Direct C–C Bond Construction from Arylzinc Reagents and Aryl Halides without External Catalysts

…, X Wang, C Wang, M Uchiyama

Index: Minami, Hiroki; Wang, Xuan; Wang, Chao; Uchiyama, Masanobu European Journal of Organic Chemistry, 2013 , # 35 p. 7891 - 7894

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Citation Number: 3

Abstract

Cross-coupling reactions catalyzed by transition metals (TMs) are a fundamentally important tool for forming C–C and C–X bonds, both in academic research and on an industrial scale.1 The reaction occurs through an oxidative-addition–transmetalation–reductive-elimination catalytic cycle, which generally involves the transfer of two electrons, the TM determining the reactivity and/or selectivity. Therefore, development of new TM catalysts (with ligands) has long ...

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