(11bS)-N,N-双[(R)-1-苯基乙基]-联萘并[2,1-d:1',2'-f][1,3,2]二氧膦杂-4-胺结构式
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常用名 | (11bS)-N,N-双[(R)-1-苯基乙基]-联萘并[2,1-d:1',2'-f][1,3,2]二氧膦杂-4-胺 | 英文名 | (11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine |
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CAS号 | 497883-22-4 | 分子量 | 539.603 | |
密度 | N/A | 沸点 | 710.7±63.0 °C at 760 mmHg | |
分子式 | C36H30NO2P | 熔点 | 102-103°C | |
MSDS | N/A | 闪点 | 383.6±33.7 °C |
中文名 | (11bS)-N,N-双[(R)-1-苯基乙基]-联萘并[2,1-d:1',2'-f][1,3,2]二氧膦杂-4-胺 |
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英文名 | N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine |
英文别名 | 更多 |
沸点 | 710.7±63.0 °C at 760 mmHg |
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熔点 | 102-103°C |
分子式 | C36H30NO2P |
分子量 | 539.603 |
闪点 | 383.6±33.7 °C |
精确质量 | 539.201416 |
LogP | 10.33 |
蒸汽压 | 0.0±2.3 mmHg at 25°C |
储存条件 | 室温,干燥 |
个人防护装备 | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
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危险品运输编码 | NONH for all modes of transport |
Tandem asymmetric conjugate addition--silylation of enantiomerically enriched zinc enolates. Synthetic importance and mechanistic implications.
Org. Lett. 4 , 3835, (2002) [formula: see text] The zinc enolates, resulting from the copper-catalyzed enantioselective conjugate addition of dialkyl zinc reagents to cyclic and acyclic enones, could be trapped, quantitatively, ... |
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Copper-catalyzed enantioselective conjugate addition of dialkylzinc reagents to (2-pyridyl)sulfonyl imines of chalcones.
J. Org. Chem. 70 , 7451, (2005) [reaction: see text] The enantioselective catalytic 1,4-addition to alpha,beta-unsaturated ketimines is an unprecedented process. Herein, we document the copper-catalyzed addition of dialkylzinc reage... |
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Synlett , 1375, (2001)
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N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine |
Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1R)-1-phenylethyl]- |
MFCD08561138 |
(11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine |