃，体符号为500L，再加入亚硝酸钠36.7kg，温度14～15℃，溶液保持酸性，控制终点备偶合。
偶合桶中放水1000L，液碱108kg，升温至60℃，搅拌加入乙萘酚79.3kg使溶解，并调整体积至3500L，温度30℃左右，备用。
在良好搅拌下，快速把CLT酸重氮液放入偶合桶，终点pH值10～11温度28℃，继续反应1h，pH值逐渐降至7.5～8。加入13kg松香溶解的透明溶液，pH值为8.5～9。把116kg氧化钡溶解于一定体积中，加入到偶合桶中，总体积为8000～8500L，终点pH值8～8.5, 继续反应1h，快速升温至100℃，保温1h。过滤，滤饼80℃进行烘干。得量255kg。