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(1R,3S,5R)-2-(叔丁氧基羰基)-2-氮杂双环[3.1.0]己烷-3-羧酸

更新时间:2024-01-12 18:02:59

(1R,3S,5R)-2-(叔丁氧基羰基)-2-氮杂双环[3.1.0]己烷-3-羧酸结构式
(1R,3S,5R)-2-(叔丁氧基羰基)-2-氮杂双环[3.1.0]己烷-3-羧酸结构式
品牌特惠专场
常用名 (1R,3S,5R)-2-(叔丁氧基羰基)-2-氮杂双环[3.1.0]己烷-3-羧酸 英文名 N-Boc-L-trans-4,5-methanoproline
CAS号 197142-34-0 分子量 227.257
密度 1.3±0.1 g/cm3 沸点 355.9±25.0 °C at 760 mmHg
分子式 C11H17NO4 熔点 N/A
MSDS N/A 闪点 169.0±23.2 °C

 名称

中文名 N-叔丁氧羰基-L-反-2-氮杂二环[3.1.0]己烷-3-羧酸
英文名 (1R,3S,5R)-2-[(2-methylpropan-2-yl)oxycarbonyl]-2-azabicyclo[3.1.0]hexane-3-carboxylic acid
英文别名 更多

 物理化学性质

密度 1.3±0.1 g/cm3
沸点 355.9±25.0 °C at 760 mmHg
分子式 C11H17NO4
分子量 227.257
闪点 169.0±23.2 °C
精确质量 227.115753
PSA 66.84000
LogP 0.41
蒸汽压 0.0±1.7 mmHg at 25°C
折射率 1.537
储存条件 2-8°C,干燥密封

 合成线路

~75%

(1R,3S,5R)-2-(叔丁氧基羰基)-2-氮杂双环[3.1.0]己烷-3-羧酸结构式

(1R,3S,5R)-2-(叔...

197142-34-0

文献:Hanessian, Stephen; Reinhold, Ulrich; Gentile, Gabriella Angewandte Chemie (International Edition in English), 1997 , vol. 36, # 17 p. 1881 - 1884

~76%

(1R,3S,5R)-2-(叔丁氧基羰基)-2-氮杂双环[3.1.0]己烷-3-羧酸结构式

(1R,3S,5R)-2-(叔...

197142-34-0

文献:BRISTOL-MYERS SQUIBB COMPANY; PACK, Shawn, K.; TYMONKO, Steven; PATEL, Bharat, P.; NATALIE, JR., Kenneth, J.; BELEMA, Makonen Patent: WO2011/59850 A1, 2011 ; Location in patent: Page/Page column 179-180 ;

~60%

(1R,3S,5R)-2-(叔丁氧基羰基)-2-氮杂双环[3.1.0]己烷-3-羧酸结构式

(1R,3S,5R)-2-(叔...

197142-34-0

文献:BRISTOL-MYERS SQUIBB COMPANY; PACK, Shawn, K.; TYMONKO, Steven; PATEL, Bharat, P.; NATALIE, JR., Kenneth, J.; BELEMA, Makonen Patent: WO2011/59850 A1, 2011 ; Location in patent: Page/Page column 178-179 ;

~%

(1R,3S,5R)-2-(叔丁氧基羰基)-2-氮杂双环[3.1.0]己烷-3-羧酸结构式

(1R,3S,5R)-2-(叔...

197142-34-0

文献:Hanessian, Stephen; Reinhold, Ulrich; Gentile, Gabriella Angewandte Chemie (International Edition in English), 1997 , vol. 36, # 17 p. 1881 - 1884

~%

(1R,3S,5R)-2-(叔丁氧基羰基)-2-氮杂双环[3.1.0]己烷-3-羧酸结构式

(1R,3S,5R)-2-(叔...

197142-34-0

文献:BRISTOL-MYERS SQUIBB COMPANY; PACK, Shawn, K.; TYMONKO, Steven; PATEL, Bharat, P.; NATALIE, JR., Kenneth, J.; BELEMA, Makonen Patent: WO2011/59850 A1, 2011 ;

~%

(1R,3S,5R)-2-(叔丁氧基羰基)-2-氮杂双环[3.1.0]己烷-3-羧酸结构式

(1R,3S,5R)-2-(叔...

197142-34-0

文献:BRISTOL-MYERS SQUIBB COMPANY; PACK, Shawn, K.; TYMONKO, Steven; PATEL, Bharat, P.; NATALIE, JR., Kenneth, J.; BELEMA, Makonen Patent: WO2011/59850 A1, 2011 ;

~%

(1R,3S,5R)-2-(叔丁氧基羰基)-2-氮杂双环[3.1.0]己烷-3-羧酸结构式

(1R,3S,5R)-2-(叔...

197142-34-0

文献:BOEHRINGER INGELHEIM INTERNATIONAL GMBH; THIBEAULT, Carl; EDWARDS, Paul, J.; KUHN, Cyrille; MOREAU, BenoIt; POIRIER, Maude; SURPRENANT, Simon Patent: WO2012/48421 A1, 2012 ;

~%

(1R,3S,5R)-2-(叔丁氧基羰基)-2-氮杂双环[3.1.0]己烷-3-羧酸结构式

(1R,3S,5R)-2-(叔...

197142-34-0

文献:BOEHRINGER INGELHEIM INTERNATIONAL GMBH; THIBEAULT, Carl; EDWARDS, Paul, J.; KUHN, Cyrille; MOREAU, BenoIt; POIRIER, Maude; SURPRENANT, Simon Patent: WO2012/48421 A1, 2012 ;

~%

(1R,3S,5R)-2-(叔丁氧基羰基)-2-氮杂双环[3.1.0]己烷-3-羧酸结构式

(1R,3S,5R)-2-(叔...

197142-34-0

文献:BRISTOL-MYERS SQUIBB COMPANY; PACK, Shawn, K.; TYMONKO, Steven; PATEL, Bharat, P.; NATALIE, JR., Kenneth, J.; BELEMA, Makonen Patent: WO2011/59850 A1, 2011 ;

 英文别名

(1R,3S,5R)-2-{[(2-Methyl-2-propanyl)oxy]carbonyl}-2-azabicyclo[3.1.0]hexane-3-carboxylic acid
N-Boc-L-trans-4,5-methanoproline
(1R,3S,5R)-2-(tert-butoxycarbonyl)-2-azabicyclo[3.1.0]hexane-3-carboxylic acid
(1R,3S,5R)-2-aza-bicyclo[3.1.0]hexane-2,3-dicarboxylic acid 2-tert-butyl ester
2-Azabicyclo[3.1.0]hexane-2,3-dicarboxylic acid, 2-(1,1-dimethylethyl) ester, (1R,3S,5R)-
(1R,3S,5R)-2-tert-butoxycarbonyl-2-azabicyclo[3.1.0]hexane-3-carboxylic acid
(4R,5R)-metano-N-Boc-L-proline
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