2277-19-2

• 常用中文名：(Z)-6-壬烯醛
• 常用英文名：CIS-6-NONENAL
• CAS号：2277-19-2
• 分子式：C₉H₁₆O
• 分子量：140.22300
• 发布时间：2018-03-22 08:00:00
• 更新时间：2024-01-09 18:26:16
• 下载msds

名称

• 中文名: 顺-6-壬烯醛
• 英文名: cis-6-nonenal
• 中文别名: (Z)-6-壬烯醛
• 英文别名: (6Z)-nonenal; (6Z)-6-Nonenal; (Z)-non-6-enal; 6-cis-Nonenal; FEMA 3580; EINECS 218-900-9; MFCD00014683; cis-6-Nonen-1-al; cis-6-Nonenal; 6-Nonenal,cis; non-6c-enal; C6 NONENAL; (Z)-6-Nonenal; (z)-6-nonena; NONENAL-CIS-6

物化性质

• 密度: 0.841 g/mL at 25 °C(lit.)
• 沸点: 87 °C19 mm Hg(lit.)
• 分子式: C₉H₁₆O
• 分子量: 140.22300
• 闪点: >230 °F
• 精确质量: 140.12000
• PSA: 17.07000
• LogP: 2.71190
• 折射率: n20/D 1.442(lit.)
• 储存条件:

  储存在干爽的惰性气体下，保持容器密封，放入紧密的出藏器内，储存在阴凉，干燥的地方

• 稳定性:

  避免氧化物，空气接触

• 分子结构:

  1、 摩尔折射率：43.98

  2、 摩尔体积（m³/mol）：168.0

  3、 等张比容（90.2K）：386.3

  4、 表面张力（dyne/cm）：27.9

  5、 极化率（10 ^-24cm ³）：17.43

• 计算化学:

  1、 疏水参数计算参考值（XlogP）：2.3

  2、 氢键供体数量：0

  3、 氢键受体数量：1

  4、 可旋转化学键数量：6

  5、 互变异构体数量：2

  6、 拓扑分子极性表面积（TPSA）：17.1

  7、 重原子数量：10

  8、 表面电荷：0

  9、 复杂度：94.9

  10、同位素原子数量：0

  11、确定原子立构中心数量：0

  12、不确定原子立构中心数量：0

  13、确定化学键立构中心数量：1

  14、不确定化学键立构中心数量：0

  15、共价键单元数量：1

• 更多:

  1. 性状：无色液体

  2. 密度（g/L,20ºC）：0.847

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC 10mmHg）：72

  7. 折射率（nD20）：1.442

  8. 闪点（ºF）：>230

  9. 比旋光度（）：未确定

  10. 自燃点或引燃温度（ºC）：75

  11. 蒸气压（Pa,25ºC）：未确定

  12. 饱和蒸气压（kPa,20ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：不能拌和的或难以拌和

MSDS

Name: cis-6-Nonenal, 90% Material Safety Data Sheet Synonym: cis-6-nonen-1-al CAS: 2277-19-2 Section 1 - Chemical Product MSDS Name: cis-6-Nonenal, 90% Material Safety Data Sheet Synonym: cis-6-nonen-1-al SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 2277-19-2 Cis-6-nonenal 90.0 218-900-9 Hazard Symbols: None Listed. Risk Phrases: None Listed. SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. Chronic: Not available. SECTION 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear. Notes to Physician: Treat symptomatically and supportively. Antidote: None reported. SECTION 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Combustible liquid. Can form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated. Extinguishing Media: Use water spray to cool fire-exposed containers. Use water spray, dry chemical, carbon dioxide, or chemical foam. SECTION 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. SECTION 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use only in a well-ventilated area. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Use only in a chemical fume hood. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Keep under a nitrogen blanket. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.) SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 2277-19-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 87 deg C @ 19.00mm Hg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: 75 deg C ( 167.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: insoluble Specific Gravity/Density: .8410g/cm3 Molecular Formula: C9H16O Molecular Weight: 140.23 SECTION 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, ignition sources, excess heat. Incompatibilities with Other Materials: Oxidizing agents Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported. SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 2277-19-2: RA8509200 LD50/LC50: CAS# 2277-19-2: Dermal, guinea pig: LD50 = >5 gm/kg; Oral, mouse: LD50 = >5 gm/kg. Carcinogenicity: Cis-6-nonenal - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. SECTION 12 - ECOLOGICAL INFORMATION SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. SECTION 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 2277-19-2: No information available. Canada CAS# 2277-19-2 is listed on Canada's DSL List. CAS# 2277-19-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 2277-19-2 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION MSDS Creation Date: 2/19/1999 Revision #2 Date: 3/18/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 1 、皮肤/眼睛刺激性：豚鼠，皮肤接触，标准Draize实验：100%/24H，轻度反应 2、急性毒性：小鼠经口LD50：>5 mg/kg；几内亚猪，皮肤接触LD50：>5 mg/kg 生态学数据: 通常对水是不危害的，若无政府许可，勿将材料排入周围环境。 CHEMICAL IDENTIFICATION RTECS NUMBER : RA8509200 CHEMICAL NAME : 6-Nonenal, (Z)- CAS REGISTRY NUMBER : 2277-19-2 LAST UPDATED : 199701 DATA ITEMS CITED : 4 MOLECULAR FORMULA : C9-H16-O MOLECULAR WEIGHT : 140.25 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - guinea pig REFERENCE : FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 20,777,1982 ** ACUTE TOXICITY DATA ** TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : >5 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 20,777,1982 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : >5 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 20,777,1982

安全

• 符号: GHS07
• 信号词: Warning
• 危害声明: H315-H319-H335
• 警示性声明: P261-P305 + P351 + P338
• 个人防护装备: Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
• 危害码 (欧洲): Xi
• 风险声明 (欧洲): R36/37/38:Irritating to eyes, respiratory system and skin .
• 安全声明 (欧洲): S26-S36
• 危险品运输编码: NONH for all modes of transport
• WGK德国: 2
• RTECS号: RA8509200
• 海关编码: 2912190090

合成路线

31502-19-9 ~94% 2277-19-2

文献：Snyder, Scott A.; Treitler, Daniel S.; Brucks, Alexandria P.; Sattler, Wesley Journal of the American Chemical Society, 2011 , vol. 133, # 40 p. 15898 - 15901

80634-88-4 ~88% 2277-19-2

文献：Iwamoto, Minoru; Kubota, Noboru; Takagi, Yoshikazu; Kogami, Kunio; Hayashi, Kazuo Agricultural and Biological Chemistry, 1982 , vol. 46, # 9 p. 2383 - 2386

1136196-28-5 ~% 2277-19-2

文献：Journal of the American Chemical Society, , vol. 133, # 40 p. 15898 - 15901

629-11-8 ~% 2277-19-2

文献：Journal of the American Chemical Society, , vol. 133, # 40 p. 15898 - 15901

103202-59-1 ~% 2277-19-2

文献：Journal of the American Chemical Society, , vol. 133, # 40 p. 15898 - 15901

118794-69-7 ~% 2277-19-2

文献：Journal of the American Chemical Society, , vol. 133, # 40 p. 15898 - 15901

海关

海关编码	2912190090
中文概述	HS: 2912190090. 其他无环醛（不含其他含氧基）. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 四聚甲醛报明外观
Summary	2912190090 acyclic aldehydes without other oxygen function。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%