The Journal of organic chemistry

Palladium-catalyzed thiocarbonylation of iodoarenes with thiols in phosphonium salt ionic liquids

H Cao, L McNamee, H Alper

Index: Cao, Hong; McNamee, Laura; Alper, Howard Journal of Organic Chemistry, 2008 , vol. 73, # 9 p. 3530 - 3534

Full Text: HTML

Citation Number: 78

Abstract

Trihexyl (tetradecyl) phosphonium hexafluorophosphate, a phosphonium salt ionic liquid (PSIL) is a particularly effective general reaction media for the Pd-catalyzed carbonylation reaction of iodoarenes and thiols to form thioesters. Recycling of the ionic liquid containing active Pd-catalyst was also demonstrated.

~80%

~89%

~95%

~43%

~79%

~95%

~74%

The direct thioesterification of aldehydes with disulfides v...

[Singh, Santosh; Yadav, Lal Dhar S. Tetrahedron Letters, 2012 , vol. 53, # 38 p. 5136 - 5140]

Equilibrium shift in the rhodium-catalyzed acyl transfer rea...

[Arisawa, Mieko; Igarashi, Yui; Kobayashi, Haruki; Yamada, Toru; Bando, Kentaro; Ichikawa, Takuya; Yamaguchi, Masahiko Tetrahedron, 2011 , vol. 67, # 40 p. 7846 - 7859]

An Improved Process for Preparation of S-Acetyl-l-glutathion...

[Bandgar, Babasaheb Pandurang; More, Parmeshwar Eknath; Kamble, Vinod Tribhuvannathji; Sawant, Sanjay Suresh Australian Journal of Chemistry, 2008 , vol. 61, # 12 p. 1006 - 1010]

Air-Stable, Cationic, Lewis Acid, Titanocene Perfluorooctane...

[Qiu, Ren Hua; Xu, Xin Hua; Li, Yin Hui; Shao, Ling Ling; Zhang, Guo Ping; An, De Lie Synthetic Communications, 2010 , vol. 40, # 22 p. 3309 - 3314]

An approach to the synthesis of thioesters and selenoesters ...

[Lin, Shao-Miao; Zhang, Ji-Lei; Chen, Jiu-Xi; Gao, Wen-Xia; Ding, Jin-Chang; Su, Wei-Ke; Wu, Hua-Yue Journal of the Brazilian Chemical Society, 2010 , vol. 21, # 9 p. 1616 - 1620]