Journal of Catalysis

Gold (I) and (III) catalyze Suzuki cross-coupling and homocoupling, respectively

C González-Arellano, A Corma, M Iglesias…

Index: Gonzalez-Arellano; Corma; Iglesias; Sanchez Journal of Catalysis, 2006 , vol. 238, # 2 p. 497 - 501

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Citation Number: 108

Abstract

Trinuclear triphenylphosphine 1, 2Au (I) complexes with the [N, N, O]-tridentate unsymmetrical Schiff bases (1, 2) catalyze the Suzuki cross-coupling reaction to afford nonsymmetrical biaryls in good yields, whereas the 1, 2Au (III) complexes give only arylboronic homocoupling.