RhIII??Catalyzed Oxidative Olefination of Vinylic C H Bonds: Efficient and Selective Access to Di??unsaturated α??Amino Acid Derivatives and Other Linear 1, 3?? …

T Besset, N Kuhl, FW Patureau…

Index: Besset, Tatiana; Kuhl, Nadine; Patureau, Frederic W.; Glorius, Frank Chemistry - A European Journal, 2011 , vol. 17, # 26 p. 7167 - 7171

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Citation Number: 101

Abstract

The directed oxidative olefination of aromatic CÀH bonds, as pioneered by Fujiwara and Moritani,[1] mostly catalyzed by Pd [2–4](eg work by the groups of de Vries and van Leeuwen,[3] and Yu [4]) or Rh (eg work by Miura and Satoh and co-workers,[5] us,[6] and others [7]), has considerably improved the field of cross-coupling chemistry as it minimizes waste formation and prefunctionalization steps. However, applying these directed arene ...