2-(Dimethylamino)ethyl methacrylate

Modify Date: 2024-01-02 11:01:38

2-(Dimethylamino)ethyl methacrylate Structure
2-(Dimethylamino)ethyl methacrylate structure
Common Name 2-(Dimethylamino)ethyl methacrylate
CAS Number 2867-47-2 Molecular Weight 157.210
Density 0.9±0.1 g/cm3 Boiling Point 187.0±0.0 °C at 760 mmHg
Molecular Formula C8H15NO2 Melting Point -50 °C
MSDS Chinese USA Flash Point 70.6±0.0 °C
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

 Names

Name 2-(Dimethylamino)ethyl methacrylate
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 187.0±0.0 °C at 760 mmHg
Melting Point -50 °C
Molecular Formula C8H15NO2
Molecular Weight 157.210
Flash Point 70.6±0.0 °C
Exact Mass 157.110275
PSA 29.54000
LogP 1.50
Vapour density 5.4 (vs air)
Vapour Pressure 0.6±0.3 mmHg at 25°C
Index of Refraction 1.444
Stability Stable. Incompatible with strong acids, strong bases, strong oxidizing or reducing agents. May decompose on exposure to air and moisture. May undergo autopolymerization. Light sensitive.
Water Solubility decomposes

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OZ4200000
CHEMICAL NAME :
Methacrylic acid, 2-(dimethylamino)ethyl ester
CAS REGISTRY NUMBER :
2867-47-2
BEILSTEIN REFERENCE NO. :
1757048
LAST UPDATED :
199710
DATA ITEMS CITED :
11
MOLECULAR FORMULA :
C8-H15-N-O2
MOLECULAR WEIGHT :
157.24
WISWESSER LINE NOTATION :
1UY1&VO2N1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1751 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,55,1982
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
620 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,55,1982
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1800 mg/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,55,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
25 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
20800 nL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPMSAE Journal of Pharmaceutical Sciences. (American Pharmaceutical Assoc., 2215 Constitution Ave., NW, Washington, DC 20037) V.50- 1961- Volume(issue)/page/year: 63,376,1974 *** REVIEWS *** TOXICOLOGY REVIEW EVHPAZ EHP, Environmental Health Perspectives. (U.S. Government Printing Office, Supt of Documents, Washington, DC 20402) No.1- 1972- Volume(issue)/page/year: 11,141,1975 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1344 No. of Facilities: 438 (estimated) No. of Industries: 15 No. of Occupations: 18 No. of Employees: 3056 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - A1344 No. of Facilities: 129 (estimated) No. of Industries: 3 No. of Occupations: 4 No. of Employees: 10637 (estimated) No. of Female Employees: 429 (estimated)

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H302 + H312-H314-H317
Precautionary Statements P301 + P312 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P333 + P313
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant
Risk Phrases R21/22;R36/38;R43
Safety Phrases S26-S28-S2
RIDADR UN 2522 6.1/PG 2
WGK Germany 1
RTECS OZ4200000
Packaging Group II
Hazard Class 6.1
HS Code 29221980

 Synthetic Route

~89%

2-(Dimethylamino)ethyl methacrylate Structure

2-(Dimethylamin...

CAS#:2867-47-2

Detail
Literature: Liu, Leo Zhaoqing Patent: US2008/234515 A1, 2008 ; Location in patent: Page/Page column 4- 5 ;

~%

2-(Dimethylamino)ethyl methacrylate Structure

2-(Dimethylamin...

CAS#:2867-47-2

Literature: Arkema France Patent: US2012/123148 A1, 2012 ; Location in patent: Page/Page column 4-5 ;

~%

2-(Dimethylamino)ethyl methacrylate Structure

2-(Dimethylamin...

CAS#:2867-47-2

Literature: CIBA SPECIALTY CHEMICALS HOLDING INC. Patent: WO2007/57120 A1, 2007 ; Location in patent: Page/Page column 21-22 ;

~%

2-(Dimethylamino)ethyl methacrylate Structure

2-(Dimethylamin...

CAS#:2867-47-2

Literature: Rohm and Haas Co. Patent: US2832800 , 1956 ;

 Customs

HS Code 2922199090
Summary 2922199090. other amino-alcohols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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 Synonyms

Dimethylaminoethyl methacrylate
N,N-dimethyl-2-aminoethyl methacrylate
n,n-dimethylaminoethyl
DMAEMA
2-(N,N-dimethylamino)-ethyl methacrylate
Methacrylic Acid 2-(Dimethylamino)ethyl Ester
MFCD00008589
usafrh-3
2-Dimethylaminomethacrylate
ageflexfm-1
(2,2-dimethylaminoethyl) methacrylate
2-(Dimethylamino)ethyl Methacrylate
N,N-dimethylaminoethyl methacrylate
EINECS 220-688-8
Sipomer 2M1M