Synthesis and chemical behavior of perchlorophenylacetylene

…, J Castaner, J Riera, I Tabernero

Index: Ballester, Manuel; Castaner, Juan; Riera, Juan; Tabernero, Ignacio Journal of Organic Chemistry, 1986 , vol. 51, # 9 p. 1413 - 1419

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Citation Number: 15

Abstract

Perchlorophenylacetylene (6) is synthesized in three steps:(1) vicinal reductive dechlorination of perchlorostyrene (1) to (pentachloropheny1) acetylene (2),(2) conversion of 2 into its silver acetylide (7), and (3) chlorination of 7 to 6. Some thermal and photochemical reactions of 6 are reported-including chlorine, cyclohexane, hydrogen chloride, water, methanol, perchloroethylene, and trichloroethylene additions-which yield ...