(11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
Modify Date: 2024-01-06 15:08:26
![(11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Structure](https://image.chemsrc.com/caspic/019/497883-22-4.png)
(11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine structure
|
Common Name | (11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine | ||
|---|---|---|---|---|
| CAS Number | 497883-22-4 | Molecular Weight | 539.603 | |
| Density | N/A | Boiling Point | 710.7±63.0 °C at 760 mmHg | |
| Molecular Formula | C36H30NO2P | Melting Point | 102-103°C | |
| MSDS | N/A | Flash Point | 383.6±33.7 °C | |
| Name | N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine |
|---|---|
| Synonym | More Synonyms |
| Boiling Point | 710.7±63.0 °C at 760 mmHg |
|---|---|
| Melting Point | 102-103°C |
| Molecular Formula | C36H30NO2P |
| Molecular Weight | 539.603 |
| Flash Point | 383.6±33.7 °C |
| Exact Mass | 539.201416 |
| LogP | 10.33 |
| Vapour Pressure | 0.0±2.3 mmHg at 25°C |
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
|---|---|
| RIDADR | NONH for all modes of transport |
|
Tandem asymmetric conjugate addition--silylation of enantiomerically enriched zinc enolates. Synthetic importance and mechanistic implications.
Org. Lett. 4 , 3835, (2002) [formula: see text] The zinc enolates, resulting from the copper-catalyzed enantioselective conjugate addition of dialkyl zinc reagents to cyclic and acyclic enones, could be trapped, quantitatively, ... |
|
|
Copper-catalyzed enantioselective conjugate addition of dialkylzinc reagents to (2-pyridyl)sulfonyl imines of chalcones.
J. Org. Chem. 70 , 7451, (2005) [reaction: see text] The enantioselective catalytic 1,4-addition to alpha,beta-unsaturated ketimines is an unprecedented process. Herein, we document the copper-catalyzed addition of dialkylzinc reage... |
|
|
Synlett , 1375, (2001)
|
| N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine |
| Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1R)-1-phenylethyl]- |
| MFCD08561138 |
| (11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine |