58729-31-0

• 常用中文名：硫代吗啉-3-羧酸乙酯
• 常用英文名：Ethyl 3-thiomorpholinecarboxylate
• CAS号：58729-31-0
• 分子式：C₇H₁₃NO₂S
• 分子量：175.249
• 发布时间：2018-06-26 14:51:04
• 更新时间：2024-09-13 10:22:25

名称

• 中文名: 硫代吗啉-3-羧酸乙酯
• 英文名: Ethyl thiomorpholine-3-carboxylate
• 英文别名: MFCD00107967; 3-Thiomorpholinecarboxylic acid, ethyl ester; Ethyl thiomorpholine-3-carboxylate; Ethyl 3-thiomorpholinecarboxylate

物化性质

• 密度: 1.1±0.1 g/cm3
• 沸点: 261.8±35.0 °C at 760 mmHg
• 熔点: 118ºC
• 分子式: C₇H₁₃NO₂S
• 分子量: 175.249
• 闪点: 112.2±25.9 °C
• 精确质量: 175.066696
• PSA: 63.63000
• LogP: 0.88
• 蒸汽压: 0.0±0.5 mmHg at 25°C
• 折射率: 1.495

MSDS

Name: Ethyl thiomorpholine-3-carboxylate Material Safety Data Sheet Synonym: CAS: 58729-31-0 Section 1 - Chemical Product MSDS Name:Ethyl thiomorpholine-3-carboxylate Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 58729-31-0 Ethyl thiomorpholine-3-carboxylate 97+% unlisted Hazard Symbols: C Risk Phrases: 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Causes burns. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 58729-31-0: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Pale yellow Odor: Without to slight pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 118 - 121 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C7H13NO2S Molecular Weight: 175.25 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, reducing agents, strong bases, amines. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 58729-31-0 unlisted. LD50/LC50: Not available. Carcinogenicity: Ethyl thiomorpholine-3-carboxylate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: AMINES, SOLID, CORROSIVE, N.O.S.* Hazard Class: 8 UN Number: 3259 Packing Group: III IMO Shipping Name: AMINES, SOLID, CORROSIVE, N.O.S. Hazard Class: 8 UN Number: 3259 Packing Group: III RID/ADR Shipping Name: AMINES, SOLID, CORROSIVE, N.O.S. Hazard Class: 8 UN Number: 3259 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 22 Do not breathe dust. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 58729-31-0: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 58729-31-0 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 58729-31-0 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): C
• 海关编码: 2934999090

合成路线

60-23-1 3674-13-3 ~% 58729-31-0

文献：US5610120 A1, ;

72850-30-7 ~% 58729-31-0

文献：Acta Chemica Scandinavica, , vol. 48, # 6 p. 517 - 525

70-23-5 ~% 58729-31-0

文献：Acta Chemica Scandinavica, , vol. 48, # 6 p. 517 - 525

上下游产品

上游产品  4
60-23-1 3674-13-3 72850-30-7 70-23-5
下游产品  3
156474-26-9 128453-98-5 20960-92-3

海关

海关编码	2934999090
中文概述	2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%