Iminoxyl radicals and stable products from the one-electron oxidation of 1-methylindole-3-carbaldehyde oximes

…, AC Ferguson, B Vojnovic, P Wardman

Index: Everett, Steven A.; Naylor, Matthew A.; Stratford, Michael R.L.; Patel, Kantilal B.; Ford, Eleonora; Mortensen, Alan; Ferguson, Amanda C.; Vojnovic, Borivoj; Wardman, Peter Journal of the Chemical Society, Perkin Transactions 2, 2001 , # 10 p. 1989 - 1997

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Citation Number: 18

Abstract

The radical intermediates and the stable products formed on one-electron oxidation of 1- methylindole-3-carbaldehyde oxime 2a were compared with those of 1-methylindole-3- carboxamidine oxime 4a in aqueous solution. The dibromide radical anion generated radiolytically by pulse radiolysis reacted with both 2a and 4a [double bond splayed left] C [double bond, length as m-dash] NOH to yield the radical cations [[double bond splayed ...