Synthesis of certain cyclic silanes

…, JA Hrabie, SL Narasimhan

Index: House, Herbert O.; Hrabie, Joseph A.; Narasimhan, S. Lakshmi Journal of Chemical & Engineering Data, 1986 , vol. 31, # 1 p. 124 - 127

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Citation Number: 9

Abstract

AS part of ou COMlWhg intereat (7-4) in the u88 Of steriCa# v bulky substitvents to control reactant conformatton and, in some cases, reactkn ste “ktry, we initiated a study of certain triilkylsilyl substituents, R, SI-. Such substituents, R, SC, have sufficient steric bulk (5-9) to exert control over reactant con-formation in a manner similar to bulky alkyl substituents (70). Thus, a conformational A value of 2.4-2.6 kcal/md Is reported for the trheWkW spup (8, Q). ...