Acyl Iodides in Organic Synthesis. Reaction of Acyl Iodides with N, N-Dimethyl Carboxylic Acid Amides

MG Voronkov, IP Tsyrendorzhieva…

Index: Voronkov; Tsyrendorzhieva; Rakhlin Russian Journal of Organic Chemistry, 2010 , vol. 46, # 10 p. 1476 - 1478

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Citation Number: 2

Abstract

Abstract Acyl iodides RCOI (R= Me, Ph) reacted with N, N-dimethylformamide and N, N- dimethylacetamide Me 2 NC (= O) R'(R'= H, Me) along two concurrent pathways involving transacylation and cleavage of the Me-N bond. The first pathway leads to the formation of acyl group exchange products, and the second, to the corresponding imides R'CON (Me) COR.