Conformational structure of poly [2-(dimethylamino) ethyl methacrylate], 2-(dimethylamino) ethyl pivalate and of their quaternary iodides. Vibrational and NMR spectra

B Schneider, J Štokr, J Straka, M Přádný…

Index: Schneider, Bohdan; Stokr, Jan; Straka, Jaroslav; Pradny, Martin; Sevcik, Stanislav Collection of Czechoslovak Chemical Communications, 1988 , vol. 53, # 12 p. 3097 - 3107

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Abstract

Abstract Raman, infrared, and 1 H and 13 C NMR spectra of 2-(dimethylamino) ethyl pivalate, 2-(pivaloyloxy) ethyltrimethylammonium iodide, poly [2-(dimethylamino) ethyl methacrylate] and of its quaternary iodide were measured. Spectral analysis revealed that in crystalline 2-(dimethylamino) ethyl pivalate and in its quaternary salt, the 2-(dimethylamino) ethyl group exists in the g conformational state. In the liquid state, these compounds also ...