Journal of the American Chemical Society

Derivatives of Thianaphthene. III

FF Blicke, DG Sheets

Index: Blicke; Sheets Journal of the American Chemical Society, 1949 , vol. 71, p. 4010

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Citation Number: 27

Abstract

Summary Several 2-aminothiazoles and 2-acetamidothiazoles were prepared. Reactions of mercuration, halogenation, nitration and thiocyanation are reported. The bromine in 5-bromo- 2-acetarnidothiazole is replaced by nitro during nitration. Reduction of the 5-thiocyanato derivatives produces the 5-mercapto derivatives, but oxidation caused cleavage to sulfuric acid. Sp-Chlorobenzylisothiuroniurn sulfate is a new derivative of sulfuric acid.