Organic letters

MnO2 Promoted Sequential C–O and C–N Bond Formation via C–H Activation of Methylarenes: A New Approach to Amides

R Vanjari, T Guntreddi, KN Singh

Index: Vanjari, Rajeshwer; Guntreddi, Tirumaleswararao; Singh, Krishna Nand Organic Letters, 2013 , vol. 15, # 18 p. 4908 - 4911

Full Text: HTML

Citation Number: 55

Abstract

The development of novel chemical reactions and recuperating the reaction conditions to maximize product selectivity, energy efficiency, and environmental safety remains the main thrust of current chemical research. Hydrocarbons, derived from oil and natural gas, constitute the most inexpensive and readily available feed stocks for chemical industries. Therefore, direct formation of C–C and C–X linkage via carbon–hydrogen (C–H) bond activation of hydrocarbons is of immense ...

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p-Xylene Structure

106-42-3

p-Xylene

chloro-benzyl amine Structure

29237-95-4

chloro-benzyl amine

~78%

Benzamide,4-methyl-N-(phenylmethyl)- Structure

5436-83-9

Benzamide,4-met...

Benzylamine Structure

100-46-9

Benzylamine

~%

Benzamide,4-methyl-N-(phenylmethyl)- Structure

5436-83-9

Benzamide,4-met...

PIPERIDINE, 1-CHLORO- Structure

2156-71-0

PIPERIDINE, 1-C...

Toluene Structure

108-88-3

Toluene

~76%

1-benzoylpiperidine Structure

776-75-0

1-benzoylpiperidine

2-Chlorotoluene Structure

95-49-8

2-Chlorotoluene

chloro-benzyl amine Structure

29237-95-4

chloro-benzyl amine

~66%

N-benzyl-2-chloro-benzamide Structure

7506-50-5

N-benzyl-2-chlo...

Benzylamine Structure

100-46-9

Benzylamine

~%

N-benzyl-2-chloro-benzamide Structure

7506-50-5

N-benzyl-2-chlo...

N-chlorobutan-1-amine Structure

19798-58-4

N-chlorobutan-1...

Toluene Structure

108-88-3

Toluene

~76%

Benzamide, N-butyl- Structure

2782-40-3

Benzamide, N-butyl-

N-CHLOROMORPHOLINE Structure

23328-69-0

N-CHLOROMORPHOLINE

p-Xylene Structure

106-42-3

p-Xylene

~67%

(4-Methylphenyl)morpholin-4-ylmethanone Structure

63833-44-3

(4-Methylphenyl...

2-Phenylethanamine Structure

64-04-0

2-Phenylethanamine

~%

2-CHLORO-N-PHENETHYL-BENZAMIDE Structure

38925-70-1

2-CHLORO-N-PHEN...

Benzylamine Structure

100-46-9

Benzylamine

~%

N-benzyl-4-chloro-benzamide Structure

7461-34-9

N-benzyl-4-chlo...

4-Chlorotoluene Structure

106-43-4

4-Chlorotoluene

chloro-benzyl amine Structure

29237-95-4

chloro-benzyl amine

~73%

N-benzyl-4-chloro-benzamide Structure

7461-34-9

N-benzyl-4-chlo...

4-Bromotoluene Structure

106-38-7

4-Bromotoluene

chloro-benzyl amine Structure

29237-95-4

chloro-benzyl amine

~76%

N-Benzyl-4-bromobenzamide Structure

80311-89-3

N-Benzyl-4-brom...

N-chloro-N-methyl-1-phenylmethanamine Structure

3555-71-3

N-chloro-N-meth...

Toluene Structure

108-88-3

Toluene

~65%

N-benzyl-N-methylbenzamide Structure

61802-83-3

N-benzyl-N-meth...

N-CHLOROMORPHOLINE Structure

23328-69-0

N-CHLOROMORPHOLINE

Toluene Structure

108-88-3

Toluene

~80%

4-benzoylmorpholine Structure

1468-28-6

4-benzoylmorpholine

4-Methylanisole Structure

104-93-8

4-Methylanisole

chloro-benzyl amine Structure

29237-95-4

chloro-benzyl amine

~75%

Benzamide,4-methoxy-N-(phenylmethyl)- Structure

7465-87-4

Benzamide,4-met...

Benzylamine Structure

100-46-9

Benzylamine

~%

Benzamide,4-methoxy-N-(phenylmethyl)- Structure

7465-87-4

Benzamide,4-met...


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