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| 中文名 | 反-六氢对苯二甲基二胺 |
|---|---|
| 英文名 | [4-(aminomethyl)cyclohexyl]methanamine |
| 英文别名 |
C,C'-cyclohexane-1,4-diyl-bis-methylamine
cis-1,4-Di(aminomethyl)cyclohexane cis-1,4-cyclohexanedimethanamine 1,4-Cyclohexanedimethanamine, cis- 1,4-Cyclohexanedimethanamine Cyclohexane-1,4-diyldimethanamine cis-cyclohexane-1,4-diyldimethanamine 1,4-Cyclohexanediyldimethanamine cis-1,4-Bis(aminomethyl)cyclohexane cis-Hexahydro-p-xylylenediamine cis-1,4-Cyclohexanediyldimethanamine |
| 密度 | 0.9±0.1 g/cm3 |
|---|---|
| 沸点 | 229.4±8.0 °C at 760 mmHg |
| 熔点 | -9 °C |
| 分子式 | C8H18N2 |
| 分子量 | 142.242 |
| 闪点 | 119.7±20.4 °C |
| 精确质量 | 142.147003 |
| PSA | 52.04000 |
| LogP | 0.47 |
| 外观性状 | 液体;Colorless to Almost colorless clear liquid |
| 蒸汽压 | 0.1±0.5 mmHg at 25°C |
| 折射率 | 1.478 |
| 储存条件 | 存放于惰性气体之中;避免空气 |
|
cis-1,4-Bis(aminomethyl)cyclohexane
Revision number: 5
SAFETY DATA SHEET Section1. IDENTIFICATION Product name:cis-1,4-Bis(aminomethyl)cyclohexane Revision number:5 Section2. HAZARDS IDENTIFICATION GHS classification PHYSICAL HAZARDSNot classified HEALTH HAZARDS Acute toxicity (Oral)Category 4 Category 3 Acute toxicity (Dermal) Skin corrosion/irritationCategory 1B Category 1 Serious eye damage/eye irritation ENVIRONMENTAL HAZARDSNot classified GHS label elements, including precautionary statements Pictograms or hazard symbols Signal wordDanger Hazard statementsHarmful if swallowed Toxic in contact with skin Causes severe skin burns and eye damage Precautionary statements: [Prevention]Do not breathe dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Wear protective gloves and eye/face protection. [Response]IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or doctor/physician. [Storage]Store locked up. [Disposal]Dispose of contents/container through a waste management company authorized by the local government. cis-1,4-Bis(aminomethyl)cyclohexane Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture:Substance Components:cis-1,4-Bis(aminomethyl)cyclohexane Percent:>98.0%(GC)(T) CAS Number:10029-09-1 Synonyms:cis-1,4-Di(aminomethyl)cyclohexane , cis-Hexahydro-p-xylylenediamine Chemical Formula:C8H18N2 Section4. FIRST AID MEASURES Remove victim to fresh air and keep at rest in a position comfortable for breathing. Inhalation: Immediately call a POISON CENTER or doctor/physician. Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of soap and water. Immediately call a POISON CENTER or doctor/physician. Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician. Ingestion:Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. A rescuer should wear personal protective equipment, such as rubber gloves and air- Protection of first-aiders: tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, foam, water in large amounts, carbon dioxide. media: Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to from the chemical:generate poisonous fume. Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Personal precautions,Use extra personal protective equipment (self-contained breathing apparatus). Keep protective equipment and people away from and upwind of spill/leak. Ensure adequate ventilation. Entry to non- emergency procedures: involved personnel should be controlled around the leakage area by roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust). containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected up: material should be promptly disposed of, in accordance with appropriate laws and regulations. Section7. HANDLING AND STORAGE Precautions for safe handling Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment. Prevent generation of vapour or mist. Wash hands and face thoroughly after handling. Use a closed system if possible. Use a ventilation, local exhaust if vapour or aerosol will be generated. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Storage conditions:Keep container tightly closed. Store in a cool and dark place. Store under inert gas. Store locked up. Store away from incompatible materials such as oxidizing agents. cis-1,4-Bis(aminomethyl)cyclohexane Section7. HANDLING AND STORAGE Air-sensitive Packaging material:Comply with laws. Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls:Install a closed system or local exhaust. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Half or full facepiece respirator, self-contained breathing apparatus(SCBA), supplied air respirator, etc. Use respirators approved under appropriate government standards and follow local and national regulations. Hand protection:Impervious gloves. Eye protection:Safety goggles. A face-shield, if the situation requires. Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Liquid Physical state (20°C): Form:Clear Colour:Colorless - Almost colorless Odour:No data available pH: No data available Melting point/freezing point:-9°C Boiling point/range:76°C/0.1kPa Flash point:No data available Flammability or explosive limits: Lower:No data available No data available Upper: Relative density:0.94 Solubility(ies): [Water]No data available [Other solvents]No data available Section10. STABILITY AND REACTIVITY Chemical stability:Stable under proper conditions. Possibility of hazardous No special reactivity has been reported. reactions: Incompatible materials: Oxidizing agents, Acids Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx) products: Section11. TOXICOLOGICAL INFORMATION Acute Toxicity:No data available Skin corrosion/irritation: No data available No data available Serious eye damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: IARC =No data available NTP =No data available Reproductive toxicity:No data available Section12. ECOLOGICAL INFORMATION Ecotoxicity: No data available Fish: Crustacea:No data available No data available Algae: Persistence / degradability: No data available cis-1,4-Bis(aminomethyl)cyclohexane Section12. ECOLOGICAL INFORMATION BioaccumulativeNo data available potential(BCF): Mobility in soil No data available Log Pow: Soil adsorption (Koc):No data available No data available Henry's Law constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION 8: Corrosive. Hazards Class: Subsidiary risk:6.1: Toxic substance. 2922 UN-No: Proper shipping name:Corrosive liquid, toxic, n.o.s. II Packing group: Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | C |
|---|---|
| 海关编码 | 2921300090 |
|
~%
10029-09-1 |
| 文献：Bengtsson, Christoffer; Blaho, Stefan; Saitton, David Blomberg; Brickmann, Kay; Broddefalk, Johan; Davidsson, Oejvind; Drmota, Tomas; Folmer, Rutger; Hallberg, Kenth; Hallen, Stefan; Hovland, Ragnar; Isin, Emre; Johannesson, Petra; Kull, Bengt; Larsson, Lars-Olof; Loefgren, Lars; Nilsson, Kristina E.; Noeske, Tobias; Oakes, Nick; Plowright, Alleyn T.; Schnecke, Volker; Sthlberg, Pernilla; Soerme, Pernilla; Wan, Hong; Wellner, Eric; Oester, Linda Bioorganic and Medicinal Chemistry, 2011 , vol. 19, # 10 p. 3039 - 3053 |
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~%
10029-09-1 |
| 文献：Mitsui Chemicals, Inc.; YOSHIMURA, Naritoshi; KIYONO, Shinji; HAMADA, Tetsuya; WATANABE, Eiji; SAWADA, Saiko Patent: EP2626344 A1, 2013 ; Location in patent: Paragraph 0152-0156 ; |
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10029-09-1 |
| 文献：Mitsui Chemicals, Inc.; YOSHIMURA, Naritoshi; KIYONO, Shinji; HAMADA, Tetsuya; WATANABE, Eiji; SAWADA, Saiko Patent: EP2626344 A1, 2013 ; Location in patent: Paragraph 0218-0221 ; |
|
~%
10029-09-1 |
| 文献：Bengtsson, Christoffer; Blaho, Stefan; Saitton, David Blomberg; Brickmann, Kay; Broddefalk, Johan; Davidsson, Oejvind; Drmota, Tomas; Folmer, Rutger; Hallberg, Kenth; Hallen, Stefan; Hovland, Ragnar; Isin, Emre; Johannesson, Petra; Kull, Bengt; Larsson, Lars-Olof; Loefgren, Lars; Nilsson, Kristina E.; Noeske, Tobias; Oakes, Nick; Plowright, Alleyn T.; Schnecke, Volker; Sthlberg, Pernilla; Soerme, Pernilla; Wan, Hong; Wellner, Eric; Oester, Linda Bioorganic and Medicinal Chemistry, 2011 , vol. 19, # 10 p. 3039 - 3053 |
|
~%
10029-09-1 |
| 文献：Bengtsson, Christoffer; Blaho, Stefan; Saitton, David Blomberg; Brickmann, Kay; Broddefalk, Johan; Davidsson, Oejvind; Drmota, Tomas; Folmer, Rutger; Hallberg, Kenth; Hallen, Stefan; Hovland, Ragnar; Isin, Emre; Johannesson, Petra; Kull, Bengt; Larsson, Lars-Olof; Loefgren, Lars; Nilsson, Kristina E.; Noeske, Tobias; Oakes, Nick; Plowright, Alleyn T.; Schnecke, Volker; Sthlberg, Pernilla; Soerme, Pernilla; Wan, Hong; Wellner, Eric; Oester, Linda Bioorganic and Medicinal Chemistry, 2011 , vol. 19, # 10 p. 3039 - 3053 |
|
~%
10029-09-1 |
| 文献：Mitsui Chemicals, Inc.; YOSHIMURA, Naritoshi; KIYONO, Shinji; HAMADA, Tetsuya; WATANABE, Eiji; SAWADA, Saiko Patent: EP2626344 A1, 2013 ; |
|
~%
10029-09-1 |
| 文献：Malachowski; Jankiewicz; Wasowska; Jozkiewicz Chemische Berichte, 1938 , vol. 71, p. 759,760, 764 |
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10029-09-1 |
| 文献：Malachowski; Jankiewicz; Wasowska; Jozkiewicz Chemische Berichte, 1938 , vol. 71, p. 759,760, 764 |
| 上游产品 7 | |
|---|---|
| 下游产品 0 | |
| 海关编码 | 2921300090 |
|---|---|
| 中文概述 | 2921300090 其他环（烷，烯，萜烯）单胺或多胺（包括其衍生物及它们的盐）. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2921300090 other cyclanic, cyclenic or cyclotherpenic mono- or polyamines, and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0% |
