Reactions of 1, 3-diacylthioureas with methoxide ion and with amines

J Kaválek, J Jirman, V Štěrba

Index: Kavalek, Jaromir; Jirman, Josef; Sterba, Vojeslav Collection of Czechoslovak Chemical Communications, 1987 , vol. 52, # 1 p. 120 - 131

Full Text: HTML

Citation Number: 6

Abstract

Abstract Rate constants of base-catalyzed methanolysis and dissociation constants in methanol have been determined for benzoylthiourea (II), 1, 3-diacetylthiourea (III), 1, 3- dibenzoylthiourea (IV), and 1-acetyl-3-benzoylthiourea (V). With the diacyl derivatives III and IV, the reaction of methoxide ion with the neutral substrate is accompanied by that of methoxide with the substrate anion (at higher alkoxide concentrations). Above 0.1 mol l-1 ...