10108-73-3

• 常用中文名：Nitric acid, cerium(3+)salt (3:1)
• 常用英文名：Nitric acid, cerium(3+)salt (3:1)
• CAS号：10108-73-3
• 分子式：CeN₃O₉
• 分子量：326.131
• 发布时间：2017-01-10 16:32:11
• 更新时间：2024-01-31 14:50:12

名称

• 英文名: Cerous nitrate [Ce(NO3)3]
• 英文别名: cerium nitrate; Cerium(3+) trinitrate; citriumnitrate

物化性质

• 沸点: 83ºC at 760mmHg
• 分子式: CeN₃O₉
• 分子量: 326.131
• 精确质量: 325.868896
• PSA: 66.05000
• LogP: 0.17550
• 外观性状: 无色至白色固体
• 储存条件: 库房通风低温干燥,轻装轻卸,与有机物、还原剂、硫、磷易燃物分开存放

MSDS

Name: Cerium(III) nitrate hexahydrate 99.5% Material Safety Data Sheet Synonym: Cerium nitrate hexahydrate; Cerium trinitrate hexahydrate; Cerous nitrate hexahydrate CAS: 10108-73-3 Section 1 - Chemical Product MSDS Name:Cerium(III) nitrate hexahydrate 99.5% Material Safety Data Sheet Synonym:Cerium nitrate hexahydrate; Cerium trinitrate hexahydrate; Cerous nitrate hexahydrate Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 10108-73-3 Cerium(III) nitrate hexahydrate 99.5 unlisted Hazard Symbols: XI O Risk Phrases: 36 8 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes. Contact with combustible material may cause fire.Hygroscopic (absorbs moisture from the air). Potential Health Effects Eye: Causes severe eye irritation. Skin: Causes skin irritation. Ingestion: Causes gastrointestinal irritation with nausea, vomiting and diarrhea. Methemoglobinemia is characterized by dizziness, drowsiness, headache, shortness of breath, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), rapid heart rate and chocolate-brown colored blood. Ingestion of nitrate containing compounds can lead to methemoglobinemia. Inhalation: Causes respiratory tract irritation. Chronic: May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis (bluish skin due to deficient oxygenation of blood), rapid heart rate, unconsciousness and possible death. Section 4 - FIRST AID MEASURES Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately. Skin: In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse. Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Keep combustibles (wood, paper, oil, etc.,) away from spilled material. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid contact with clothing and other combustible materials. Avoid breathing dust. Inform laundry personnel of contaminant's hazards. Storage: Do not store near combustible materials. Store in a cool, dry place. Keep container closed when not in use. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits CAS# 10108-73-3: CAS# 10294-41-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: colorless Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 200 deg C Freezing/Melting Point: 150 deg C Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: >200 C Solubility in water: Soluble. Specific Gravity/Density: 1.67 @ 20C Molecular Formula: CeN3O9.6H2O Molecular Weight: 434.22 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Exposure to moist air or water. Incompatibilities with Other Materials: Combustible materials, organic materials, strong reducing agents. Hazardous Decomposition Products: Nitrogen oxides, irritating and toxic fumes and gases. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 10108-73-3: FK6280000 CAS# 10294-41-4: FK6300000 LD50/LC50: CAS# 10108-73-3: Oral, rat: LD50 = 3154 mg/kg. CAS# 10294-41-4: Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, skin: 500 mg/24H Mild; Oral, rat: LD50 = 4200 mg/kg. Carcinogenicity: Cerium nitrate anhydrous - Not listed by ACGIH, IARC, or NTP. Cerium(III) nitrate hexahydrate - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: NITRATES, INORGANIC, N.O.S. Hazard Class: 5.1 UN Number: 1477 Packing Group: II IMO Shipping Name: NITRATES, INORGANIC, N.O.S. Hazard Class: 5.1 UN Number: 1477 Packing Group: II RID/ADR Shipping Name: NITRATES, INORGANIC, N.O.S. Hazard Class: 5.1 UN Number: 1477 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI O Risk Phrases: R 36 Irritating to eyes. R 8 Contact with combustible material may cause fire. Safety Phrases: S 17 Keep away from combustible material. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 39 Wear eye/face protection. WGK (Water Danger/Protection) CAS# 10108-73-3: No information available. CAS# 10294-41-4: No information available. Canada CAS# 10108-73-3 is listed on Canada's DSL List. CAS# 10108-73-3 is not listed on Canada's Ingredient Disclosure List. CAS# 10294-41-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 10108-73-3 is listed on the TSCA inventory. CAS# 10294-41-4 is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form is on the inventory (40CFR720.3(u)(2)). SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : FK6280000 CHEMICAL NAME : Cerium(III) nitrate CAS REGISTRY NUMBER : 10108-73-3 LAST UPDATED : 199701 DATA ITEMS CITED : 7 MOLECULAR FORMULA : N3-O9.Ce MOLECULAR WEIGHT : 326.15 WISWESSER LINE NOTATION : .CE..N-O3*3 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 3154 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : EQSSDX Environmental Quality and Safety, Supplement. (Stuttgart, Fed. Rep. Ger.) V.1-5, 1975-76. Discontinued. Volume(issue)/page/year: 1,1,1975 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 216 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : EQSSDX Environmental Quality and Safety, Supplement. (Stuttgart, Fed. Rep. Ger.) V.1-5, 1975-76. Discontinued. Volume(issue)/page/year: 1,1,1975 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 37 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : EQSSDX Environmental Quality and Safety, Supplement. (Stuttgart, Fed. Rep. Ger.) V.1-5, 1975-76. Discontinued. Volume(issue)/page/year: 1,1,1975 ** REPRODUCTIVE DATA ** TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intratesticular DOSE : 26092 ug/kg SEX/DURATION : male 1 day(s) pre-mating TOXIC EFFECTS : Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Paternal Effects - testes, epididymis, sperm duct REFERENCE : JRPFA4 Journal of Reproduction and Fertility. (Biochemical Soc. Book Depot, POB 32, Commerce Way, Colchester, Essex CO2 8HP, UK) V.1- 1960- Volume(issue)/page/year: 7,21,1964 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 17760 No. of Facilities: 10 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 20 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 17760 No. of Facilities: 33 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 688 (estimated) No. of Female Employees: 259 (estimated)

安全

• 危险品运输编码: UN 1477
• 包装等级: II
• 危险类别: 5.1