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| 中文名 | 1-萘甲基胺 |
|---|---|
| 英文名 | 1-Naphthalenemethylamine |
| 中文别名 | 1-萘甲胺 |
| 英文别名 |
1-Naphthalenemethanamine
1-(naphthalen-1-yl)methanamine Naphthalen-1-ylmethanamine 1-Naphthalenemethyl amine 1-Naphthylmethylamine 1-(1-Naphthyl)methanamine EINECS 204-244-0 MFCD00004048 1-Naphthalenemethylamine |
| 密度 | 1.1±0.1 g/cm3 |
|---|---|
| 沸点 | 294.5±0.0 °C at 760 mmHg |
| 熔点 | 262-269 °C |
| 分子式 | C11H11N |
| 分子量 | 157.212 |
| 闪点 | 148.3±11.5 °C |
| 精确质量 | 157.089142 |
| PSA | 26.02000 |
| LogP | 2.32 |
| 外观性状 | 透明淡黄色至黄色液体 |
| 蒸汽压 | 0.0±0.6 mmHg at 25°C |
| 折射率 | 1.653 |
| 储存条件 | 储存于阴凉、通风的库房。远离火种、空气。应与氧化剂分开存放，切忌混储。配备相应品种和数量的消防器材。储区应备有合适的材料收容泄漏物。 |
| 稳定性 | 常温常压稳定，避免与强氧化剂、空气接触。 |
| 分子结构 | 五、分子性质数据： 1、 摩尔折射率：52.54 2、 摩尔体积（m3/mol）：143.5 3、 等张比容（90.2K）：376.9 4、 表面张力（dyne/cm）：47.5 5、 极化率（10-24cm3）：20.83 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:1 3.氢键受体数量:1 4.可旋转化学键数量:1 5.互变异构体数量:无 6.拓扑分子极性表面积26 7.重原子数量:12 8.表面电荷:0 9.复杂度:144 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：无色液体。 2. 密度（g/mL,25℃）：1.073 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：262-269 5. 沸点（ºC,常压）：290-293 6. 沸点（ºC, KPa）：未确定 7. 折射率：1.643 8. 闪点（ºC）：>110 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（mmHg, ºC）：未确定 12. 饱和蒸气压（kPa, ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
Synonym:1-(Aminomethyl)naphthalen Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 118-31-0: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: yellow Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 290 - 293 deg C @760mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: > 110 deg C (> 230.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.073 Molecular Formula: C11H11N Molecular Weight: 157.21 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents, acids, acid anhydrides, chloroformates, acid chlorides. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 118-31-0 unlisted. LD50/LC50: Not available. Carcinogenicity: 1-Naphthalenemethylamine - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: IMO Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: RID/ADR Shipping Name: Not regulated. Hazard Class: UN Number: Packing group: Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 118-31-0: No information available. Canada CAS# 118-31-0 is listed on Canada's NDSL List. CAS# 118-31-0 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 118-31-0 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 对水体没有危害。
|
| 符号 |
GHS07 |
|---|---|
| 信号词 | Warning |
| 危害声明 | H315-H319-H335 |
| 警示性声明 | P261-P305 + P351 + P338 |
| 个人防护装备 | Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| 危害码 (欧洲) | Xi:Irritant; |
| 风险声明 (欧洲) | R36/37/38 |
| 安全声明 (欧洲) | S26-S36/37/39 |
| 危险品运输编码 | 2735 |
| WGK德国 | 3 |
| 包装等级 | III |
| 危险类别 | 8 |
| 海关编码 | 2921499090 |
| 上游产品 10 | |
|---|---|
| 下游产品 10 | |
| 海关编码 | 2921499090 |
|---|---|
| 中文概述 | 2921499090 其他芳香单胺及衍生物及它们的盐. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |
![3-bromo-N-(naphthalen-1-ylmethyl)-benzo[b]thiophene-2-carboxamide结构式](https://www.chemsrc.com/caspic/495/1355943-34-8.png)
