6321-40-0
6321-40-0结构式
- 常用中文名：2-Propen-1-amine,2-methyl-N,N-bis(2-methyl-2-propen-1-yl)-
- 常用英文名：2-Propen-1-amine,2-methyl-N,N-bis(2-methyl-2-propen-1-yl)-
- CAS号：6321-40-0
- 分子式：C12H21N
- 分子量：179.30200
- 发布时间：2017-02-07 17:02:33
- 更新时间：2024-01-02 14:38:42
| 英文名 | 2-methyl-N,N-bis(2-methylprop-2-enyl)prop-2-en-1-amine |
|---|---|
| 英文别名 |
2-methyl-n,n-bis(2-methylprop-2-en-1-yl)prop-2-en-1-amine
tris(2-methylallyl)amine Trimethallylamin (CH2=C(CH3)CH2)3N TRIMETHALLYLAMINE |
| 密度 | 0.794 g/mL at 25ºC(lit.) |
|---|---|
| 沸点 | 83-85ºC15 mm Hg(lit.) |
| 分子式 | C12H21N |
| 分子量 | 179.30200 |
| 闪点 | 128 °F |
| 精确质量 | 179.16700 |
| PSA | 3.24000 |
| LogP | 3.01670 |
| 折射率 | n20/D 1.4575(lit.) |
Synonym:None known Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 10 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Flammable. Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. May cause chemical conjunctivitis and corneal damage. Skin: Causes skin irritation. May cause irritation and dermatitis. May cause cyanosis of the extremities. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Ingestion of large amounts may cause CNS depression. Inhalation: Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. Can produce delayed pulmonary edema. May cause burning sensation in the chest. Chronic: Effects may be delayed. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels. Exposure Limits CAS# 6321-40-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: pale-yellow Odor: amine-like pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 83- 85 deg C @ 15.00mm Hg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: 53 deg C ( 127.40 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: .7940g/cm3 Molecular Formula: C12H21N Molecular Weight: 179.30 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Incompatible materials, ignition sources, excess heat, strong oxidants. Incompatibilities with Other Materials: Acids, acid chlorides, acid anhydrides, carbon dioxide, strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 6321-40-0 unlisted. LD50/LC50: Not available. Carcinogenicity: Tris-(2-methylallyl)-Amine - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: FLAMMABLE LIQUID, N.O.S.* Hazard Class: 3 UN Number: 1993 Packing Group: II IMO Shipping Name: FLAMMABLE LIQUID, N.O.S. Hazard Class: 3.2 UN Number: 1993 Packing Group: II RID/ADR Shipping Name: FLAMMABLE LIQUID, N.O.S. Hazard Class: 3 UN Number: 1993 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 10 Flammable. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 9 Keep container in a well-ventilated place. S 16 Keep away from sources of ignition - No smoking. S 24/25 Avoid contact with skin and eyes. S 28A After contact with skin, wash immediately with plenty of water. S 33 Take precautionary measures against static discharges. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 6321-40-0: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 6321-40-0 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 6321-40-0 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | Xi |
|---|---|
| 风险声明 (欧洲) | R10;R36/37/38 |
| 安全声明 (欧洲) | S16-S24/25 |
| 危险品运输编码 | UN 1993 3/PG 3 |
| 包装等级 | III |
| 危险类别 | 3.2 |
| 海关编码 | 2921199090 |
|
~69%
6321-40-0 |
| 文献：Sachinvala; Winsor; Maskos; Grimm; Hamed; Vigo; Bertoniere Journal of Organic Chemistry, 2000 , vol. 65, # 26 p. 9234 - 9237 |
|
~%
6321-40-0 |
| 文献：Shell Devel.Co. Patent: US2172822 , 1937 ; Full Text Show Details Tamele et al. Industrial and Engineering Chemistry, 1941 , vol. 33, p. 119 |
| 上游产品 2 | |
|---|---|
| 下游产品 1 | |
| 海关编码 | 2921199090 |
|---|---|
| 中文概述 | 2921199090 其他无环单胺及其衍生物及其盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |