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| 中文名 | (1R,2R,3S,5R)-(-)-2,3-蒎烷二醇 |
|---|---|
| 英文名 | (1R,3S,4R,5R)-4,6,6-trimethylbicyclo[3.1.1]heptane-3,4-diol |
| 中文别名 |
(1R,2R,3S,5R)-2,6,6-三甲基二环[3.1.1]庚-2,3-二醇
(1R,2R,3S,5R)-(-)-蒎二醇 (1R,2R,3S,5R)-(-)-蒎烷二醇 (1R-(1alpha,2beta,3beta,5alpha))-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇 三甲基庚烷二醇 |
| 英文别名 |
(-)-(1R,2R,3S,5R)-pinane-2,3-diol
(1R,2R,3S,5R)-2,6,6-Trimethylbicyclo[3.1.1]heptane-2,3-diol (1R,2R,3S,5R)-(-)-Pinanediol Pinanediol [INCI] (-)-pinane-2,3-diol (-)-2-Hydroxyisopinocampheol (-)-cis-Pinane-cis-2,3-diol MFCD00010365 (1R,2R,3S,5R)-2,3-Pinanediol (1R,2R,3S,5R)-(-)-2,3-Pinanediol (-)-pinanediol [1R-(1|A,2|A,3|A,5|A)]-2,6,6-Trimethylbicyclo[3.1.1]heptane-2,3-diol (1R,2R,3S,5R)-2,6,6-trimethylbicyclo[3.3.1]heptane-2,3-diol Bicyclo[3.1.1]heptane-2,3-diol, 2,6,6-trimethyl-, (1R,2R,3S,5R)- (-)-2,3-Pinanediol (1R,2R,3S,4R)-2,6,6-trimethylcyclo[3.1.1]heptane-2,3-diol |
| 密度 | 1.1±0.1 g/cm3 |
|---|---|
| 沸点 | 263.7±8.0 °C at 760 mmHg |
| 熔点 | 55-59ºC |
| 分子式 | C10H18O2 |
| 分子量 | 170.249 |
| 闪点 | 120.8±13.0 °C |
| 精确质量 | 170.130676 |
| PSA | 40.46000 |
| LogP | 1.58 |
| 外观性状 | 白色结晶固体 |
| 蒸汽压 | 0.0±1.2 mmHg at 25°C |
| 折射率 | 1.520 |
| 储存条件 | 密闭于阴凉干燥环境中 |
| 稳定性 | 遵照规定使用和储存则不会分解。 |
| 水溶解性 | 可溶于：甲醇 |
| 分子结构 | 1、 摩尔折射率：47.45 2、 摩尔体积（m3/mol）：156.0 3、 等张比容（90.2K）：389.2 4、 表面张力（dyne/cm）：38.7 5、 极化率（10 -24cm 3）：18.81 |
| 更多 | 1. 性状：无可用 2. 密度（g/mL,25/4℃）：无可用 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：55-59 5. 沸点（ºC,常压）：101-102/1mmHg 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：-8.5（C=6.5,甲苯） 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：无可用 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Use agent most appropriate to extinguish fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.) Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 22422-34-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 101 - 102 deg C @ 1mmHg Freezing/Melting Point: 57 - 59 deg C Autoignition Temperature: Not applicable. Flash Point: > 110 deg C (> 230.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C10H18O2 Molecular Weight: 170.25 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Incompatible materials, dust generation, excess heat, strong oxidants. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 22422-34-0 unlisted. LD50/LC50: Not available. Carcinogenicity: (1R,2R,3S,5R)-(-)-2,3-Pinanediol - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. S 28A After contact with skin, wash immediately with plenty of water. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 22422-34-0: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 22422-34-0 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 22422-34-0 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。
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| 个人防护装备 | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
|---|---|
| 危害码 (欧洲) | Xi |
| 风险声明 (欧洲) | R36/37/38 |
| 安全声明 (欧洲) | S24/25 |
| 危险品运输编码 | NONH for all modes of transport |
| 海关编码 | 2942000000 |
|
~66%
22422-34-0 |
| 文献：Hobuss, Dennis; Thoene, Carsten; Laschat, Sabine; Baro, Angelika Synthesis, 2003 , # 13 p. 2053 - 2056 |
|
~91%
22422-34-0 |
| 文献：Zhu, Yongqiang; Zhao, Xin; Zhu, Xinrong; Wu, Gang; Li, Yuejie; Ma, Yuheng; Yuan, Yunxia; Yang, Jie; Hu, Yang; Ai, Li; Gao, Qingzhi Journal of Medicinal Chemistry, 2009 , vol. 52, # 14 p. 4192 - 4199 |
|
~%
22422-34-0 |
| 文献：Bulletin of the Chemical Society of Japan, , vol. 41, # 11 p. 2700 - 2703 |
|
~%
22422-34-0 |
| 文献：Bulletin of the Chemical Society of Japan, , vol. 41, # 11 p. 2700 - 2703 |
|
~%
22422-34-0 |
| 文献：Bulletin of the Chemical Society of Japan, , vol. 41, p. 1180,1183 |
| 上游产品 4 | |
|---|---|
| 下游产品 1 | |
| 海关编码 | 2906199090 |
|---|---|
| 中文概述 | 2906199090. 其他环烷醇，环烯醇及环萜烯醇. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2906199090. cyclanic, cyclenic or cyclotherpenic alcohols. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0% |
