查看所有供应商和价格请点击：
| 中文名 | 1,1,1-三氟乙酰丙酮镍(II) |
|---|---|
| 英文名 | nickel(2+),1,1,1-trifluoro-4-oxopent-2-en-2-olate,dihydrate |
| 中文别名 | 1,1,1-三氟乙酰丙酮镍 |
| 英文别名 |
Nickel(II) 1,1,1-trifluoro-2,4-pentanedionate dihydrate
Bis-(1,1,1-trifluoro-2,4-pentanedionato-O,O')-nickel Nickel(II)trifluoroacetylacetonatedihydrate nickeltrifluoroacetylacetonate Nickel 1,1,1-trifluoro 2,4-pentanedionate dihydrate MFCD00150656 Nickel 1,1,1-trifluoroacetylacetonate dihydrate NICKEL TRIFLUOROPENTANEDIONATE,dihydrate Nickeltrifluoroacetylacetonatedihydrate |
| 沸点 | 106ºC at 760mmHg |
|---|---|
| 分子式 | C10H10F6NiO4 |
| 分子量 | 366.86800 |
| 闪点 | 26.1ºC |
| 精确质量 | 365.98400 |
| PSA | 68.28000 |
| LogP | 2.19380 |
| 外观性状 | Powder | green |
| 蒸汽压 | 0.108mmHg at 25°C |
| 储存条件 | 常温密闭避光，通风干燥 |
| 稳定性 | 常温常压下稳定 避免的物料： 氧化物 |
| 计算化学 | 1、 氢键供体数量：0 2、 氢键受体数量：10 3、 可旋转化学键数量：4 4、 互变异构体数量：15 5、 拓扑分子极性表面积（TPSA）：68.3 6、 重原子数量：21 7、 表面电荷：0 8、 复杂度：159 9、 同位素原子数量：0 10、 确定原子立构中心数量：0 11、 不确定原子立构中心数量：0 12、 确定化学键立构中心数量：0 13、 不确定化学键立构中心数量：0 14、 共价键单元数量：3 |
| 更多 | 1. 性状：绿色粉末 2. 密度（g/mL,25/4℃）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：不能溶解的 |
|
Section 1: Product Identification Chemical Name:Nickel (II) trifluoroacetylacetonate dihydrate, 98% CAS Registry Number:14324-83-5 Formula:Ni(CF3COCHCOCH3)2.2H2O EINECS Number:None Chemical Family:metal fluorobeta-diketonate complexes Synonym:Nickel 1,1,1-trifluoro 2,4-pentanedionate, dihydrate
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound14324-83-5100%0.2mg/m3 (as Ni)1mg/m3 (as Ni) Section 3: Hazards Identification Irritating to skin, eyes and mucous membranes. May cause sensitization by skin contact. Nickel and certain Emergency Overview: nickel compounds may cause cancer. Primary Routes of Exposure:Ingestion, inhalation of dust Eye Contact:Causes irritation of the eyes, redness and pain. Skin Contact:Causes irritation of the skin with redness or rash. Prolonged contact with nickel salts may lead to dermatitis. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions. Acute Health Affects:Irritating to skin, eyes and respiratory tract. May cause sensitization by skin contact. Skin irritation and dermatitis. May cause cancer. Product contains organic fluorine which under certain Chronic Health Affects:conditions of use, decomposition, or metabolism, may generate fluoride ion, causing, nausea, hypocalcaemia, deterioration of bone, and kidney and liver damage. NTP:Yes IARC:Yes OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit corrosive fumes of hydrofluoric acid. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry place in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:green pwdr. Molecular Weight:364.87 (400.90) Melting Point:no data Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents Decomposition Products:carbon monoxide, carbon dioxide, fluorinated organics, nickel oxide and organic fumes. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:Carcinogen (as Ni) Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound: See category code N495 for reporting. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A |
|
毒理学数据: 1、急性毒性：主要的刺激性影响： 在皮肤上面：刺激皮肤和粘膜； 在眼睛上面：刺激的影响；没有已知的敏化影响。 生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。
|
| 危害码 (欧洲) | C: Corrosive; |
|---|---|
| 风险声明 (欧洲) | R20/21/22 |
| 安全声明 (欧洲) | 26-36/37/39-45 |
| 危险品运输编码 | UN 3288 |