84852-15-3
84852-15-3结构式
- 常用中文名：壬基酚
- 常用英文名：4-Nonylphenol, branched
- CAS号：84852-15-3
- 分子式：C15H24O
- 分子量：220.35000
- 相关类别： 化学试剂 有机试剂 酚类
- 发布时间：2018-07-17 16:17:47
- 更新时间：2024-01-02 07:59:43
| 中文名 | 壬基酚 |
|---|---|
| 英文名 | nonylphenol |
| 中文别名 |
对壬基苯酚
壬酚,壬酚,壬基苯酚 |
| 英文别名 |
4-Nonylphenol,tech.
mixture of ring and chain isomers branched(mixedisomers) C9-Branchedalkylphenol EINECS 203-199-4 p-nonylphenol,branched nonylphenols 4-Nonylphenol ers MFCD01778271 Branchedp-nonylphenol 4-nonyl-phenobranched |
| 密度 | 0.937 g/mL at 25 °C(lit.) |
|---|---|
| 沸点 | 293 °C |
| 分子式 | C15H24O |
| 分子量 | 220.35000 |
| 闪点 | 150°C |
| 精确质量 | 220.18300 |
| PSA | 20.23000 |
| LogP | 4.68530 |
| 外观性状 | 透明粘性液体 |
| 折射率 | n20/D 1.511(lit.) |
| 储存条件 | ?20°C |
| 计算化学 | 1、 疏水参数计算参考值（XlogP）：5.6 2、 氢键供体数量：1 3、 氢键受体数量：1 4、 可旋转化学键数量：7 5、 互变异构体数量：2 6、 拓扑分子极性表面积（TPSA）：20.2 7、 重原子数量：16 8、 表面电荷：0 9、 复杂度：157 10、同位素原子数量：0 11、确定原子立构中心数量：0 12、不确定原子立构中心数量：0 13、确定化学键立构中心数量：0 14、不确定化学键立构中心数量：0 15、共价键单元数量：1 |
| 更多 | 1. 液相标准热熔(J·mol-1·K-1)：426.8 2. 密度（g/mL25 ºC）：0.937 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：293 6. 沸点（ºC0.35mmHg）：未确定 7. 折射率：n20/D 1.511 8. 闪点（ºC）：150 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（正辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
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Section I.Chemical Product and Company Identification Chemical Name 4-Nonylphenol Portland OR SynonymNot available. Chemical FormulaC9H19C6H4OH CAS Number84852-15-3 Section II.Composition and Information on Ingredients Chemical NameCAS Number Percent (%)TLV/PELToxicology Data 4-Nonylphenol84852-15-3--------Not available.Rat LD50 (oral) 1620mg/kg Section III. Hazards Identification Acute Health EffectsHarmful if ingested or inhaled. Minimize exposure to this material. Severe overexposure can result in injury or death. Irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound. Chronic Health EffectsCARCINOGENIC EFFECTS : Not available. MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Not available. DEVELOPMENTAL TOXICITY: Not available. There is no known effect from chronic exposure to this product. Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions. Section IV.First Aid Measures Eye Contact Check for and remove any contact lenses. DO NOT use an eye ointment. Flush eyes with running water for a minimum of 15 minutes, occasionally lifting the upper and lower eyelids. Seek medical attention. Treat symptomatically and supportively. Skin Contact After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with an emollient. Seek medical attention. Treat symptomatically and supportively. Wash any contaminated clothing before reusing. If the victim is not breathing, perform artificial respiration. Loosen tight clothing such as a collar, tie, belt or waistband. If Inhalation breathing is difficult, oxygen can be administered. Seek medical attention. Treat symptomatically and supportively. IngestionINDUCE VOMITING by sticking finger in throat. Lower the head so that the vomit will not reenter the mouth and throat. Loosen tight clothing such as a collar, tie, belt, or waistband. If the victim is not breathing, administer artificial respiration. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Seek immediate medical attention and, if possible, show the chemical label. Treat symptomatically and supportively. Section V. Fire and Explosion Data Not available. FlammabilityCombustible.Auto-Ignition Flash PointsFlammable LimitsNot available. 150°C (302°F). Combustion Products These products are toxic carbon oxides (CO, CO 2). Fire Hazards No specific information is available regarding the flammability of this compound in the presence of various materials. Explosion HazardsRisks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. No additional information is available regarding the risks of explosion. Fire Fighting Media SMALL FIRE: Use DRY chemicals, CO 2, water spray or foam. and InstructionsLARGE FIRE: Use water spray, fog or foam. DO NOT use water jet. Continued on Next Page 4-Nonylphenol Section VI.Accidental Release Measures Spill CleanupIrritating material. InstructionsKeep away from heat and sources of ignition. Mechanical exhaust required. Stop leak if without risk. Finish cleaning the spill by rinsing any contaminated surfaces with copious amounts of water. Consult federal, state, and/or local authorities for assistance on disposal. Section VII. Handling and Storage Handling and StorageIRRITANT. Keep away from heat and sources of ignition. Mechanical exhaust required. When not in use, tightly seal the container and store in a dry, cool place. Avoid excessive heat and light. DO NOT ingest. Do not breathe gas, fumes, Information vapor or spray. