Aromatic aldehyde functionalized polycaprolactone and polystyrene macromonomers: Synthesis, characterization and aldehyde–aminooxy click reaction

PS Sane, BV Tawade, DV Palaskar, SK Menon…

Index: Sane, Prakash S.; Tawade, Bhausaheb V.; Palaskar, Dnyaneshwar V.; Menon, Shamal K.; Wadgaonkar, Prakash P. Reactive and Functional Polymers, 2012 , vol. 72, # 10 p. 713 - 721,9

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Citation Number: 8

Abstract

New bis-aldehyde functionalized initiators, viz, 4, 4′-(4, 4′-(5-hydroxypentane-2, 2-diyl) bis (4, 1-phenylene)) bis (oxy) dibenzaldehyde (1) and 4, 4′-bis (4-(4-(formylphenoxy) phenyl) pentyl 2-bromopropanoate (2) were synthesized starting from commercially available 4, 4′-bis (4-hydroxyphenyl) pentanoic acid. These initiators were utilized, respectively, for ring opening polymerization of ε-caprolactone and atom transfer radical ...