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| 中文名 | (R)-1-[(SP)-2-(二环己基膦)二茂铁基乙基]二苯基膦 |
|---|---|
| 英文名 | (r)-1-[(1s)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-phenylphosphine |
| 中文别名 | (S)-(-)-l-[(S)-2-( 二环己基膦基) 三戊铁基]乙基二环己基膦 |
| 英文别名 |
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ET
(R,R)-1-(DICYCLOHEXYLPHOSPHINO)-2-[1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE 1-{2-[P(cHex)2]-ferrocenyl}ethyl-PPh2 MFCD00800280 (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDIPHENYLPHOSPHINE JOSIPHOS SL-J004-1 (R)1[(1S)2(di-C-hexylphosphino)ferrocen]et-diphenylphosphin 1-[2-(dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine |
| 分子式 | C36H44FeP2 |
|---|---|
| 分子量 | 594.52700 |
| 精确质量 | 594.22700 |
| PSA | 27.18000 |
| LogP | 9.12070 |
| 储存条件 | 室温 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:2 4.可旋转化学键数量:7 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:39 8.表面电荷:0 9.复杂度:527 10.同位素原子数量:0 11.确定原子立构中心数量:1 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:3 |
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Section 1: Product Identification Chemical Name:(R)-(-)-1-[(S)-2-Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine, min. 97% CAS Registry Number:158923-09-2 Formula:C36H44FeP2 EINECS Number:None Chemical Family:organophosphine ligand Synonym:[(S)-1-(R)-(-)-2(Diphenylphosphanylethyl)dicyclohexyl phosphanylferrocene
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound158923-09-2100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and mucous membranes. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, eyes Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information available on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. The toxicological properties of this compound have not been thoroughly investigated. Unrecognized hazards Chronic Health Affects: may be present. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Keep material in a tightly sealed container. Prolonged exposure to the air will result in degradation of the Handling and Storage: product. Handle and store material under an inert atmosphere of nitrogen or argon. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:orange powder Molecular Weight:594.59 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:Insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:exposure to oxygen, contact with strong oxidizing agents Incompatibility:Oxidizing agents and halogens Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, phosphorus oxides, and iron oxide. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A |
| 个人防护装备 | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
|---|---|
| 风险声明 (欧洲) | 36/37/38 |
| 安全声明 (欧洲) | 26-36/37/39 |
| 危险品运输编码 | NONH for all modes of transport |
| WGK德国 | 3 |