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Treat symptomatically and supportively. Avoid contact with skin and eyes. Always store away from incompatible compounds such as oxidizing agents, alkalis (bases). Section VIII. Exposure Controls/Personal Protection Engineering ControlsProvide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash station and safety shower is proximal to the work-station location. Personal ProtectionSplash goggles. Lab coat. Vapor respirator. Boots. Gloves. A MSHA/NIOSH approved respirator must be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure LimitsNot available. Section IX. Physical and Chemical Properties Solubility Physical state @ 20°CViscous colorless liquid.Inosluble in water. Soluble in benzene, chlorinated solvents, 0.94ancline, heptane, aliphathic alcohols, and Specific Gravity ethylene glycol. Molecular Weight220.35Partition Coefficient Not available. Boiling Point293-297°CVapor PressureNot available. Melting PointNot available.Vapor DensityNot available. Refractive Index1.513VolatilityNot available. Critical TemperatureNot available.OdorSlight phenolic odor. ViscosityComparitively high.TasteNot available. Section X.Stability and Reactivity Data Stability This material is stable if stored under proper conditions. (See Section VII for instructions) Conditions of Instability Avoid excessive heat and light. Incompatibilities Reactive with strong oxidizing agents, strong alkalis (bases). Section XI. Toxicological Information RTECS NumberSM5600000 Routes of ExposureEye contact. Ingestion. Inhalation. Skin contact. Toxicity DataRat LD50 (oral) 1620mg/kg CARCINOGENIC EFFECTS : Not available. Chronic Toxic Effects MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Not available. DEVELOPMENTAL TOXICITY: Not available. There is no known effect from chronic exposure to this product. Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions. Acute Toxic EffectsHarmful if ingested or inhaled. Minimize exposure to this material. Severe overexposure can result in injury or death. Irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound. Continued on Next Page 4-Nonylphenol Section XII.Ecological Information EcotoxicityNot available. Environmental Fatep-Nonylphenol's production and use in the preparation of lubricating oil additives, resins, plasticizers, surface active agents, in stabilizers, petroleum demulsifiers, fungicides, antioxidants for rubbers and plastics, and as a starting material for the production of phenolic resins may result in its release to the environment through various waste streams. A major source of p-nonylphenol in the envrionment is as a biodegradation product of nonylphenyl ethoxylates. p-Nonylphenol has been identified in drinking water, ground water, river and lake water, sewage treatment plant effluent, and is a prominent contaminant in sewage sludge. If released to soil, p-nonylphenol will have no mobility. p-Nonylphenol will not be susceptible to direct photolysis on soil surfaces or in water based upon its lack of absorption of light at wave lengths >290 nm. Biodegradation of p-nonylphenol will occur rapidly in aerobic soils, but is inhibited in anaerobic soil conditions. If released to water, p-nonylphenol should adsorb to suspended solids and sediment. p-Nonylphenol may volatilize from water surfaces based on an estimated Henry's Law constant of 3.4X10-5 atm-cu m/mole with estimated half-lives for a model river and model lake of 1.8 days and 18 days, respectively. Volatilization half-lives from a model pond, can be estimated to be about 19.6 days if the effect of adsorption to sediment is ignored and 5.8 years when the effect of maximum adsorption is considered. Experimental BCF values of 281, 1300, and 3400 suggest that p-nonylphenol will bioconcentrate in aquatic organisms. Biodegradation of p-nonylphenol should occur rapidly in water. If released to the atmosphere, p-nonylphenol will exist in the vapor phase. Vapor-phase p-nonylphenol is degraded in the atmosphere by reaction with photochemically produced hydroxyl radicals with an estimated half-life of about 7.5 hours. Reactions with nitrate radicals may also be important. The general population may be exposed to p-nonylphenol through drinking water.(SRC) Section XIII. Disposal Considerations Recycle to process, if possible. Consult your local or regional authorities. You may dissolve or mix material with a Waste Disposal combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state, and local regulations when disposing of this substance. Section XIV. Transport Information DOT Classification DOT CLASS 8: Corrosive liquid. PIN Number Proper Shipping NameAlkylphenols, liquid, n.o.s. Packing Group (PG)III DOT Pictograms Section XV. Other Regulatory Information and Pictograms TSCA Chemical InventoryThis product is ON the Toxic Substances Control Act (TSCA) list. (EPA) WHMIS Classification Not available. (Canada) EINECS Number (EEC) 203-199-4 EEC Risk Statements R20/21/22- Harmful by inhalation, in contact with skin and if swallowed. R36/37/38- Irritating to eyes, respiratory system and skin. SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 1、皮肤/眼睛刺激性：标准Draize实验：兔子，500 mg/24HREACTION SEVERITY，强烈反应； 标准Draize实验：兔子，眼睛接触，100 mgREACTION SEVERITY，强烈反应； 2、 急性毒性：大鼠经口LD50：1300mg/kg；兔子皮肤接触LDLo：3160mg/kg； CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
|
| 符号 |
GHS05, GHS07, GHS08, GHS09 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H302-H314-H361fd-H410 |
| 补充危害声明 | Repeated exposure may cause skin dryness or cracking. |
| 警示性声明 | P273-P280-P305 + P351 + P338-P310-P501 |
| 个人防护装备 | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US) |
| 危害码 (欧洲) | C:Corrosive;N:Dangerousfortheenvironment; |
| 风险声明 (欧洲) | R22;R34;R50/53 |
| 安全声明 (欧洲) | S26-S36/37/39-S45 |
| 危险品运输编码 | UN 3145 8/PG 2 |
| WGK德国 | 3 |
| RTECS号 | SM5650000 |
| 危险类别 | 8.0 |