The challenge of palladium-catalyzed aromatic azidocarbonylation: from mechanistic and catalyst deactivation studies to a highly efficient process

…, CL McMullin, MM Belmonte, J Benet-Buchholz…

Index: Katritzky, Alan R.; Widyan, Khalid; Kirichenko, Kostyantyn Journal of Organic Chemistry, 2007 , vol. 72, # 15 p. 5802 - 5804

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Citation Number: 12

Abstract

... Select a Journal or Book ... Azidocarbonylation of iodoarenes with CO and NaN 3 , a novel Heck-type carbonylation reaction, readily occurs in an organic solvent–H 2 O ... N 3 ] (R = Me, Et) do not undergo CO insertion into the Pd–Ph bond but are rather converted to trans-[(R 3 P ...