1719-06-8

• 常用中文名：蒽-D10
• 常用英文名：(2H10)Anthracene
• CAS号：1719-06-8
• 分子式：C₁₄D₁₀
• 分子量：188.291
• 相关类别： 化学试剂 氘代试剂
• 发布时间：2018-05-10 08:00:00
• 更新时间：2024-01-02 16:40:20

• 染料工业用于制造分散染料、茜素还原染料。涂料工业用于制造油漆。塑料工业用作制造塑料和绝缘材料的原料。有机工业用于制造蒽醌。半导体工业用于有机半导体的研制。定性分析中用于显色反应定性检验茚、锑和溴。有机微量分析中用于测定碳和氢。

名称

• 中文名: 蒽-d10
• 英文名: 1,2,3,4,5,6,7,8,9,10-decadeuterioanthracene
• 中文别名: 蒽–d10; 蒽-D10
• 英文别名: (H)Anthracene; Anthracene-d; EINECS 217-004-5; anthracene-d10; decadeuterio-anthracene; MFCD00001241; Perdeuterioanthracene; Anthracene. perdeutero

物化性质

• 密度: 1.1±0.1 g/cm3
• 沸点: 337.4±9.0 °C at 760 mmHg
• 熔点: 210-215ºC(lit.)
• 分子式: C₁₄D₁₀
• 分子量: 188.291
• 闪点: 146.6±12.8 °C
• 精确质量: 188.141022
• LogP: 4.68
• 外观性状: 米色-黄色粉末
• 蒸汽压: 0.0±0.3 mmHg at 25°C
• 折射率: 1.715
• 储存条件:

  2-8°C密封储存

• 稳定性:

  常温常压下稳定，避免氧化物 光 酸接触

• 分子结构:

  1、 摩尔折射率：61.93

  2、 摩尔体积（m³/mol）：157.6

  3、 等张比容（90.2K）：414.9

  4、 表面张力（dyne/cm）：47.9

  5、 介电常数（F/m）：无可用

  6、 极化率（10 ^-24cm ³）：24.55

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:0

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积0

  7.重原子数量:14

  8.表面电荷:0

  9.复杂度:154

  10.同位素原子数量:10

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：有强烈刺激性的蓝色荧光的黄色结晶体。

  2. 密度（g/mL,25/4℃）： 1.25

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：210-215

  5. 沸点（ºC,常压）：340

  6. 沸点（ºC,5.2kPa）： 未确定

  7. 折射率： 未确定

  8. 闪点（ºC）： 121.11

  9. 比旋光度（º）： 未确定

  10. 自燃点或引燃温度（ºC）： 540

  11. 蒸气压（kPa,25ºC）： 0.13

  12. 饱和蒸气压（kPa,60ºC）： 未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）： 未确定

  15. 临界压力（KPa）： 未确定

  16. 油水（辛醇/水）分配系数的对数值： 未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）： 未确定

  19. 溶解性：溶于乙醇、乙醚、苯、氯仿和二硫化碳。

MSDS

Name: Anthracene-d10 Material Safety Data Sheet Synonym: CAS: 1719-06-8 Section 1 - Chemical Product MSDS Name:Anthracene-d10 Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 1719-06-8 Anthracene-d10 98+% 217-004-5 Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Hygroscopic (absorbs moisture from the air). Potential Health Effects Eye: May cause eye irritation. Skin: Causes mild skin irritation. Ingestion: The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Store under nitrogen. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 1719-06-8: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: beige to slight yellow Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 218-220 deg Autoignition Temperature: Not available. Flash Point: 121 deg C ( 249.80 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Insoluble. Specific Gravity/Density: Molecular Formula: C14D10 Molecular Weight: 188.14 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, light. Incompatibilities with Other Materials: Strong oxidizing agents, fluorine, acids (mineral, oxidizing, e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid), hypochlorite. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 1719-06-8 unlisted. LD50/LC50: Not available. Carcinogenicity: Anthracene-d10 - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 1719-06-8: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 1719-06-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 1719-06-8 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 符号: GHS07, GHS09
• 信号词: Warning
• 危害声明: H315-H319-H335-H410
• 警示性声明: P261-P273-P305 + P351 + P338-P501
• 靶器官: Blood, Central nervous system, Liver
• 危害码 (欧洲): Xi: Irritant;N: Dangerous for the environment;T: Toxic;
• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): 26-60-61-36/37-24/25-23-53
• 危险品运输编码: UN 3077 9
• WGK德国: 2

上下游产品

上游产品  1
120-12-7
下游产品  1
64983-55-7

制备

在煤焦油中，蒽的含量为1.4%。焦油连续蒸馏所得的I蒽油馏分段，占焦油12-14%，初馏点为300℃，在350℃前的馏出量为95%。I蒽油经冷却结晶、真空过滤或用离心机脱除部分油分，离心后的粗蒽含油分大于20-25%，其余成分是：蒽25-30%，咔唑20-25%、菲30%左右。其中蒽的收率占焦油中蒽源的58-87%。除了苯和萘以外，蒽是煤焦油中最重要的组分之一。在蒽的工业生产中，因为必须把沸点相近的菲和咔唑分离掉，所以比萘的制造困难得多。即使把蒸馏、结晶及溶剂抽提巧妙地结合起来，其产率也只有40-50%。从粗蒽中提取和精制蒽，是先利用菲易溶于油的特性使菲与蒽、咔唑分离。进一步分离蒽与咔唑的方法有蒸馏分离法和钾熔法。